Catalytic-esterification-free acid-degrading process for continuous production of high-acid-value waste oil and fat glycerin

A technology for catalyzing esterification and production process, applied in the field of circular economy and waste recycling, can solve the problems of a large amount of waste acid water polluting the environment, slow esterification reaction speed, frequent and complicated operations, etc., to avoid equipment corrosion, oleic acid Thorough, easy-to-use effects

A technology for catalyzing esterification and production process, applied in the field of circular economy and waste recycling, can solve the problems of a large amount of waste acid water polluting the environment, slow esterification reaction speed, frequent and complicated operations, etc., to avoid equipment corrosion, oleic acid Thorough, easy-to-use effects

CN107459997AInactive Publication Date: 2017-12-12INST OF CHEM IND OF FOREST PROD CHINESE ACAD OF FORESTRY
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  • Catalytic-esterification-free acid-degrading process for continuous production of high-acid-value waste oil and fat glycerin

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0025] (1) Mixing and distribution of raw materials: 12 tons / h of raw oil with an acid value of 48mgKOH / g and 1.32 tons / h of glycerin with a content of 95.7% are respectively transported through a centrifugal pump, measured by a flow meter, and mixed together into a heat exchanger. Glycerin and The mass ratio of oil and fat is 1.1:10.

[0026] (2) Heat exchange between mixed raw materials and finished products: the mixed raw materials and finished products pass through two shell-and-tube heat exchangers to exchange heat in countercurrent, the mixed raw materials are heated in series through the shell side of two shell-and-tube heat exchangers, and the finished oil passes through two shell-and-tube heat exchangers in series. The shell-and-tube tube pass is cooled. The mixed raw materials are heated to 116°C after heat exchange, and the temperature of the finished oil is reduced from 235°C to 142°C after heat exchange.

[0027] (3) Preheating of mixed raw materials after heat e...

Embodiment 2

[0032] (1) Mixing and distribution of raw materials: 13 tons / h of raw oil with an acid value of 26mgKOH / g and 1.3 tons / h of glycerol with a content of 96% are respectively transported through a centrifugal pump, measured by a flow meter, and mixed together into a heat exchanger. Glycerin and The mass ratio of oil and fat is 1:10.

[0033] (2) Heat exchange between mixed raw materials and finished products: the mixed raw materials and finished products pass through two shell-and-tube heat exchangers to exchange heat in countercurrent, the mixed raw materials are heated in series through the shell side of two shell-and-tube heat exchangers, and the finished oil passes through two shell-and-tube heat exchangers in series. The shell-and-tube tube pass is cooled. The mixed raw materials are heated to 110°C after heat exchange, and the temperature of the finished oil is reduced from 235°C to 148°C after heat exchange.

[0034] (3) Preheating of mixed raw materials after heat exchan...

Embodiment 3

[0039] (1) Mixing and distribution of raw materials: 11 tons / h of raw oil with an acid value of 71mgKOH / g and 1.32 tons / h of glycerin with a content of 96.1% are respectively transported through a centrifugal pump, measured by a flow meter, and mixed together into a heat exchanger. Glycerin and The mass ratio of oil and fat is 1.2:10.

[0040] (2) Heat exchange between mixed raw materials and finished products: the mixed raw materials and finished products pass through two shell-and-tube heat exchangers to exchange heat in countercurrent, the mixed raw materials are heated in series through the shell side of two shell-and-tube heat exchangers, and the finished oil passes through two shell-and-tube heat exchangers in series. The shell-and-tube tube pass is cooled. The mixed raw materials are heated to 122°C after heat exchange, and the temperature of the finished oil is reduced from 235°C to 137°C after heat exchange.

[0041] (3) Preheating of mixed raw materials after heat e...

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Abstract

A catalytic-esterification-free acid-degrading process for continuous production of high-acid-value waste oil and fat glycerin comprises the steps of raw material mixing and delivery, mixed raw material and finished product heat exchange, mixed raw material preheating after heat exchange, flash evaporation and dehydration of mixed raw materials, continuous esterification reaction and separation of glycerin extracted in the esterification process. The problems of low esterification reaction speed and non-thorough esterification caused by untimely reaction moisture discharging due to low reaction temperature in the process of preparing biodiesel by using high-acid-value waste cooking oil and leftovers in oil production industry and using methyl alcohol as an esterifying agent for pre-esterification and acid decrease are effectively solved, and the problems of device corrosion and environmental pollution brought by a large amount of produced waste acid water due to the fact that sulfuric acid is added to serve as a catalyst in the esterification process is solved. A continuous production process is adopted for esterification reaction, heat exchange of raw materials and finished products is achieved in the continuous process, and the problems of frequent and complicated operation, high labor cost, high production energy consumption, small yield and low efficiency of an intermittent esterification process are solved.

Description

technical field [0001] The invention uses low-cost waste oil with high acid value as a raw material to prepare biodiesel pre-esterification and acid reduction technology, and belongs to the fields of waste reuse and circular economy. It specifically relates to an energy-saving and high-efficiency high-acid-value waste oil glycerin non-catalyzed esterification and acid-reducing continuous production process. Background technique [0002] As the reserves of traditional petrochemical energy are dwindling, new renewable energy is getting more and more attention. As a substitute for petrochemical diesel, biodiesel has attracted widespread attention from all over the world because of its excellent performance and environmental friendliness. As biodiesel is a renewable clean energy, the development of biodiesel industry is of great significance to protect the environment and reduce dependence on petroleum. [0003] Biodiesel is fatty acid methyl ester (FAME) or ethyl ester fuel ...

Claims

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Application Information

Patent Timeline
12 Dec 2017
Publication
CN107459997A
IPC
C10G3/00
CPC
C10G3/40; C10G2300/1007; C10G2400/04; Y02E50/10; Y02P30/20
Inventors
蒋剑春; 陈水根