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Preparation method of composite algicide

An algaecide and the technology of preparation steps are applied in the field of compound algaecide preparation, which can solve the problems of low long-term algae killing rate, high local chemical concentration, and short effective time of chemical algae killing, so as to increase the specific surface area, Strong adsorption and the effect of improving the efficiency of algae removal

Inactive Publication Date: 2017-12-15
薛向东
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] The main technical problem to be solved by the present invention is that most of the current chemical algae removal methods directly add chemical algicides, which may easily cause excessive local chemical concentrations, which will have adverse effects on non-red algal organisms in the water body, and the chemical algae removal method is effective. Short time and long-term algae killing rate are low, and a preparation method of a compound algaecide is provided

Method used

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Examples

Experimental program
Comparison scheme
Effect test

example 1

[0026]Weigh the montmorillonite and soak it in hydrochloric acid with a concentration of 0.5mol / L for 1 hour, take it out, spray and freeze it with liquid nitrogen immediately for 2 minutes, and then put the frozen montmorillonite in an oven at 105°C for 1 hour to obtain pretreated montmorillonite soil; according to the mass ratio of 1:3, the mass fraction is 30% cobalt nitrate solution and the mass fraction is 20% ferric nitrate solution to mix to obtain a mixed solution, and the above pretreatment montmorillonite is soaked in 1mol / L citric acid solution for 20min After taking it out, immediately pour it into the mixed solution and continue soaking for 30 minutes to obtain the reaction mixed solution; adjust the pH of the above reaction mixed solution to 7.3 with 20% ammonia water by mass fraction, and heat up to 60°C, stir and mix for 20 minutes, filter, and separate to obtain the filter residue , transfer the obtained filter residue into a muffle furnace, heat-preserve and c...

example 2

[0028] Weigh the montmorillonite and soak it in 0.5mol / L hydrochloric acid for 1 hour, take it out, spray and freeze it with liquid nitrogen immediately for 2 minutes, then put the frozen montmorillonite in an oven and dry it at 108°C for 2 hours to obtain pretreated montmorillonite soil; according to the mass ratio of 1:3, the mass fraction is 30% cobalt nitrate solution and the mass fraction is 20% ferric nitrate solution to mix to obtain a mixed solution, and the above-mentioned pretreatment montmorillonite is soaked in 1mol / L citric acid solution for 25min After taking it out, immediately pour it into the mixed solution and continue soaking for 35 minutes to obtain the reaction mixed solution; adjust the pH of the above reaction mixed solution to 7.4 with 20% ammonia water by mass fraction, and heat up to 65°C, stir and mix for 25 minutes, filter, and separate to obtain the filter residue , transfer the obtained filter residue into a muffle furnace, heat-preserve and calcin...

example 3

[0030] Weigh the montmorillonite and soak it in hydrochloric acid with a concentration of 0.5mol / L for 2 hours, take it out, immediately spray and freeze it with liquid nitrogen for 3 minutes, then put the frozen montmorillonite in an oven and dry it at 110°C for 2 hours to obtain pretreated montmorillonite Soil; be 1:3 by mass fraction be that 30% cobalt nitrate solution and mass fraction are 20% ferric nitrate solution to mix to obtain mixed solution, above-mentioned pretreatment montmorillonite concentration is that 1mol / L citric acid solution soaks 30min After taking it out, immediately pour it into the mixed solution and continue soaking for 40 minutes to obtain the reaction mixed solution; adjust the pH of the above reaction mixed solution to 7.5 with 20% ammonia water by mass fraction, and heat up to 70°C, stir and mix for 30 minutes, filter, and separate to obtain the filter residue , transfer the obtained filter residue into a muffle furnace, heat-preserve and calcinat...

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Abstract

The invention relates to the technical field of algicide preparation, in particular to a preparation method of a composite algicide. The preparation method comprises steps as follows: interlayer spacing of montmorillonite is widened firstly, the montmorillonite is soaked with citric acid, cobalt-iron ions are complexed with citric acid, magnetic cobalt ferrite is generated after calcination, hydroxyl free radicals, hydrogen peroxide and ozone produced through a photochemical reaction are promoted to effectively kill algae under the photomagnetic synergistic effect, then snailase rich in different enzymes is supported on a crude algicide product and adopted to damage slime outside the algae, the algae are enabled to be exposed from slime outside the algae, the exposed algae are contacted with copper ions, and the copper ions are adsorbed to algal cell walls, penetrate through the cell walls and remains on cell membranes to inhibit activity of enzymes in the cell membranes and result in algal death finally, so that the purpose of algae removal is achieved. The metal copper ions are chelated on the surface of a magnetic green body, the release speed is reduced, so that the long-time algae removal effect can be achieved, and the preparation method has broad application prospect.

Description

technical field [0001] The invention relates to the technical field of algaecide preparation, in particular to a preparation method of a compound algaecide. Background technique [0002] Red tide refers to the change of water color caused by the sudden and abnormal proliferation of microorganisms in seawater. This phenomenon is caused by the blooms and high concentrations of certain microscopic plankton known as red tide organisms. Red tide is a kind of complex ecological anomaly, and its causes are complicated. The eutrophication of seawater is the material basis of red tide. In recent years, red tide disasters have occurred frequently in my country's coastal waters, resulting in serious economic losses and even threatening human health. The main methods of controlling red tide are physical method, biological method and chemical method. At present, most of the fastest-growing methods are chemical methods, which can be divided into direct killing method, coagulant precipi...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C02F1/50A01N63/02A01N59/16A01N59/20A01N59/00A01N59/06A01P13/00
CPCA01N59/00A01N59/06A01N59/16A01N59/20A01N63/10C02F1/50
Inventor 李华林茂兰
Owner 薛向东
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