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A kind of high-strength, high-conductivity, high-thermal-stability chromium-zirconium-copper alloy and preparation method thereof

A high thermal stability, chromium zirconium copper technology, applied in the field of alloy materials, can solve the problems of low tensile strength and high temperature stability, poor electrical conductivity and softening temperature, low hardness, tensile strength and high temperature stability, etc. To achieve the effect of good thermal stability, uniform microstructure and high cost performance

Active Publication Date: 2019-06-18
CHINA XD ELECTRIC CO LTD
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  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0006] Chinese patent CN 105543540 A discloses a chromium-zirconium-copper alloy and its preparation method. This type of alloy is a traditional low-chromium (0.7-2.0%) chromium-zirconium-copper alloy with a tensile strength of >520MPa and an electrical conductivity of >90% IACS. 350°C high temperature tensile strength > 390MPa, although its electrical conductivity is good, but the tensile strength and high temperature stability are low
Chinese patent CN102912178A discloses a high-strength and high-conductivity rare-earth copper alloy and its preparation method. This type of alloy is a traditional low-chromium (0.2-1.0%) rare-earth copper alloy, with tensile strength > 550MPa, hardness > 150HV, and conductivity > 80 %IACS, softening temperature > 450°C, although its electrical conductivity is good, but its hardness, tensile strength and high temperature stability are low
When smelting, zirconium is directly added, and the three elements of chromium, zirconium and copper are mixed and smelted at the same time, and then the ingot is hot-forged and then solid-soluted. The tensile strength of the obtained chromium-zirconium-copper material is 850-1300MPa , conductivity 70-80% IACS, softening temperature 500-550°C, although the strength is high, the conductivity and softening temperature are not good

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  • A kind of high-strength, high-conductivity, high-thermal-stability chromium-zirconium-copper alloy and preparation method thereof

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preparation example Construction

[0031] The preparation method of the high-strength, high-conductivity and high-thermal-stability chromium-zirconium-copper alloy comprises the following steps:

[0032] (1) Melting:

[0033] 1) Put copper in a metal cleaning solution prepared by powdered metal cleaning agent and 35-40°C hot water at a mass ratio of 1:(45-50), remove surface oil with a cotton brush, and then wash it with water And dry the copper with a compressed air gun.

[0034] 2) Furnace loading of raw materials: preheat the crucible in the resistance furnace to 80-110°C, take it out, wrap the weighed chromium powder with copper foil and place it at the bottom of the crucible, and put magnesium particles and copper from step 1) , and any one or more of selenium, nickel, silicon, and iron; then use copper wire to hang the copper bag wrapped with zirconium powder on the tamping rod; put the crucible and the mold with the riser into the furnace body In the middle, seal the furnace.

[0035] 3) Heat up to 10...

Embodiment 1

[0045] A high-strength, high-conductivity, high-thermal-stability chromium-zirconium-copper alloy contains the following components by weight percentage: 9% chromium, 0.3% zirconium, 0.006% magnesium, 0.013% nickel, and the balance is copper.

[0046] Its preparation method is:

[0047] (1) Melting:

[0048] 1) Place the industrial high-purity cathode copper rod in a metal cleaning solution prepared by powdered metal cleaning agent and 35°C hot water at a mass ratio of 1:45, remove the surface oil with a cotton brush, and then wash it with clean water and use Compressed air gun to dry industrial high-purity cathode copper rod.

[0049] 2) Furnace loading of raw materials: Preheat the magnesia crucible in the resistance furnace to 100°C and take it out, wrap the weighed chromium powder with copper foil and place it at the bottom of the magnesia crucible, and put magnesium grains, nickel and step 1) The industrial high-purity cathode copper rod; finally, hang the copper bag wr...

Embodiment 2

[0059] A high-strength, high-conductivity, high-thermal-stability chromium-zirconium-copper alloy contains the following components by weight percentage: 10% chromium, 0.24% zirconium, 0.017% magnesium, 0.008% selenium and iron, and the balance is copper.

[0060] Its preparation method is:

[0061] (1) Melting:

[0062] 1) Place the industrial high-purity cathode copper rod in a metal cleaning solution prepared by powdered metal cleaning agent and 38°C hot water at a mass ratio of 1:48, remove the surface oil with a cotton brush, and then wash it with clean water and use Compressed air gun to dry industrial high-purity cathode copper rod.

[0063] 2) Furnace loading of raw materials: preheat the magnesia crucible in the resistance furnace to 80°C and take it out, wrap the weighed chromium powder with copper foil and place it at the bottom of the magnesia crucible, and put magnesium grains, selenium, iron and the industrial high-purity cathode copper rod of step 1); the copp...

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Abstract

The invention provides a high-strength, high-conductivity and high-thermal-stability chromium-zirconium-copper alloy and a preparation method thereof. The chromium-zirconium-copper alloy comprises 9-14% of chromium, 0.24-0.6% of zirconium, 0.006-0.019% of magnesium, 0.008-0.13% of X and the balance copper, wherein X is any or several of selenium, nickel, silicon and iron. The preparation method of the chromium-zirconium-copper alloy comprises the following steps: charging raw materials; vacuumizing, charging a protective gas, and heating to melt copper; continuing to heat to melt chromium; adding zirconium in a crucible, melting down zirconium, then cooling until the skin of a melting-down melt starts to be solidified, vacuumizing and charging the protective gas, then heating until the melt is melted down again, cooling, casting, cooling and discharging. The content of the chromium component is increased through a reasonable alloy component design; and the copper alloy with a high strength (850-950MPa), high conductivity (82%-90%IACS) and high thermal stability (a softening temperature is 610-630 DEG C) is obtained through adjustment for the other components and the contents of the other components.

Description

technical field [0001] The invention belongs to the technical field of alloy materials, and relates to a high-strength, high-conductivity, high-thermal-stability copper alloy suitable for high requirements on strength, conductivity, and thermal stability, and specifically relates to a high-strength, high-conductivity, high-thermal-stability copper alloy Chromium zirconium copper alloy and its preparation method. Background technique [0002] Chromium-zirconium copper-based copper alloy is a kind of alloy with high electrical conductivity that is widely used. It is widely used in industrial fields such as coil spring contacts, integrated circuit lead frames, tram and electric locomotive contact wires, etc. Its main feature is that it has a high Conductivity, but low strength. [0003] The coil spring contact finger is a new type of movable electrical contact that has only appeared in recent years. The strength of chromium-zirconium copper alloy traditionally used to make co...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C22C9/00C22C1/02C22F1/08
CPCC22C1/02C22C9/00C22F1/08
Inventor 李家梅邵茜苏谋李伟李西育
Owner CHINA XD ELECTRIC CO LTD