Ore dressing combination reagent for rutile and ore dressing method of reagent

A technology of reagent and pulp, which is applied in the field of rutile mineral dressing combination reagent and its mineral processing, can solve the problems of weak collecting ability, poor use effect, low solubility, etc., achieve strong collecting ability and selection ability, facilitate industrial production, The effect of process simplification

Active Publication Date: 2017-12-29
CENT SOUTH UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Although fatty acid collectors are cheap, low in toxicity and strong in collecting ability, they have poor selectivity and are rarely used in flotation rutile; benzyl arsinic acid is the most typical rutile arsinic acid collector. Good performance, but expensive, high toxicity, and low solubility, some domestic rutile beneficiation plants still insist on using this kind of collector, but with the stricter and stricter environmental protection requirements and pressure year by year, arsine acid collectors are also gradually stopped Use: Styrene phosphonic acid is a typical rutile phosphonic acid collector, with good selectivity, strong collection capacity, and lower toxicity than arsinic acid collectors. It has long been regarded as a substitute for arsinic acid collectors Collector
However, it is expensive and highly corrosive to equipment. At the same time, phosphonic acid collectors have poor selectivity to calcium-containing gangue minerals. When the calcite content in the raw ore is too high, its use effect is not good; rutile hydroxamic acid Collectors are divided into alkyl (C 7~9 ) and benzene rings
The former has good collection performance and certain foaming performance, but its selective performance is weak; the latter has good selectivity and low toxicity, but its collection ability is weak and expensive

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0025] A kind of beneficiation method, mineral raw material is a certain rutile mine in Hubei, TiO 2 The grade is about 2.9%, and the main gangue minerals are hornblende and garnet.

[0026] The amount of flotation agent (combined beneficiation agent for rutile) is as follows (the amount used in the roughing process, the beneficiation process and the sweeping process is based on 1 ton of pulp):

[0027] Lead nitrate: the rough selection is 600g / t, and the sweeping selection is 300g / t;

[0028] Sodium fluorosilicate: the rough selection amount is 600g / t, and the selected amount is 300g / t;

[0029] Phenylalanine: 1000g / t for rough selection, 200g / t for sweeping;

[0030] No. 2 oil: 50g / t for crude and 25g / t for sweeping.

[0031] The specific flotation operation steps and technical conditions are as follows:

[0032] In the flotation process, the ore is added to the ore mill for grinding until the mineral monomers are dissociated, and the mass fraction of the minerals in the...

Embodiment 2

[0039] A kind of beneficiation method, mineral raw material is a certain rutile ore in Shandong, TiO 2 The grade is about 3.1%, and the main gangue minerals are hornblende and garnet.

[0040] The amount of flotation agent (combined beneficiation agent for rutile) is as follows (the amount used in the roughing process, the beneficiation process and the sweeping process is based on 1 ton of pulp):

[0041] Lead nitrate: the rough selection is 600g / t, and the sweeping selection is 300g / t;

[0042] Sodium hexametaphosphate: 300g / t for rough selection and 100g / t for selection;

[0043] Phenylalanine: 800g / t for crude and 400g / t for sweeping;

[0044] No. 2 oil: 50g / t for crude and 25g / t for sweeping.

[0045] The specific flotation operation steps and technical conditions are as follows:

[0046]In the flotation process, the ore is added to the ore mill for grinding until the mineral monomers are dissociated, and the mass fraction of the minerals in the slurry is controlled to...

Embodiment 3

[0053] A mineral processing method, the mineral raw material is a rutile mine in Inner Mongolia, TiO 2 The grade is about 4.6%, and the main gangue mineral is hornblende, followed by calcite.

[0054] The amount of flotation agent (combined beneficiation agent for rutile) is as follows (the amount used in the roughing process, the beneficiation process and the sweeping process is based on 1 ton of pulp):

[0055] Lead nitrate: the rough selection is 600g / t, and the sweeping selection is 300g / t;

[0056] Sodium hexametaphosphate: 300g / t for rough selection and 100g / t for selection;

[0057] Carboxymethyl cellulose: 200g / t for coarse selection and 100g / t for selection;

[0058] Phenylalanine: 500g / t for crude and 200g / t for sweeping;

[0059] No. 2 oil: 40g / t for crude and 20g / t for sweeping.

[0060] The specific flotation operation steps and technical conditions are as follows:

[0061] In the flotation process, the ore is added to the ore mill for grinding until the mine...

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PUM

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Abstract

The invention provides an ore dressing combination reagent for rutile. The reagent comprises a collecting agent, the collecting agent is phenyl amino acid, a pH value modulation agent, an activating agent, an inhibitor and a foaming agent are further included, and through the technical scheme, the reagent has the beneficial effects that the amino acid rutile collecting agent is adopted, and is poisonless and harmless, green and environment-friendly. The phenyl amino acid is adopted to serve as the collecting agent, the collecting capacity and the selecting capacity of rutile are high, and efficient separation of rutile and gangue mineral in the actual ore flotation can be achieved. The phenyl amino acid is adopted as the collecting agent, in combination with the pH value modulation agent, the activating agent, the inhibitor and the foaming agent, the rutile is subject to ore dressing, the proper matching is adopted, concentrate products with high TiO2 grade and the high recycling rate can be obtained, and the ore dressing effect is far better than that of the prior art.

Description

technical field [0001] The invention relates to the field of mineral processing technology, in particular to a rutile mineral processing combined reagent for rutile flotation and a mineral processing method thereof. Background technique [0002] Rutile is the mineral with the highest titanium content in nature, and it is the main raw material for extracting titanium metal, producing titanium dioxide and titanium dioxide materials with photocatalytic properties. my country's primary rutile mines account for 86% of natural rutile resources. Primary rutile resources are rich in reserves, but most of them are low-grade ores with finer particle size distribution, close intercalation relationship, complex mineral composition, and similar surface properties between useful minerals and gangue minerals. Therefore, the primary rutile ore in my country cannot adopt the combined process of gravity separation, electric separation and magnetic separation commonly used abroad. The flotati...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B03D1/01B03D101/02B03D103/04
CPCB03D1/01B03D2201/02B03D2203/04
Inventor 高志勇田孟杰孙伟胡岳华
Owner CENT SOUTH UNIV
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