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Preparation method for boron carbide-aluminium alloy composite board with crack-arresting through holes

An aluminum alloy and boron carbide technology, which is applied in the field of preparation of boron carbide ceramic-aluminum alloy composite plates, can solve the problems such as difficulty in giving full play to the excellent characteristics of boron carbide ceramics, difficulty in preparing large-size products, and limitations of large-thickness products, etc. The effect of mitigating adverse effects, simple process, and improving impact resistance

Inactive Publication Date: 2018-02-23
ZHEJIANG LIGHT TOUGH COMPOSITE MATERIALS
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] At present, the preparation of boron carbide ceramics-aluminum alloy composites is usually to prepare a porous boron carbide skeleton first, and then use the method of infiltrating liquid aluminum to obtain a three-dimensional network structure of boron carbide-aluminum composites, but it is difficult for this structural material to fully utilize carbonization. The excellent characteristics of boron ceramics are also difficult to prepare large-scale products
Tape casting can be used to form large-scale ceramic products, but it is usually suitable for the preparation of thin sheet products, and has great limitations in the preparation of large-thickness products

Method used

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  • Preparation method for boron carbide-aluminium alloy composite board with crack-arresting through holes
  • Preparation method for boron carbide-aluminium alloy composite board with crack-arresting through holes
  • Preparation method for boron carbide-aluminium alloy composite board with crack-arresting through holes

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0017] Step 1: Preparation of boron carbide ceramic plate

[0018] a. A certain proportion of B 4 Raw materials such as C powder and modified phenolic resin are ball milled in a ball mill for 12-24 hours to form a slurry. Raw material formula: B 4 C quality 80kg, modified phenolic resin 7kg, PVA800g, PEG400g, absolute ethanol 90kg; B 4 C is graded from powders of three particle sizes, one B 4 The average particle size of C powder is 8-10 microns, and the mass accounts for B 4 45% of the total mass of C; another B 4 The average particle size of C powder is 20-25 microns, and the mass accounts for B 4 35% of the total mass of C; the third type B 4 The average particle size of C powder is 2-4 microns, and the mass accounts for B 4 20% of the total mass of C; the ball milling medium is silicon carbide balls, and the weight ratio of balls to materials is 2: 1;

[0019] B carry out granulation with self-manufacturing granulator, and granulator is the self-made granulator of t...

Embodiment 2

[0029] The experimental procedure of this example is the same as that of Example 1, the only difference is that the step d) in the preparation method of the boron carbide ceramic plate in step 1) of Example 1 is replaced by: heating the compact in a mesh belt furnace, and the phenolic resin is decomposed And produce a coated carbon source to obtain a green body. The highest decomposition temperature of the compact in the mesh belt furnace is 820-850°C, and the speed of the mesh belt is 80-90 mm / min.

[0030] The company adopts the self-innovated reaction sintering process to coat the boron carbide powder with carbon source. By adding a binder, the strength of the compact is significantly improved. After the drying process, the crack hole can be processed on the green body. This process reduces the dissolution of silicon relative to boron carbide particles during the sintering process, improves the mechanical properties of ceramic products, and increases the microhardness, flexu...

Embodiment 3

[0032] The experimental procedure of this embodiment is the same as that of Example 1, and the only difference is the preparation method of the boron carbide ceramic plate in step 1) of Example 1; those skilled in the art know a variety of methods that can prepare a green body, such as using Conventional ball milling raw materials, granulator and compaction technology, as long as the granulated powder is controlled to be pressed into a compact with a thickness of 60-80mm, the purpose of the present invention can be achieved.

[0033] The brittleness of ceramic materials makes it poorly resistant to multiple bullets when used as a bulletproof material. After being impacted by a bullet, it is easy to cause overall fragmentation, disintegration of the structure, and cannot continue to protect subsequent strikes. Therefore, it is necessary to reduce the brittleness of boron carbide ceramics. The expansion of cracks in the center makes it only partially shattered when it is impacted...

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Abstract

The invention provides a preparation method for a boron carbide-aluminium alloy composite board with crack-arresting through holes. The method comprises the following steps: firstly, preparing a boroncarbide ceramic board with large thickness, and then directly performing pouring on the ceramic plate with aluminum alloy, so as to enable the boron carbide ceramic to be restrained and solidified bythe aluminum alloy in three-dimensional space, and to form an integrated structural material of aluminum-coated boron carbide. The crack-arresting holes uniformly distributed in the ceramic board arealso beneficial to flow and penetration of liquid aluminum in the pouring process, so that the combination of the aluminum alloy and the boron carbide ceramic is firmer.

Description

technical field [0001] The invention relates to the field of boron carbide bulletproof ceramics, in particular to a method for preparing a boron carbide ceramic-aluminum alloy composite plate. Background technique [0002] Bulletproof armor materials are increasingly developing in the direction of high hardness, high strength, high toughness, low density and low cost. Due to the high density of traditional metal bulletproof materials, vehicles, ships and aircraft have to sacrifice their payloads. At the same time, too thick armor reduces the operational flexibility of equipment. Therefore, lightweight bulletproof materials have become a current research hotspot and development trend . Ceramic materials have excellent properties such as high strength, high hardness, high temperature resistance, oxidation resistance, excellent wear resistance at high temperatures, small thermal expansion coefficient, and low density, and ceramic materials have beneficial energy absorption eff...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C04B35/563B22D19/08C04B35/622C04B35/626C04B35/634
CPCB22D19/08C04B35/563C04B35/622C04B35/62695C04B35/63476C04B2235/3826C04B2235/428C04B2235/48C04B2235/608C04B2235/612
Inventor 赵立夏伦刚崔毅方宁象
Owner ZHEJIANG LIGHT TOUGH COMPOSITE MATERIALS