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Fluorinated, hydrophobic and anti-seepage medical bag material and preparation method thereof

A hydrophobic and fluorinated technology, applied in the field of materials, can solve the problems of plasticizer migration, blooming, aging, etc., and achieve the effects of improving stability, strength, dispersion compatibility, and hydrophobic performance.

Inactive Publication Date: 2018-03-23
ANHUI JIANYUAN MEDICAL APP & INSTR EQUIP
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] However, the currently commercially available medical polyvinyl chloride materials tend to harden gradually at low temperatures, and will become brittle and yellow due to aging after long-term use, accompanied by the phenomenon of "blooming" in which plasticizers migrate to the surface

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0022] A fluorinated hydrophobic anti-leakage medical bag material, which is made up of the following raw materials in parts by weight:

[0023] Fluorinated monomer 20, zirconia 9, itaconic acid 2, dioctyl sebacate 4, polyethylene glycol 1000 4, lauryl dimethyl amine oxide 1, benzotriazole 1, ammonium polyphosphate 4 , Polyvinyl chloride 140, butyl tin mercaptide 1, dicumyl peroxide 2.

[0024] Described fluorinated monomer is made up of the raw material of following weight part:

[0025] Hexafluoroacetylacetone 0.2, borax 5, methyl methacrylate 10, methyl mercaptide tin 1, n-methylpyrrolidone 13.

[0026] The preparation method of described fluorinated monomer comprises the following steps:

[0027] Mix hexafluoroacetylacetone and tin methyl mercaptide, heat and stir at 60°C for 20 minutes, add to n-methylpyrrolidone, stir evenly, add borax, raise the temperature to 90°C, heat and stir for 10 minutes, add Methyl methacrylate, stirred to normal temperature to obtain the flu...

Embodiment 2

[0036] A fluorinated hydrophobic anti-leakage medical bag material, which is made up of the following raw materials in parts by weight:

[0037] Fluorinated monomer 16, zirconia 6, itaconic acid 1, dioctyl sebacate 3, polyethylene glycol 1000 3, lauryl dimethyl amine oxide 0.5, benzotriazole 0.7, ammonium polyphosphate 3 , polyvinyl chloride 120, butyl tin mercaptide 0.8, dicumyl peroxide 1.

[0038] Described fluorinated monomer is made up of the raw material of following weight part:

[0039] Hexafluoroacetylacetone 0.1, borax 3, methyl methacrylate 8, methyl mercaptan tin 0.7, n-methylpyrrolidone 10.

[0040] The preparation method of described fluorinated monomer comprises the following steps:

[0041] Mix hexafluoroacetylacetone and tin methyl mercaptide, heat and stir at 50°C for 10 minutes, add to n-methylpyrrolidone, stir evenly, add borax, raise the temperature to 80°C, heat and stir for 4 minutes, add Methyl methacrylate, stirred to normal temperature to obtain th...

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PUM

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Abstract

The invention discloses a fluorinated hydrophobic anti-leakage medical bag material, which is composed of the following raw materials in parts by weight: fluorinated monomer 16-20, zirconium oxide 6-9, itaconic acid 1-2, sunflower Dioctyl dioic acid 3‑4, polyethylene glycol 1000 3‑4, lauryl dimethylamine oxide 0.5‑1, benzotriazole 0.7‑1, ammonium polyphosphate 3‑4, polyvinyl chloride 120‑ 140, butyl tin mercaptide 0.8-1, dicumyl peroxide 1-2, the present invention effectively improves the dispersion compatibility of zirconia in polyester, improves the stability strength of the finished product, the present invention adopts Fluorine-modified monomers can effectively improve the hydrophobicity of finished materials.

Description

technical field [0001] The invention belongs to the field of materials, and in particular relates to a fluorinated hydrophobic anti-leakage medical bag material and a preparation method thereof. Background technique [0002] Medical polyvinyl chloride is a thermoplastic resin polymerized by vinyl chloride under the action of an initiator. The average degree of polymerization is 5001-14001. It is insoluble in water but soluble in organic solvents such as cyclohexanone and tetrahydrofuran. The heat resistance is not high, generally it should be used below 70°C. Medical polyvinyl chloride requires its products to be slightly yellow, transparent, soft, and have certain anticoagulation and flexibility. It is mainly used for blood transfusion, infusion bags, catheters for extracorporeal circulation devices, bubbling oxygenation bags, urine bags, etc. Products for short-term human exposure. [0003] However, currently commercially available medical polyvinyl chloride materials t...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L27/06C08L33/16C08K13/02C08K3/22C08K3/32C08K5/092C08K5/11C08F120/22
CPCC08L27/06C08F120/22C08K2003/2244C08K2003/323C08L33/16C08K13/02C08K3/22C08K3/32C08K5/092C08K5/11
Inventor 吴代斌
Owner ANHUI JIANYUAN MEDICAL APP & INSTR EQUIP
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