A kind of anti-WSSV membrane material and preparation method thereof
A technology of membrane material and membrane casting solution, which is applied in the field of anti-WSSV membrane material and its preparation, can solve the problems of no effective method, infection of cultured prawns, and influence on growth and development, and achieve shortened cleaning time, tolerance to natural seawater immersion, Strong anti-pollution effect
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Embodiment 1
[0042] This embodiment discloses the preparation method of anti-WSSV membrane material, adopts following steps:
[0043] (1) Prepare the casting solution according to the composition of the membrane material casting solution:
[0044] Polyvinylidene fluoride (PVDF) 10.0~16%; polyvinylpyrrolidone (PVP) 4.0%; calcium zinc heat stabilizer dose 1.0%; adjust the mass percentage to 100 each time with N, N-dimethylacetamide (DMAC) solvent %;
[0045] (2) Weigh each formula drug according to the above mass percentage;
[0046] (3) After the stirring is completed, the mixture has been completely dissolved to form a homogeneous casting solution, which is placed in an oven at 70°C for 24 hours for defoaming;
[0047] (4) Put a piece of paper on the floor of the scraping machine to prevent the glass plate from sliding, put the glass plate on the paper, use the screw micrometer head and the slider to adjust the height of the scraper to set the thickness of the scraping film, stick it wit...
Embodiment 2
[0068] In order to further determine the mass percentage of modifier PEG400 on the basis of example 1.
[0069] The configuration of the casting solution is as follows:
[0070] Polyvinylidene fluoride (PVDF) 10.0-16%; polyvinylpyrrolidone (PVP) 4.0%; calcium zinc heat stabilizer 1.0%; modifier PEG400 3.0-9.0%; The amide (DMAC) solvent adjusts the mass percentage of the casting solution to 100%.
[0071] (1) Viscosities of PEG / PVDF membranes with different concentration ratios
[0072] When the mass fraction of PEG400 is 3.0-9.0%, the viscosity of the PEG / PVDF film increases to a certain extent, but the increased viscosity is not very large. When the mass fraction of PEG400 is 3.0%, the mass fraction of PEG400 is 3.0%. Membrane fluid mixes best with other substances.
[0073] (2) Film thickness and tensile strength of PVDF / PEG modified film
[0074]
[0075] It can be seen from Table 2.1 that the thickness of the modified film changes without obvious rules, and there is...
Embodiment 3
[0083] On the basis of examples 1 and 2, in order to further consider the addition of CuSO to the casting solution 4 The effect on the removal rate of free virus WSSV, a casting solution: the mass fraction of polyvinylidene fluoride is 13%, polyvinylpyrrolidone (wt) is 4%, DMAC (wt) is 78.5-79.5%, calcium zinc heat stabilizer (wt) is 1%, PEG400 (wt) is 3%, CuSO 4 The mass fraction of polyvinylidene fluoride is 0.5 to 1.5%, and another casting solution: polyvinylidene fluoride is 13%, polyvinylpyrrolidone (wt) is 4%, DMAC (wt) is 79%, calcium zinc heat stabilizer ( wt) is 1%, PEG400 (wt) is 3%. Tubular membranes were prepared from two casting solutions (the pore size of both membranes was 0.22 μm), and the initial virus concentration of WSSV configured was determined by fluorescent quantitative PCR. The initial prawn WSSV filtrate was filtered through the two tubular membrane cups , the removal effect on WSSV is shown in Table 3.1.
[0084] Table 3.1 Changes in the number of...
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