Preparation method of enhanced polycarboxylate superplasticizer

A technology of polycarboxylate and water reducer, which is applied in the field of preparation of enhanced polycarboxylate water reducer, can solve the problems of large investment in fixed assets, slow production efficiency, long production process, etc., and achieve good economic and social benefits , easy operation, fast response effect

Inactive Publication Date: 2018-05-29
KZJ NEW MATERIALS GROUP CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] On the one hand, the current production process of polycarboxylate superplasticizers mostly adopts heating methods, such as steam heating, heat conduction oil heating, etc., which will cause environmental pollution
[0005] On the other hand, the current production process of polycarboxylate superplasticizers is relatively long, generally takes about 4 to 5 hours, and the production efficiency is slow, so it needs to be stocked in advance, and a certain amount of inventory needs to be occupied, resulting in waste of resources and large investment in fixed assets.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0017] (1) Graphene oxide modified polyether monomer: At 70-80°C, allyl polyoxyethylene ether and graphene oxide reacted for 5-8 hours under the catalysis of p-toluenesulfonic acid to obtain a modified polyether monomer. ether monomer. Wherein the mass ratio of allyl polyoxyethylene ether, graphene oxide and p-toluenesulfonic acid is: 100:5:3.

[0018] (2) Add the modified polyether monomer and water prepared in step (1) into the reactor to dissolve, put the reactor under ultraviolet light, and add the first solution and the second solution dropwise at a constant speed within 1-2h Carry out the polymerization reaction, after the dropwise addition, react at a constant temperature for 1 hour, add sodium hydroxide solution to neutralize to pH = 6-7, and obtain the enhanced polycarboxylate water reducer. Wherein the first solution is an aqueous solution of 2-methyl-1-(4-methylthiophenyl)-2-morpholino-1-propanone and 3,6-dioxo-1,8-octanedithiol, The second solution is an aqueous ...

Embodiment 2

[0021] (1) Graphene oxide modified polyether monomer: at 70-80°C, methallyl polyoxyethylene ether and graphene oxide react with p-toluenesulfonic acid for 5-8 hours to obtain modified permanent polyether monomer. Wherein the mass ratio of methallyl polyoxyethylene ether, graphene oxide and p-toluenesulfonic acid is: 100:7:4.

[0022] (2) Add the modified polyether monomer and water prepared in step (1) into the reactor to dissolve, put the reactor under ultraviolet light, and add the first solution and the second solution dropwise at a constant speed within 1-2h Carry out the polymerization reaction, after the dropwise addition, react at a constant temperature for 1 hour, add sodium hydroxide solution to neutralize to pH = 6-7, and obtain the enhanced polycarboxylate water reducer. Wherein the first solution is 2,2-dimethoxy-2-phenylacetophenone and 4-cyano-4-(phenylthioformylthio)valeric acid solution, and the second solution is maleic acid , N, N-dimethyl (meth)acrylamide ...

Embodiment 3

[0024] (1) Graphene oxide modified polyether monomer: At 70-80°C, isopentenyl polyoxyethylene ether and graphene oxide are reacted for 5-8 hours under the catalysis of p-toluenesulfonic acid to obtain modification Polyether monomer. Wherein the mass ratio of isopentenyl polyoxyethylene ether, graphene oxide and p-toluenesulfonic acid is: 100:10:3.

[0025] (2) Add the modified polyether monomer and water prepared in step (1) into the reactor to dissolve, put the reactor under ultraviolet light, and add the first solution and the second solution dropwise at a constant speed within 1-2h Carry out the polymerization reaction, after the dropwise addition, react at a constant temperature for 1 hour, add sodium hydroxide solution to neutralize to pH = 6-7, and obtain the enhanced polycarboxylate water reducer. Wherein the first solution is an aqueous solution of 4-hydroxybenzophenone and 2-(phenylthioformylthio)propionic acid, and the second solution is an aqueous solution of metha...

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Abstract

The invention discloses a preparation method of an enhanced polycarboxylate superplasticizer. Compared with a conventional solution polymerization method, the preparation method has the advantages ofhigh reaction speed, no need of heating, narrow molecular weight distribution and lower cost as well as simplicity and convenience in operation, easiness in industrial production and broad applicationprospect. A photoinitiator is adopted as a main substance, so that the reaction speed is improved, and high polymerization speed and high conversion rate of a product are realized; the prepared polycarboxylate superplasticizer has stable performance; a molecular structure of the prepared polycarboxylate superplasticizer is a comb type structure; a main chain contains a polar group, and a side chain contains a nitrogen-containing group; the enhanced polycarboxylate superplasticizer has good dispersity in concrete, and further early strength and late strength of the concrete are remarkably improved; the enhanced polycarboxylate superplasticizer has the characteristics of excellent working performance, good durability, low bleeding rate and good economic and social benefits.

Description

technical field [0001] The invention belongs to the technical field of building admixtures, and in particular relates to a preparation method of an enhanced polycarboxylate water reducer. Background technique [0002] With the development of concrete in the direction of high performance and multifunctionality, concrete is required to have high workability, high strength, high durability, and can meet the application in many special cases. Superplasticizers with hyperdispersive properties have become one of the indispensable components in high performance concrete. [0003] In recent years, with the country's increasing emphasis on energy saving and emission reduction and the rapid promotion of the concept of low-carbon economy, scientific and technological workers are striving to improve the performance of concrete water reducing agents and also pay attention to how to reduce their energy consumption. In particular, enterprises are trying to find products with low energy co...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08F283/06C08F222/02C08F220/58C08F220/54C08F220/06C08F222/38C08F2/48C08F2/38C04B24/26C04B103/30
Inventor 柯余良方云辉陈小路林添兴桂苗苗
Owner KZJ NEW MATERIALS GROUP CO LTD
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