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Preparation method of aluminum oxide porous ceramic with high closed porosity

A technology of porous ceramics and alumina, applied in the field of porous materials, can solve the problems of complex process and many kinds of additives, and achieve the effects of simple preparation process, high compressive strength and high closed porosity

Inactive Publication Date: 2018-06-15
WUHAN UNIV OF TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

The Chinese invention patent "A Preparation of Alumina Porous Ceramics by Gel-Foaming Method" (CN 102432332 A) discloses a method for preparing high-performance alumina porous ceramics by using a gel-foaming method. This method uses organic Monomers, crosslinking agents, dispersants, sintering aids, foaming agents and foam stabilizers, and more types of additives make the process more complicated, and the organic monomer N-methylolacrylamide and crosslinking agent N, N '-Methylenebisacrylamide is a low-toxic reagent, and the foaming agent is sodium dodecylbenzenesulfonate, which has slightly toxic properties

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  • Preparation method of aluminum oxide porous ceramic with high closed porosity
  • Preparation method of aluminum oxide porous ceramic with high closed porosity

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Embodiment 1

[0027] A preparation method of alumina porous ceramics with high closed porosity, comprising the steps of:

[0028] ①Raw material treatment: Ball mill the raw materials and pass through a 325-mesh sieve, and the particle size of all raw materials is controlled at 45-60 μm;

[0029] ② Raw material ratio: The mass percentage of each raw material is: alumina 50%, quartz 30%, Suzhou soil 10%, Australian clay 10%, CMC 0.6% (additional), gum arabic 0.7% (additional), pore forming agent Addition amount is 1.1g / (100g powder);

[0030] ③Raw material mixing: ball mill alumina, quartz, Suzhou soil, and Australian clay for 2 hours according to the ratio, and mark it as powder A; the quality of tap water accounts for 40% of the total mass of the slurry, and weigh the corresponding mass of CMC according to the ratio of raw materials 1. Dissolve gum arabic in tap water for later use, and mark it as solution B; mix powder A and solution B for 30 minutes to obtain a slurry. Add the pore-form...

Embodiment 2

[0037] A preparation method of alumina porous ceramics with high closed porosity, comprising the steps of:

[0038] ①Raw material treatment: Ball mill the raw materials and pass through a 325-mesh sieve, and the particle size of all raw materials is controlled at 45-60 μm;

[0039] ② Raw material ratio: the mass percentage of each raw material is: alumina 60%, quartz 20%, Suzhou soil 10%, North Sea kaolin 10%, CMC 0.6% (additional), gum arabic 0.6% (additional), pore forming agent Addition amount is 1.2g / (100g powder);

[0040]③Raw material mixing: ball mill alumina, quartz, Suzhou soil, and Beihai kaolin for 2 hours according to the ratio, and mark it as powder A; the quality of tap water accounts for 40% of the total mass of the slurry, and weigh the corresponding mass of CMC according to the ratio of raw materials 1. Dissolve gum arabic in tap water for later use, and mark it as solution B; mix powder A and solution B for 30 minutes to obtain a slurry. Add the pore-formin...

Embodiment 3

[0047] A preparation method of alumina porous ceramics with high closed porosity, comprising the steps of:

[0048] ①Raw material treatment: Ball mill the raw materials and pass through a 325-mesh sieve, and the particle size of all raw materials is controlled at 45-60 μm;

[0049] ② Raw material ratio: the mass percentage of each raw material is: alumina 60%, quartz 20%, Suzhou soil 20%, CMC 0.5% (additional), gum arabic 0.7% (additional), the amount of pore-forming agent added is 1.2% g / (100g material)

[0050] ③ Mixing of raw materials: Mix alumina, quartz, and Suzhou soil by ball milling for 2 hours according to a certain ratio, and mark it as powder A; the quality of tap water accounts for 40% of the total mass of the slurry, and weigh the corresponding quality of CMC and Arabica according to the ratio of raw materials. The gum was dissolved in tap water for later use, and marked as solution B; powder A and solution B were mixed for 30 minutes to obtain a slurry. Add th...

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Abstract

The invention relates to a method for preparing aluminum oxide porous ceramic with high closed porosity by taking aluminum oxide, clay and quartz as main raw materials through utilizing the thixotropyof slurry. The method comprises the following steps: preparing powder A from the following components: 50 percent to 80 percent of the aluminum oxide, 10 percent to 30 percent of the quartz and 10 percent to 20 percent of the clay; preparing a solution B from the following components: 0.4 to 0.6 percent of (additional) CMC (Carboxymethyl Cellulose), 0.5 to 0.7 percent of (additional) Arabic gum and tap water; taking an organic lightweight microsphere as a pore forming agent; mixing the powder A, the water solution B and the pore forming agent to obtain ceramic slurry; pouring the ceramic slurry into a gypsum mold, and curing and molding; then drying a blank body and firing the blank body to prepare the aluminum oxide porous ceramic with the high closed porosity. The aluminum oxide porousceramic prepared by the method has the advantages of simple preparation technology and toxin-free used raw materials and reagents; the product has the closed porosity which is greater than 65 percentand the compression strength which is greater than 17MPa.

Description

technical field [0001] The invention relates to a preparation method of alumina porous ceramics with high closed porosity. The porous ceramic is mainly used as a heat insulating material in various high-temperature environments, and belongs to the field of heat insulating materials and the technical field of porous materials. Background technique [0002] Porous ceramics have the characteristics of high porosity, low thermal conductivity, light weight, high temperature resistance, and corrosion resistance, and are ideal heat insulation materials. The raw materials for the preparation of alumina porous ceramics are easy to obtain and low in price. They have high strength at room temperature and high temperature. Organic insulation materials, mineral wool insulation boards, ceramic fiber boards, etc. In order to obtain excellent heat insulation performance, alumina porous ceramics are required to have a high closed porosity, which can effectively block conduction, convection...

Claims

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Application Information

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IPC IPC(8): C04B35/10C04B38/06
CPCC04B35/10C04B38/067C04B2235/3418C04B2235/349C04B2235/96C04B2235/9607C04B38/0074
Inventor 吴建锋桑榆徐晓虹张亚祥周炀张晨丁春江杜怿鑫
Owner WUHAN UNIV OF TECH