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Preparation method of cation modified polyacrylamide as well as sewage treatment method

A technology of polyacrylamide and treatment method, which is applied in the direction of water/sewage treatment, water/sludge/sewage treatment, flocculation/sedimentation water/sewage treatment, etc. It can solve the problems of unsatisfactory environmental assessment standards, unsatisfactory use effect, and residual water quality There are many impurities and other problems, and the composition and use process of the water purifying agent are simplified and the effect of remarkable purification effect is achieved.

Inactive Publication Date: 2018-06-22
南昌水业集团有限责任公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0003] At present, the main component of the water purifying agent used in the flocculation and sedimentation process is polymeric inorganic salts such as polyaluminum chloride, and the corresponding cost is relatively low, but the effect is not ideal according to the national environmental assessment standard. Polyacrylamide compounds have been introduced into the composition of water purifiers in recent years, but most of these compounds on the market are simple polyacrylamides with a single polymer unit structure, and there are still many functionalized polyacrylamides for domestic urban sewage treatment. There is a big blank, and the corresponding use effect is not ideal. This has also led to the innovation of water purifiers in recent years, which mainly focuses on the introduction of more compounds and more complex water purifiers.
[0004] Although this type of technology has realized the comprehensive treatment of various sewage components to a certain extent, it should be pointed out that the water purifier itself is also a type of impurities, and its complex components will also cause more residual impurities in the treated water. Therefore, the innovation of water purifiers that deserves more attention should focus on the use of purifiers with the simplest composition to achieve multifunctional treatment of various pollutant components, which requires the development of new water purifiers with a single chemical composition and multiple functions. Combined with the current water purification process, one of the most feasible directions to achieve this requirement is to carry out functional design and preparation of the chemical structure of polyacrylamide from the source and to screen the appropriate use process and conditions to realize the composition of water purification agent and application process. Simplify and improve the purification effect, thus adapting to the national environmental protection regulations and standards

Method used

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  • Preparation method of cation modified polyacrylamide as well as sewage treatment method
  • Preparation method of cation modified polyacrylamide as well as sewage treatment method

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preparation example Construction

[0024] Disclosed is a preparation method of cationic modified polyacrylamide; it comprises the following steps:

[0025] (1) Add 50ml-100ml of deionized water, 15g-25g of acrylamide with a concentration of 0.2-0.5g / ml, and 5g-10g of dimethyldiallyl ammonium chloride with a concentration of 0.1-0.3g / ml into the container , urea 0.05-0.2g, edetate disodium 0.05-0.2g;

[0026] (2) Pass nitrogen into the container (three-necked flask) to remove the oxygen in the container;

[0027] (3) Stir for 0.5h;

[0028] (4) Dissolve 0.01-0.002 g of ammonium persulfate and 0.01-0.002 g of a mixture of sodium borohydride and azobisisobutylamidine hydrochloride with a total mass of 0.0125% in 2 to 3 ml of deionized water to form a solution. (3) In the stirred solution;

[0029] (5) Heat up to 45-55°C, and stop the reaction when the reaction solution turns into a transparent colloid;

[0030] (6) Reduce the temperature and dry the colloid at 70°C to 90°C to constant weight and then pulverize...

Embodiment 1

[0045] Preparation of 30% monomer concentration cationic modified polyacrylamide (CPAM):

[0046] 1. In a three-necked flask equipped with a stirrer, reflux condenser and conduit, add 21g of acrylamide, 9g of dimethyl diallyl ammonium chloride, 0.1g of urea, EDTA-2Na salt (ethylenediaminetetraacetic acid di Sodium) 0.1g, deionized water 70mL;

[0047] 2. Continue to stir for 30 minutes and pass nitrogen;

[0048] 3. Slowly add the composite initiator dropwise: 0.0053g of ammonium persulfate, 0.0037g of sodium borohydride, 0.0125g of azobisisobutylamidine hydrochloride and 2-3mL of deionized water;

[0049] 4. React in a water bath at 50°C for 2-3 hours until the solution turns into a transparent colloid;

[0050] 5. Take out the reactants and dry them in a constant temperature oven at 75°C to constant weight, then pulverize them to obtain cationic modified polyacrylamide (CPAM).

[0051] Using the cationic modified polyacrylamide (CPAM) water purification steps of the prese...

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Abstract

The invention discloses a cation modified polyacrylamide water purification agent which is developed to realize flocculating purification of various sewage components, and can optimize the step conditions from preparation to use by aiming at the water purification effect and the application process so as to provide a preparation method of cation modified polyacrylamide as well as a sewage treatment method, which are strong in water purification comprehensive function and simple in process. The preparation method of the cation modified polyacrylamide comprises the following steps: (1) mixing; (2) removing oxygen; (3) stirring; (4) adding a composite initiator; (5) heating until transparent colloid is obtained and stopping heating; and (6) cooling, drying and pulverizing. The sewage treatment method comprises the following steps: (1) adding aluminum polychloride into sewage, and mixing and stirring; (2) adding the cation modified polyacrylamide, and mixing and stirring; (3) performing static flocculation settlement; and (4) filtering, and the like.

Description

technical field [0001] The invention relates to the technical field of sewage treatment, in particular to a preparation method of cationic modified polyacrylamide and a sewage treatment method. Background technique [0002] With the rapid improvement of urbanization and industrialization in our country, the total amount of sewage has increased, and the composition of sewage has become increasingly complex. From the perspective of natural environmental protection and sustainable development of the national economy, the relevant national environmental protection discharge standards have become more and more stringent. This reality objectively requires the innovation and upgrading of sewage treatment and environmental protection technology to adapt to it. At present, urban sewage is mainly collected and purified by water treatment plants before being discharged into the natural water system. The core process is the flocculation and sedimentation of sewage components with a spec...

Claims

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Application Information

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IPC IPC(8): C02F1/56C02F1/52C08F220/56C08F226/02
CPCC02F1/56C02F1/5236C08F220/56C08F226/02
Inventor 赵丹魏锋张雨青李钢王曦
Owner 南昌水业集团有限责任公司
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