C5 petroleum resin hydrogenation method

A technology of C5 petroleum resin and hydrogenation catalyst, which is applied in chemical instruments and methods, metal/metal oxide/metal hydroxide catalysts, chemical elements of heterogeneous catalysts, etc. , uneven mixing of crystal particles, etc., to achieve the effect of good regulation and high hydrogenation activity

Active Publication Date: 2018-07-10
PETROCHINA CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the active metal compound and aluminum hydroxide dry rubber powder or alumina powder are directly mixed and formed by kneading method. This method has proble

Method used

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  • C5 petroleum resin hydrogenation method
  • C5 petroleum resin hydrogenation method
  • C5 petroleum resin hydrogenation method

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0059] 1L concentration is 185g Al 2 o 3 / L sodium metaaluminate solution and 1L nickel nitrate solution with a concentration of 15g NiO / L are mixed evenly and placed in a stainless steel container with a stirrer and the bottom of the tank can be fed with gas, and a mixed gas of carbon dioxide and air is introduced, and the mixed gas Medium carbon dioxide concentration is 70v%, flow rate is 3Nm 3 / h, the gelling temperature is 35°C, the pH value of the gelling is 9.5, after the gelling is completed, stop feeding carbon dioxide, age for 45 minutes, the aging temperature is 45°C, filter and separate the mother liquor, and wash. Dry at 110°C for 3 hours to obtain nickel-containing pseudo-boehmite. Mix and knead the obtained nickel-containing pseudo-boehmite with nitric acid, phosphoric acid, citric acid, turmeric powder and water to form a plastic body, and extrude it into strips. Then it was dried at 120°C for 4 hours and calcined at 620°C for 4 hours to obtain a nickel-contai...

Embodiment 2

[0061] Concentrate 1L to 197g Al 2 o 3 / L of sodium metaaluminate solution and 1L of nickel nitrate solution with a concentration of 2.5g NiO / L are mixed evenly and placed in a stainless steel container with a stirrer and the bottom of the tank can be fed with gas, and a mixed gas of carbon dioxide and air is introduced, and mixed The carbon dioxide concentration in the gas is 70v%, the flow rate is 4Nm 3 / h, the gelling temperature is 30°C, the gelling PH value is 9.5, after the gelling is completed, stop feeding carbon dioxide, aging for 30 minutes, the aging temperature is 40°C, filter and separate the mother liquor, wash, dry at 100°C for 2 hours, and dry at 120°C 2h, the nickel-containing pseudo-boehmite was prepared. The prepared pseudo-boehmite was weighed, mixed with nitric acid, phosphoric acid, citric acid, turnip powder and water to form a plastic body, extruded into a rod, then dried at 120°C for 4 hours, and calcined at 610°C for 4 hours to obtain a carrier. An...

Embodiment 3

[0065] Dilute 1L concentration to 45g Al 2 o 3 / L of aluminum sulfate solution and 1L of nickel nitrate solution with a concentration of 8g NiO / L are mixed evenly and put into a container at a high position, and the prepared concentration is 145g Al 2 o 3 / L Sodium metaaluminate solution 1L is put into a container at a high position, and the two containers are connected with a peristaltic pump to control the flow rate and flow into a stainless steel container with a stirrer equipped with 5L of bottom water and the bottom of the tank can be fed into the gas. 55°C, the pH value of gelation is 9.2, after the gelation is completed, the pH value of the slurry is adjusted to 9.5 by dropping ammonia water, aged for 30 minutes, the aging temperature is 50°C, the mother liquor is separated by filtration, washed, and dried at 120°C for 2 hours to obtain nickel-containing Pseudoboehmite. The prepared nickel-containing pseudo-boehmite is mixed with nitric acid, citric acid, sage powder...

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Abstract

The invention provides a C5 petroleum resin hydrogenation method. The method includes: dissolving C5 petroleum resin into an organic solvent in a mixer, preheating, adding into a fixed bed hydrogenation reactor filled with a nickel-molybdenum hydrogenation catalyst, sending hydrogenated materials into a steam stripping tower, recycling the organic solvent extracted from the upper portion after refining the organic solvent through a distillation column, and obtaining C5 petroleum resin at the bottom of the steam stripping tower. By adoption of the catalyst prepared from a nickel-containing carrier in a specific crystal form, reactive metal utilization rate can be greatly improved, and catalyst preparation difficulty is lowered; in addition, due to adding of a selected active component, a synergistic effect is achieved, and C5 petroleum resin low in bromine number and high in chromaticity and stability can be obtained.

Description

technical field [0001] The invention relates to a method for hydrogenating C5 petroleum resin, in particular to a method for hydrogenating C5 petroleum resin catalyzed by a nickel-molybdenum series catalyst. Background technique [0002] The carbon five hydrocarbons mainly come from the by-product carbon five fractions in the high-temperature cracking of petroleum hydrocarbons to ethylene (referred to as cracked carbon five) and catalytic cracking gasoline in petroleum refineries. As of 2015, the global ethylene production capacity has reached 200 million tons. If liquid hydrocarbons (such as naphtha and light diesel oil) are used as cracking raw materials, the cracking C5 yield can reach 14-20% of the ethylene production. [0003] The utilization of carbon five hydrocarbons includes two aspects of fuel and chemical industry. For now, C5 hydrocarbons are basically used as fuel, and the chemical utilization rate is only about 10%. In terms of cracking C5 utilization, Shangh...

Claims

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Application Information

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IPC IPC(8): C08F8/04C08F240/00B01J23/883
CPCB01J23/002B01J23/883B01J2523/00C08F8/04C08F240/00B01J2523/11B01J2523/68B01J2523/847B01J2523/3706B01J2523/22
Inventor 展学成胡晓丽孙利民梁顺琴马好文郑云弟王斌钱颖潘曦竹管信泽李晓军李平智谢培思
Owner PETROCHINA CO LTD
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