Large-scale controllable preparation method of surface plasmon nanonail structure
A technology of surface plasmons and nano-nails, applied in separation methods, nanotechnology for materials and surface science, chemical instruments and methods, etc., can solve problems such as narrow-spectrum resonance effects, reduce production costs, and achieve realization shape-controllable effect
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[0069] 1. Synthesis of silver nanonails whose backbone is silver nanorods:
[0070] (1) Illumination-induced growth of decahedral nuclei
[0071] Add 0.52ml 0.5M sodium citrate, 15ul 0.5M PVP (molecular weight 40k), 0.05ml 0.05M L-arginine and 0.4ml 0.05M silver nitrate to 150ml water, stir for 5min and then add 2ml 0.1M Sodium borohydride, continue to stir for 45 minutes, add a small amount of hydrogen peroxide solution, stir for 25 minutes, and irradiate the mixed solution with light for 2 hours to obtain a silver decahedron solution.
[0072] (2) Chemical reduction growth of silver nanorods
[0073] Add 0.72ml 0.5M sodium citrate and 0.135ml 0.5M PVP to 60ml water, heat and stir at 115°C for 10min, add 0.4ml 0.05M silver nitrate, and add the silver decahedron prepared in step (1) at the same time, stop heating after 10min , to obtain a silver nanorod solution.
[0074] (3) Ingot epitaxial growth into nano-nails
[0075] Centrifuge the nanorod solution prepared in step (...
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