A kind of highly dispersed modified graphene oxide, its preparation method and anti-corrosion coating

A technology of anti-corrosion coatings and oxidized stones, which is applied in the direction of anti-corrosion coatings, epoxy resin coatings, coatings, etc., can solve problems such as poor dispersion and acid and alkali resistance, difficult dispersion stability of graphene, and complicated preparation process. To achieve the effect of long service life, enhanced dispersion and good anti-corrosion performance

Active Publication Date: 2019-10-25
XIAMEN UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0003] The Chinese patent application with the application number 201610878263.1 increases the stability of graphene through secondary oxidation modification of graphene, which is conducive to maximizing the corrosion resistance of graphene itself, so that the prepared coating has excellent adhesion, Hardness, wear resistance and neutral salt spray corrosion resistance, but this method requires more materials, the preparation process is complicated, the cost is high, and the dispersion and acid and alkali resistance are not good
[0004] At present, the way graphene is applied to coatings is mostly to add graphene as a functional filler, which brings about a key problem is how to solve the problem of graphene dispersion stability, which requires modification of graphene

Method used

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  • A kind of highly dispersed modified graphene oxide, its preparation method and anti-corrosion coating
  • A kind of highly dispersed modified graphene oxide, its preparation method and anti-corrosion coating
  • A kind of highly dispersed modified graphene oxide, its preparation method and anti-corrosion coating

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Experimental program
Comparison scheme
Effect test

Embodiment 1

[0038] (1) Preparation of highly dispersed modified graphene oxide:

[0039] a) 0.2 g of graphene oxide and 0.2 g of 3-aminophenylboronic acid were ultrasonically dispersed in toluene, heated to 100° C. for reflux reaction for 6 hours, suction filtered and washed to obtain 3-aminophenylboronic acid-modified graphene oxide;

[0040] b) Take 0.1 g of 3-aminophenylboronic acid-modified graphene oxide obtained in step a) and 1 g of triglycidyl isocyanurate in 100 mL of N,N-dimethylformamide, heat to 150° C. for reflux reaction for 24 h, Filter and wash to obtain highly dispersed modified graphene oxide.

[0041] (2) Preparation of highly dispersed modified graphene oxide composite anti-corrosion coatings

[0042] Take 1g of highly dispersed modified graphene oxide prepared in step (1), 50g epoxy resin, 0.5g silicone, 0.2g defoamer BYK302, 0.5g dispersant BYK101, 0.5g ethylene glycol phenyl ether, 20g 1, 4-Butanediol diglycidyl ether is mixed, uniformly dispersed on a high-speed ...

Embodiment 2

[0044] (1) prepare highly dispersed modified graphene oxide;

[0045] With embodiment 1.

[0046] (2) Prepare highly dispersed modified graphene oxide composite anticorrosion coating;

[0047] The mass of highly dispersed modified graphene oxide in Example 1 was adjusted to 0.5g.

Embodiment 3

[0049] (1) prepare highly dispersed modified graphene oxide;

[0050] With embodiment 1.

[0051] (2) Prepare highly dispersed modified graphene oxide composite anticorrosion coating;

[0052] The mass of highly dispersed modified graphene oxide in Example 1 was adjusted to 1.5 g.

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Abstract

The invention discloses high-dispersion modified graphene oxide, a preparation method thereof and anticorrosive paint prepared from high-dispersion modified graphene oxide. The method comprises the following steps: 3-aminobenzeneboronic acid modified graphene oxide is prepared from graphene oxide and 3-aminobenzeneboronic acid through a reaction; high-dispersion modified graphene oxide is preparedfrom triglycidyl isocyanurate and 3-aminobenzeneboronic acid modified graphene oxide through a reaction. Modified graphene oxide has good stability and high dispersion. High-dispersion modified graphene oxide is further uniformly dispersed with matrix resin, a leveling agent, an antifoaming agent, a dispersing agent, a coalescing agent and a diluent, and the anticorrosive paint is obtained and isgood in anticorrosive performance and long in service life. The process is simple, environmentally friendly, efficient and suitable for industrial production.

Description

technical field [0001] The invention belongs to the technical field of paint preparation, and provides a highly dispersed modified graphene oxide, a preparation method thereof and an anti-corrosion paint. Background technique [0002] Corrosion protection plays a prominent role in the modern metalworking industry. A large amount of data shows that corrosion has caused great losses to the national economy and industrialization development. Among them, marine ship corrosion accounts for a large part. Ship corrosion causes a lot of waste to the hull and becomes a potential safety hazard. As a new type of two-dimensional material, graphene has attracted widespread attention due to its excellent physical and chemical properties. Graphene's large specific surface area, excellent electrical and optical properties make it an attractive prospect in various fields. When graphene is applied to anti-corrosion coatings, graphene has the functions of physical isolation and electronic co...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09D163/00C09D133/00C09D127/12C09D5/08C09D7/62
CPCC09D5/08C09D7/62C09D127/12C09D133/00C09D163/00C08K9/04C08K3/042
Inventor 戴李宗王世成许一婷李敏李奕奕王宏超张泓袁丛辉何凯斌刘新瑜罗伟昂
Owner XIAMEN UNIV
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