A kind of anti-blue light resin lens and preparation method thereof

A resin lens and anti-blue light technology, which is applied in optics, optical components, optical components, etc., can solve the problems of high cost of lenses, low pass rate of lenses, and low output, etc., to increase the three-dimensional network structure and increase the absorption rate of blue light , Improve the effect of cross-linking degree

Active Publication Date: 2020-03-24
JIANGSU CONANT OPTICS +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

With the progress of society and the development of science and technology, people's living standards are getting higher and higher. In order to solve the above problems at the same time, many people choose to wear glasses with anti-blue light performance. The blue light feature is achieved by coating the surface of the lens with an anti-blue light film. This kind of lens is expensive and the output is not high. The processing and production are unstable, the sustainability is not strong, and the film is easy to fall off.
[0003] There are also blue light absorbers added in the production process to directly produce anti-blue light lenses, but according to the existing technology, only conventional myopia resin lenses can be produced, and the pass rate of old light resin lenses and module semi-finished products is very low. This is because Diethylene glycol diallyl carbonate itself is highly brittle. After high-temperature curing, the curing furnace is opened. When encountering low-temperature air, the old light and the module will automatically break in the curing furnace.
Moreover, when the mold is opened, for the high-gloss old light and high-curvature modules, the edge is relatively thin, and the edge is particularly prone to cracking. The mold opening is more brittle when the temperature is lowered, and the cracked edge is larger and sticks to the mold, which leads to a lens pass rate. Not high, production cost becomes larger

Method used

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  • A kind of anti-blue light resin lens and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0028] Diethylene glycol allyl carbonate and its polymer mixture (manufactured by ACOMN, product code RAV7NG) are selected as the resin monomer, and 2-hydroxy-4-methoxybenzophenone (UV-9) is selected as the blue light absorber , the polymerization initiator is tert-butyl peroxide 2-ethylhexyl carbonate, the modifier A is polyurethane acrylate, and the modifier B is trimethylolpropane trimethacrylate (HANNONGCHEMICAL CO., LTD, CAS No. 3290-92-4).

[0029] Weigh 20Kg of RAV7NG monomer, 200g of 2-hydroxy-4-methoxybenzophenone (UV-9), mix well, heat up to 60°C, add 2-ethylhexyl peroxide after the blue light absorber is completely dissolved 300g of tert-butyl carbonate, 200g of urethane acrylate, and 300g of trimethylolpropane trimethacrylate. Stir for 2 hours at room temperature and a vacuum of 0.1MPa, continue stirring for 10 minutes after filtering through a 0.1μm filter element, vacuumize for 40 minutes under a vacuum of 0.1MPa, and pour the prepared material into the containe...

Embodiment 2

[0031] Diethylene glycol allyl carbonate and its polymer mixture (manufactured by ACOMN, product code RAV7NG) are selected as resin monomers, and benzophenone-based ultraviolet absorbers 2,2'-dihydroxy-4, 4'-dimethoxybenzophenone (BP-6) and indole blue light absorber 2-cyano-3-(1-methyl-2-phenylmethylacrylate) indole, polymerization initiator Use tert-amyl peroxide 2-ethylhexyl carbonate, epoxy acrylate as modifier A, and pentaerythritol triacrylate (HANNONG CHEMICAL CO., LTD, CAS No. 3524-68-3) as modifier B.

[0032] Weigh 20Kg of RAV7NG monomer, 280g of 2,2'-dihydroxy-4,4'-dimethoxybenzophenone, 2-cyano-3-(1-methyl-2-phenylacrylate methyl ester ) Indole 20g, mix well, heat up to 60°C, after the blue light absorber is completely dissolved, add 400g of tert-butyl peroxide 2-ethylhexyl carbonate, 160g of polyurethane acrylate, and 180g of trimethylolpropane triacrylate. Stir evenly under vacuum at room temperature and at room temperature and a vacuum of 0.1MPa for 2 hours, fi...

Embodiment 3

[0034] Resin monomer selects diethylene glycol allyl carbonate and its multimer mixture (PPG company, product code name is LS), and benzophenone UV absorber selects 2-hydroxyl-4-octyloxybenzophenone ( UV-531), polymer initiator selects tert-amyl peroxide 2-ethylhexyl carbonate, modifier A selects epoxy acrylate, modifier B selects trimethylolpropane triacrylate (HANNONGCHEMICAL CO., LTD, CAS No. 15625-89-5).

[0035]Weigh 20Kg of LS monomer, 240g of 2-hydroxy-4-octyloxybenzophenone (UV-531), mix well, heat up to 60°C, add 420g of 2-ethyl peroxide after the blue light absorber is completely dissolved Hexyl tert-amyl carbonate, 180g of epoxy acrylate, 260g of trimethylolpropane triacrylate, stir evenly in a sealed vacuum at room temperature, stir for 2 hours at room temperature and a vacuum of 0.1MPa, filter through a 0.1μm filter element and continue stirring 10 minutes, evacuated for 40 minutes under the condition of vacuum degree of 0.1MPa, poured vertically, poured the prep...

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Abstract

The invention discloses an anti-blue light resin lens and a preparation method thereof. The lens comprises a resin monomer, a blue light absorber, a polymerization initiator and a modifier, wherein the modifier is an acrylic modifier, and the weight accounts for the 0.1%‑5.0% of the total lens weight. The thermal curing molding in the lens preparation process is carried out by combining an air curing furnace and a water curing furnace. The formula described in the invention can not only improve the blue light absorption rate but also ensure the quality of the lens, improve the yield and save production cost. The modifier used can increase the reaction degree, increase the three-dimensional network structure, increase the toughness of the lens, and improve the qualified rate of the lens , while considering the reaction speed and shrinkage, refractive index and Abbe number, while the lens is toughened, its optical performance is guaranteed. The preparation method of the present invention adopts a specific curing mode, so that the edge cracking problem of old optical resin lenses and module semi-finished products is greatly improved, and the qualified rate is greater than 95%.

Description

technical field [0001] The invention belongs to the field of resin lenses, and more specifically relates to an anti-blue resin lens and a preparation method thereof. Background technique [0002] In visible light, blue light is a kind of short-wave light with high energy and high energy. Blue light can easily penetrate the lens of the glasses and reach the retina, causing photochemical damage to the eyes and rapidly accelerating the oxidation of the macular area of ​​the eye. The process can cause great damage to the eyes, leading to symptoms such as dry eyes, eye astringency and eye soreness, and can also cause fundus damage after cataract surgery. Blue light can inhibit the secretion of melatonin, disturb sleep, and increase the incidence of major diseases. With the progress of society and the development of science and technology, people's living standards are getting higher and higher. In order to solve the above problems at the same time, many people choose to wear gla...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08F283/00C08F222/14C08F218/00C08F283/10G02B5/22G02C7/10
CPCG02C7/10G02B5/223C08F283/008C08F283/105C08F218/24C08F222/103
Inventor 王传宝严清波鲍余雷杜秋黄添鸟鲁渊刘心标曹根庭
Owner JIANGSU CONANT OPTICS
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