243 results about "Trimethylolpropane triacrylate" patented technology

The invention discloses an aluminum substrate UV matt finish paint and a preparation process thereof, and relates to the technical field of paints.The aluminum substrate UV matt finish paint is prepared from, by mass, 10%-20% of modified polyurethane acrylate, 25%-32% of high-functionality aliphatic polyurethane acrylate, 18%-30% of special modified epoxy acrylate resin, 0.5%-2% of dispersing agent, 0.1%-0.5% of defoaming agent, 1%-3% of anti-settling powder and the balance water. The paint is prepared from the following components in percentage by weight: 10 to 15 percent of magnesium silicate mineral, 1 to 10 percent of matting powder, 0.2 to 1 percent of 1-hydroxycyclohexyl phenyl ketone, 0.5 to 3 percent of trimethylbenzoyl-diphenyl phosphine oxide, 1 to 3 percent of acrylate flatting agent, 0.2 to 1.2 percent of polyurea modified polyurethane rheological agent and 5 to 15 percent of trimethylolpropane triacrylate. According to the UV matte finishing paint disclosed by the invention, through compounding of ternary resin and enhancement of nano silicon dioxide, a rigid and tough cross-linked network is constructed, a paint film is free of cracks when being bent at 180 degrees, the adhesive force reaches grade 0, and a coating is resistant to acid and alkali etching liquid and free of corrosion by cooperating with a silane coupling agent and a light stabilization system, and the color difference is delta Elt after the UV matte finishing paint is subjected to high temperature of 260 DEG C; and 1.5, the anti-yellowing performance is excellent.

The invention discloses an energetic slurry toughening and photocuring 3D printing method, relates to a preparation method of energetic slurry, and aims to solve the problems that an existing energetic material is poor in mechanical property, poor in toughness and easy to crack; the particles are fast to settle in the light-cured resin, the stability is poor, and the printing precision is poor. The invention develops a photocuring high-energy resin for photopolymerization additive manufacturing. The composition contains a high-energy filler, an acrylate adhesive, whiskers and an inert plasticizer. The material has the characteristics of compatibility, printability and mechanical property, and the possibility of printing increasingly complicated high-energy articles is proved through experiments. The preparation method of the light-cured resin comprises the following steps: adding the low polymer bisphenol A epoxy acrylate and the six-functionality polyurethane acrylate; diluting monomers including 1, 6-hexanediol diacrylate and trimethylolpropane triacrylate; uniformly mixing an auxiliary agent, a thickening agent and a dispersing agent, and magnetically stirring for 30 minutes to obtain the light-cured resin. A preparation method of the energetic slurry comprises the following steps: mixing light-cured resin, whiskers, an inert plasticizer, energetic particles, a photoinitiator and a light absorber, and uniformly stirring to obtain the energetic slurry; after the energetic slurry is used for 3D printing, a sample piece is obtained, the yield reaches 95%-100%, the cost is low, preparation is easy, and the method can be applied to the field of energetic slurry 3D printing.

The invention relates to an ultra-low VOC baking type quick-drying coating and a preparation method thereof, and belongs to the technical field of coatings. The coating is prepared from the following components: composite hybrid resin, methylated melamine formaldehyde resin, neopentyl glycol diglycidyl ether, trimethylolpropane triacrylate, composite filler, zinc fatty acid, fumed silica, a silane coupling agent KH-560, aminoethyl aminopropyl polydimethylsiloxane and the like. The composite hybrid resin is prepared by adopting a special method; the composite hybrid resin is matched with methylated melamine formaldehyde resin, neopentyl glycol diglycidyl ether, trimethylolpropane triacrylate, a composite filler, zinc fatty acid, fumed silica, a silane coupling agent KH-560, aminoethyl aminopropyl polydimethylsiloxane and other components according to a certain proportion for use, and has the advantages of low VOC emission, quick drying during baking, high heat resistance, high heat resistance, high heat resistance, high heat resistance, high heat resistance, high heat resistance and the like. Meanwhile, the adhesive force is good, the hardness and the flexibility are balanced, and the chemical resistance is excellent.

The invention discloses a UV-cured high-weather-resistance optical thin film and a preparation method thereof, and relates to the technical field of optical thin films. The optical film is prepared by taking polyethylene glycol terephthalate as a base material and coating the base material with a UV curing coating, and the UV curing coating comprises the following raw materials in parts by weight: 15-20 parts of aliphatic polyurethane acrylate, 5-8 parts of perfluorobutyl ethyl acrylate, 8-12 parts of hydroxyethyl acrylate, 6-10 parts of 1, 2, 4-trimethyl-1, 3-pentanediol monoisobutyrate, 1-3 parts of 1, 2, 4-trimethyl-1, 3-pentanediol monoisobutyrate, 1-3 parts of 1, 2, 4-trimethyl-1, the invention relates to a UV (ultraviolet)-resistant coating which is prepared from the following raw materials in parts by weight: 1-2 parts of 2, 6-hexanediol diacrylate, 5-8 parts of trimethylolpropane triacrylate, 30-40 parts of modified epoxy acrylate, 1-2 parts of a silane coupling agent KH-570, 2-3 parts of a photoinitiator 1173, 0.5-1.2 parts of a modified ultraviolet absorbent UV-327, 0.8-1.5 parts of a hindered amine light stabilizer 540, 0.3-0.8 part of an antioxidant 1010, 0.09-0.12 part of an ultraviolet absorbent Tinuvin400 and 0.2-0.5 part of polyether modified polydimethylsiloxane. According to the UV-cured high-weather-resistance optical thin film, polyethylene glycol terephthalate is used as a base material, key raw materials such as a UV-cured coating with a scientific formula, modified epoxy acrylate and the like are finely prepared, a two-stage curing process is adopted, and the weather resistance is excellent.

The invention discloses nano UV light-cured printing ink and a preparation method thereof, and relates to the technical field of printing ink preparation. The nano UV light-cured printing ink is prepared from nano UV light, the invention discloses a UV (ultraviolet) photoinitiator, which is prepared from the following raw materials in parts by weight: 20 to 40 parts of polyurethane acrylate oligomer, 15 to 30 parts of modified bisphenol A type epoxy acrylate, 10 to 15 parts of tripropylene glycol diacrylate, 5 to 10 parts of ethoxylated trimethylolpropane triacrylate, 5 to 15 parts of modified nano titanium dioxide, 3 to 8 parts of nano silver wire, 2 to 5 parts of photoinitiator 1173 and 1 to 3 parts of benzoin dimethyl ether. The invention relates to a silver-loaded zirconium phosphate composite material which is prepared from the following components in parts by weight: 0.5-2 parts of polyether modified polydimethylsiloxane, 0.3-1 part of a defoaming agent, 1-3 parts of a dispersing agent, 1-5 parts of silver-loaded zirconium phosphate, 0.5-2 parts of an antioxidant 1010, 0.5-2 parts of a coupling agent KH-550 and 10-25 parts of propylene glycol methyl ether acetate. The raw materials are scientifically proportioned and contain various modified components, and parameters of each step are clear. The preparation method is reasonable in process, the performance of the ink is improved through multi-step modification, and the obtained ink is good in dispersity and compatibility, high in curing efficiency and excellent in comprehensive performance and has good practicability and innovativeness.

Provided are a wide-temperature-range solid-state electrolyte, a preparation method thereof and use thereof in solid-state lithium metal batteries. The preparation method includes: dissolving a lithium salt and a magnesium salt in a solvent to obtain a mixed salt solution; and mixing the mixed salt solution with an ammonia fluoride solution, subjecting a resulting mixture to reaction, and subjecting a resulting reaction product to centrifugation, washing, and drying in sequence to obtain magnesium-doped lithium fluoride nanoparticles; and mixing the magnesium-doped lithium fluoride nanoparticles, a liquid plasticizer, a polymer monomer and a thermal initiator to obtain a liquid precursor, and subjecting the liquid precursor to curing to obtain the wide-temperature-range solid-state electrolyte, where the polymer monomer is a mixture of ethoxylated trimethylolpropane triacrylate and hexafluorobutyl methacrylate.

The invention discloses a protective adhesive film for sealing and testing a semiconductor and a preparation method of the protective adhesive film, and relates to the technical field of adhesives. The protective adhesive film is obtained by taking a modified acrylate monomer as a main body, taking a synthetic product of 2-hydroxypyridine and methacryloyl chloride as a modifier, taking trimethylolpropane triacrylate as a cross-linking agent and adding maleic anhydride modified modified chitosan and modified polyimide in a polymerization film forming process. The modified acrylate monomer is obtained by taking graphene oxide modified by vinyl trimethoxy silane and hollow glass beads modified by methacryloxy propyl trimethoxy silane as heat conducting fillers; the modified polyimide is obtained by adding a boron nitride nanosheet modified and acidified by amino acrylic acid as a heat-conducting reinforcing filler into a polyimide prepolymer and then carrying out imidization. The mechanical property, heat conduction efficiency and low-temperature brittleness of the protective adhesive film can be improved.

The invention belongs to the technical field of UV ink formula design and digital printing application, and particularly relates to scratch-resistant UV ink, a preparation method thereof and application of the scratch-resistant UV ink to digital printing. The scratch-resistant UV ink comprises the following raw materials in parts by weight: 15-25 parts of epoxy acrylate; 10 to 20 parts of polyurethane acrylate; 15 to 25 parts of a bifunctional monomer; 5-10 parts of a monomer with three functional groups and more than three functional groups; 3 to 5 parts of an alpha-hydroxy ketone photoinitiator; 2 to 4 parts of an acyl phosphorus oxide photoinitiator; 2 to 5 parts of organically modified nano silicon dioxide; 0.1 part to 0.5 part of a flatting agent; 0.5 to 1.5 parts of a dispersing agent; 10 to 15 parts of pigment; the bifunctional monomer is tripropylene glycol diacrylate; the monomer with three functional groups and more than three functional groups is trimethylolpropane triacrylate. The ink has pencil hardness greater than or equal to 3H and excellent flexibility, the adhesive force on substrates such as PC, PET, metal and the like reaches 0 level, the printing process is simplified, and the ink is suitable for digital printing in various scenes.

The invention provides temperature-sensitive ink suitable for various printing modes, a preparation method thereof and a printed product. The ink is prepared from the following raw materials in percentage by mass: 15 to 45 weight percent of aromatic polyurethane acrylic resin, 5 to 45 weight percent of modified epoxy acrylic resin, 5 to 10 weight percent of ethoxylated trimethylolpropane triacrylate, 5 to 10 weight percent of 1, 6-hexanediol diacrylate, 5 to 10 weight percent of tetrahydrofuran acrylate, 5 to 10 weight percent of acryloyl morpholine, 5 to 10 weight percent of co-initiator, 0.5 to 1.5 weight percent of polyethylene wax, 4 to 10 weight percent of photosensitizer, 0.5 to 1.5 weight percent of heat stabilizer and 5 to 15 weight percent of calcium carbonate. According to the invention, the resin which is easy to yellow in a high-temperature environment is added into the formula, and the excessive and active photosensitizer is combined, so that the coating can obtain an excellent temperature band color change effect and an irreversible color change effect under a high-temperature condition.

The invention discloses an acrylic polymer emulsion film-forming agent, which is prepared from the following raw materials in parts by weight: 70 to 80 parts of pre-emulsion I, 40 to 60 parts of pre-emulsion II, 60 to 70 parts of emulsifier solution, 5 to 10 parts of initiation solution I and 10 to 15 parts of initiation solution II. The trifunctional ethoxylated trimethylolpropane triacrylate and the hard monomer are used as crosslinking monomers to form a network structure prepolymer I with relatively high crosslinking density, so that the film-forming property of the seed coating agent can be improved. And the acrylate monomer containing the tertiary carbon structure and the soft monomer can form a linear prepolymer II, and in an alkaline environment, ester groups can be protected, the hydrolysis rate can be reduced, and the alkali resistance can be improved. The film-forming property and alkali resistance of the polymer are further improved, so that the polymer can still stably exist in water-rich and alkaline soil, and active ingredients are slowly released for seeds to use. And the prepared seeds are not adhered and clustered after being coated, so that large-scale seeding is facilitated.

The invention relates to the technical field of optical functional film manufacturing, in particular to a multi-layer structure of a high-light-transmittance composite brightness enhancement film and a processing method of the multi-layer structure, and the multi-layer structure sequentially comprises a surface hardening layer, a high-refractive-index composite layer, a light diffusion layer, a conductive functional layer, a microstructure layer and a bonding layer from a light incident side to a light emergent side; the surface hardening layer is composed of fluorine-containing modified polyethylene glycol terephthalate (PET), the high-refractive-index composite layer comprises a composite layer of rutile type nano titanium oxide particles and methyl phenyl silicone resin, and the light diffusion layer is a cross-linked layer formed by mixing bisphenol A type epoxy acrylate and trimethylolpropane triacrylate according to the mass ratio of 4.2: 1. The conductive functional layer is an indium tin oxide (ITO) thin film, the microstructure layer is a prism array layer formed by nickel template imprinting, the optical performance of the film is remarkably improved, and the light transmittance of the wavelength of 550 nm reaches 93.5%-93.8% through the optical matching design of the composite structure and is improved by 3-5% compared with similar products.

The invention discloses a method for determining trimethylolpropane triacrylate in cosmetics, which comprises the following steps: S1, weighing a sample, adding anhydrous sodium sulfate, adding ethyl acetate, carrying out vortex mixing uniformly, then carrying out ultrasonic treatment to obtain a sample mixture, carrying out centrifugal treatment on the sample mixture, taking a supernatant, mixing the supernatant with a purifying agent, carrying out vortex treatment, then carrying out centrifugal treatment, and collecting the supernatant; taking supernate and filtering to obtain to-be-detected liquid for later use; s2, GC-MS (gas chromatography-mass spectrometry) determination: determining the content of trimethylolpropane triacrylate in the to-be-detected liquid prepared in the step S1 through a gas chromatography-mass spectrometry method. According to the method, the technical blank in the related detection field is filled, effective technical support is provided for customs departments, a scientific basis is provided for detection of trimethylolpropane triacrylate in import and export cosmetics, and supervision of the cosmetic market is facilitated.

The invention provides a skin-touch coating for a glass substrate and a preparation method of the skin-touch coating. The skin-touch coating is prepared from the following components in parts by weight: 30 to 50 parts of modified acrylic resin, 2 to 5 parts of trimethylolpropane triacrylate, 0.2 to 1 part of flatting agent, 0.2 to 1 part of defoaming agent, 0.5 to 1.5 parts of curing agent, 5 to 10 parts of adhesive agent and 10 to 30 parts of deionized water. The prepared skin-touch coating can improve the adhesive force, pencil hardness and ultraviolet aging resistance of a glass substrate, and the skin-friendly smooth surface also brings better skin-touch experience to a user.

This invention relates to the field of packaging film technology and provides a low-temperature polyolefin packaging film and its preparation method. The packaging film comprises a three-layer co-extruded structure consisting of an outer layer, a middle layer, and an inner layer. The components of each layer are as follows: Inner layer: metallocene polyolefin, high-performance polypropylene, modified lignin nanofibers, and erucamide / silica composite microspheres; Middle layer: PCR, modified nano-kaolinite, and trimethylolpropane triacrylate; Outer layer: PCR, modified tourmaline nanotubes, benzoyl peroxide microcapsules, and polydopamine-coated chitosan. This invention uses PCR, which is more energy-efficient and environmentally friendly. The addition of modified lignin nanofibers to the inner layer improves tensile strength; the addition of modified nano-kaolinite to the middle layer improves thermal shrinkage; the addition of modified tourmaline nanotubes to the outer layer lowers the crosslinking reaction initiation temperature and improves shrinkage; and the addition of polydopamine-coated chitosan allows for reversible recombination upon damage, improving puncture strength.

The invention discloses a raw material for preparing a pressure-sensitive adhesive, the pressure-sensitive adhesive and a preparation method of the pressure-sensitive adhesive, relates to the technical field of high polymer materials, and aims to solve the problem of poor compactness due to low density of the pressure-sensitive adhesive. Wherein the raw materials for preparing the pressure-sensitive adhesive comprise the following materials in parts by weight: 25 to 35 parts of polyether polyol, 26.5 to 36.5 parts of isocyanate, 17 to 23 parts of hydroxypropyl methacrylate, 7 to 13 parts of acid functional group acrylate, 2 to 2.6 parts of nano silicon dioxide, 4 to 6 parts of trimethylolpropane triacrylate, 1.5 to 2.5 parts of a photoinitiator and 0.8 to 1.2 parts of a silane coupling agent.

The invention discloses a preparation method of antibacterial enhanced ABS (acrylonitrile-butadiene-styrene) plastic, and relates to the field of ABS plastic. A hyperbranched polylactic acid network and an ABS matrix form an interpenetrating structure, and molecular chain slippage is jointly inhibited by a cross-linking point of trimethylolpropane triacrylate and a physical enhancement effect of nano SiO2, so that the tensile strength and the impact strength of the material are improved; bacterial cell membranes are destroyed through a quaternary ammonium salt group with positive electricity, synthesis of fungal cell walls is interfered and formation of biological membranes is inhibited through boric acid molecules, hypha colonization is physically hindered through high crosslinking density of a hyperbranched PLA network, and therefore the bacteriostasis rate on bacteria and fungi is increased.

The present invention relates to the field of photoresist technology, and more particularly to an aqueous liquid photosensitive photoresist and a preparation method thereof. The aqueous liquid photosensitive photoresist comprises the following raw materials, in parts by weight: 50-70 parts of an acrylic resin emulsion, 2-5 parts of a monomer composition, 8-12 parts of ethoxylated trimethylolpropane triacrylate, 3-6 parts of a photoacid generator, 0.5-1.5 parts of a thickener, 1-3 parts of a modified perfluoropolyether carboxylic acid ammonium, 0.2-0.4 parts of an anti-cratering agent, and 20-24 parts of deionized water. The aqueous liquid photosensitive photoresist prepared by the present invention has excellent etching resistance and high resolution, and the preparation method is simple.

The invention relates to an ultrahigh-temperature and high-salinity water shutoff system and a preparation method and application thereof, and belongs to the field of oilfield water shutoff systems, and the ultrahigh-temperature and high-salinity water shutoff system comprises the following substances in parts by weight: 8-10 parts of 2-acrylamido-2-methylpropanesulfonic acid, 6-10 parts of N-vinyl caprolactam, 6-8 parts of N-isopropylacrylamide and 4-6 parts of monostearyl maleate. The invention relates to a water-based adhesive which is prepared from the following components in parts by weight: 6 to 10 parts of 2-acrylamido-2-methylpropanesulfonic acid, 3 to 5 parts of dimethylaminoethyl methacrylate, 0.2 to 0.4 part of dimethyl 2-butenedioate trimethylolpropane triacrylate, 3 to 5 parts of modified nanoscale silicon dioxide, 2 to 4 parts of modified nanoscale calcium carbonate and 100 to 120 parts of deionized water. The plugging agent provided by the invention can still maintain good plugging performance in an oil reservoir environment in which the underground temperature of an oil field exceeds 120 DEG C and / or the degree of mineralization is higher than 100000mg / L, so that the plugging efficiency of a water seepage layer of an oil well in the oil field is ensured.

The invention discloses high-stripping solvent-free waterborne polyurethane synthetic leather and a preparation method thereof, and relates to the technical field of polyurethane synthetic leather, the high-stripping solvent-free waterborne polyurethane synthetic leather comprises a component A and a component B according to a weight part ratio of 100: (30-40), the component A is prepared from the following components in parts by weight: 40 to 70 parts of polyhydric alcohol, 25 to 40 parts of diisocyanate, 5 to 8 parts of hydrophilic chain extender, 6 to 10 parts of amino grafted polytetrahydrofuran ether glycol, 0 to 1.5 parts of foaming agent, 0 to 3 parts of trimethylolpropane triacrylate and 0.12 to 0.25 part of catalyst; and the component B is polyester modified MDI, and the content of-NCO is 12 to 15 weight percent. The bonding strength is remarkably improved through the components of the component A and the component B, the process is simple, the catalytic effect of the catalyst is effectively controlled, and therefore the purpose of remarkably improving the peel strength of the synthetic leather is achieved.

The invention discloses an industrial packaging coating integrating anti-counterfeiting, antibacterial and pathogen detection functions and a preparation method thereof, and relates to the technical field of industrial packaging coatings. The coating is prepared from modified polyurethane acrylate, ethyoxyl ethyoxyl ethyl acrylate, 1, 6-hexanediol diacrylate, hydroxyethyl methylacrylate, trimethylolpropane triacrylate, epsilon-polylysine, carbon quantum dot-microencapsulated spiropyrane, a water-based flatting agent, 2, 4, 6-trimethyl-1, 3-pentanediol diacrylate, a water-based curing agent, a defoaming agent, a defoaming agent and a solvent. The cleaning agent is prepared from 2, 4, 6-trimethylbenzoyl diphenyl phosphine oxide, a dispersing agent, lauryl sodium sulfate, pathogen microcapsules and ethyl acetate. The three functions of anti-counterfeiting, antibiosis and pathogen detection are integrated into a single coating, the limitation that a traditional packaging material is single in function is broken through, the anti-counterfeiting reliability is improved, no harmful substance is migrated out, and efficient pathogen screening is achieved; safety standards are met, harmful substance migration is avoided, and the base material is matched with various base materials such as films and fibers and is mechanically strengthened.

Multiphase polymers comprising crosslinking monomers and polyfunctional amine are disclosed. The multiphase polymer comprises a first phase polymer having a Tg from 60° C. to 240° C., a second phase polymer having a Tg from 40° C. to 240° C., and a soft phase polymer having a Tg from −25° C. to 30° C. The crosslinking monomers include a triacrylate such as trimethylol propane triacrylate, an unsaturated alkoxysilane, and an unsaturated keto monomer reactive with the polyfunctional amine. In contrast to conventional knowledge, incorporation of trimethylolpropane triacrylate reduces the minimum film forming temperature of multiphase polymers. This unusual reduction in MFFT helps to reduce the VOC requirement to form a good film at low VOC. The other crosslinking monomers including unsaturated alkoxy silane and unsaturated keto monomer which react with the polyfunctional amine improve print resistance, block resistance and lower the tackiness of paint films. The multiphase polymer is particularly suitable for use in deep base paints.

The invention discloses a waterproof UV (ultraviolet) curing coating and a preparation method thereof, trimethylolpropane triacrylate is used as a reactive diluent, 2-hydroxy-2-methyl-1-phenylacetone is used as a photoinitiator, polyurethane acrylate and modified filler are polymerized in the UV curing process of the coating, and a highly crosslinked waterproof UV curing coating is prepared. A perfluorocarbon chain structure and a hydrogen bond network are introduced into a polyurethane acrylate molecular chain, a molecular-level smooth super-hydrophobic layer is formed on the surface of the coating, and permeation of water molecules can be effectively blocked. The modified filler taking microcrystalline wax as a core and silicon dioxide as a shell is added, so that the wear resistance and scratch resistance of the coating can be remarkably improved, and meanwhile, the micro rough structure and the coating with low surface energy cooperatively construct a super-hydrophobic structure, so that the waterproof performance of the UV curing coating is improved.

The invention relates to an oily liquid absorbing and storing agent which is selected from one of corn starch and cassava starch. The preparation method comprises the following steps: selecting proper macromolecular resin as a framework material: one or more than one of polypropylene, polystyrene and polymethyl methacrylate; one of benzoyl peroxide, azodiisobutyronitrile and dibenzoyl peroxide is selected; triphenyl phosphate or Lewis acid is commonly used, so that the process of generating free radicals by the initiator can be accelerated; the solvent is one of vinyl benzene, trimethylolpropane triacrylate and dimaleimide; one of sodium dodecyl benzene sulfonate and lauryl sodium sulfate can be selected. The invention also discloses a method.

The present application belongs to the technical field of cable material, and particularly relates to a resin composition, a cable insulation material, a cable and a preparation method. The resin composition comprises polyethylene, a crosslinking agent and a crosslinking aid. The crosslinking agent is selected from one or more of triallyl isocyanurate, trimethylolpropane trimethacrylate and trimethylolpropane triacrylate. The crosslinking aid is selected from one or more of triphenyl phosphite, dipropylene glycol diacrylate and tetraethylene glycol diacrylate. The cable insulation material made of the resin composition has a high irradiation crosslinking rate, which can significantly improve the irradiation processing speed of the subsequent cable and improve the cable output efficiency. In addition, the cable insulation material has good aging resistance, can meet the long service life requirement, saves the cable update cost and has good economic benefits.

The invention relates to the technical field of photoresist materials, in particular to a super-thick dry film photoresist for copper cylinder electroplating and a preparation method of the super-thick dry film photoresist. The super-thick dry film photoresist is prepared from 38 to 48 parts of modified polyurethane acrylate, 12 to 18 parts of a first active diluent, 5 to 10 parts of a second active diluent, 5 to 10 parts of a plasticizer, 3 to 8 parts of a photoinitiator, 0.5 to 1.5 parts of a flatting agent and 0.1 to 0.3 part of a de-foaming agent, the second active diluent is trimethylolpropane triacrylate; the photoresist can form a super-thick and defect-free film layer, the adhesive force, the electroplating liquid corrosion resistance, the pattern resolution and other properties of the film layer are all improved, and the strict requirements of the copper cylinder electroplating process are met.

The invention relates to the field of matte ink, in particular to UV ink fountain matte varnish and a preparation method thereof. The DAPA resin is prepared from the following raw materials in percentage by weight: DAPA resin, a UV active diluting monomer, a photoinitiator, a functional monomer, a polymerization inhibitor, a matting material and the balance of a processing aid, the UV active diluting monomer is composed of one or more of triethylene glycol diacrylate, acryloyl morpholine and vinyl caprolactam; the functional monomer is composed of one or more of 15 (ethyoxyl) trimethylolpropane triacrylate, propoxylated neopentyl glycol diacrylate and 2, 2 '-diallyl bisphenol A, and the functional monomer is composed of one or more of 15 (ethyoxyl) trimethylolpropane triacrylate, propoxylated neopentyl glycol diacrylate and 2, 2'-diallyl bisphenol A; the matting material is composed of a hand feeling matting agent, wax powder and organic silicon bentonite according to the weight ratio of 18: (0.3-1.3): (3-5), and by compounding the raw materials, the wear resistance and matt effect of the matt varnish are enhanced.

This invention belongs to the field of packaging and printing materials, specifically relating to a high-temperature resistant water-based micro-crosslinked transfer coating. The raw materials for this high-temperature resistant water-based micro-crosslinked transfer coating consist of the following components: methacrylic acid, N-hydroxymethylacrylamide, butyl acrylate, methyl methacrylate, diallyl phthalate, 1,6-hexanediol diacrylate, tricyclodecanedimethylol diacrylate, trimethylolpropane triacrylate, di(trimethylolpropane)tetraacrylate, potassium persulfate, sodium bicarbonate, alkylphenol polyoxyethylene ether ammonium sulfate, nonylphenol polyoxyethylene ether, deionized water, ethanol, ammonia, wetting agent, defoamer, and film-forming agent. Its beneficial effects include a stable reaction process during the preparation of this high-temperature resistant water-based micro-crosslinked transfer coating, reducing the likelihood of slag formation or explosive polymerization; high gloss in the coating film; good adhesion to vacuum metallization; minimal fogging or whitening; high-temperature molding resistance up to 180℃; and easy peeling of PET film with a high yield.

This invention relates to a laser-engravable high-gloss black coating for automotive taillights and its preparation method, belonging to the field of coating preparation technology. The formulation of the laser-engravable high-gloss black coating is as follows (by weight): 40-60 parts polyurethane acrylate, 3-5 parts modified nano-bismuth oxide, 3-5 parts trimethylolpropane triacrylate, 1-3 parts 4-methylbenzophenone, 1-2 parts carbon black, and 0.5-1.5 parts leveling agent. The modified nano-bismuth oxide is prepared by treatment with ammonium molybdate solution and grafting with a silane coupling agent. Its layered structure synergistically enhances UV absorption efficiency and weather resistance with the molybdate layer. 4-methylbenzophenone and modified nano-bismuth oxide form a light absorption composite system, which, combined with the high cross-linking density network constructed by trimethylolpropane triacrylate, achieves narrow linewidth laser engraving precision. This invention solves the technical problems of low laser engraving precision, poor adhesion, and insufficient solvent resistance in traditional high-gloss black coatings, and is particularly suitable for precision marking applications such as automotive taillights.

The invention relates to the technical field of high polymer material synthesis, and particularly discloses hydrophobic fluorosilicone microgel and a preparation method thereof. The invention relates to a high-temperature-resistant acrylic resin, which is prepared from the following ingredients in parts by weight: 3.54 to 8.96 parts of perfluorooctyl ethyl acrylate, 0.96 to 4.05 parts of functional ingredients, 2.94 to 9.99 parts of methyl acrylate, 4.48 to 11.09 parts of butyl acrylate, 1.01 to 2.56 parts of trimethylolpropane triacrylate, 0.39 to 0.99 part of azodiisobutyronitrile and 65.0 to 85.0 parts of butyl acetate. According to the hydrophobic fluorosilicone microgel and the preparation method thereof, a coating can be endowed with good hardness and wear resistance, a fluorocarbon chain segment is introduced, the coating can be endowed with good anti-fouling and anti-fingerprint performance, functional components (isocyanate active functional groups or siloxane active groups) are introduced, the coating can be endowed with excellent adhesive force to a base material, and the hydrophobic fluorosilicone microgel can be applied to the coating. The contradiction between the antifouling property and the adhesive force is balanced.

The application belongs to the technical field of paint coating, and particularly relates to a high-stability UV and moisture dual-curing three-protection paint and a preparation method thereof, which comprises, based on the total amount of raw materials, 25.5-77.9 wt% of 3,3,5-trimethylcyclohexyl acrylate, 20-54 wt% of polyurethane acrylate with an isocyanate group, 1-8.5 wt% of an auxiliary stable crosslinking agent, 0.1-5 wt% of a dehydrating agent, and 1-7 wt% of a photoinitiator; the weight ratio of the polyurethane acrylate to the 3,3,5-trimethylcyclohexyl acrylate and the auxiliary stable crosslinking agent is 1:(1.10-1.40):(0.05-0.30); and the auxiliary stable crosslinking agent is selected from trimethylolpropane triacrylate and / or trimethylolpropane trimethacrylate. The application has the properties of UV and moisture dual curing, and has high stability and can resist acid and alkali environments.