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A method for preparing high-performance powder metallurgy products by coating alloy powder with organic matter

An alloy powder and powder metallurgy technology, which is applied in the field of organic-coated alloy powder to prepare high-performance powder metallurgy products, can solve the problems of low oxygen content, poor mechanical properties of alloy parts, increased cost, etc. performance, the effect of reducing pores

Active Publication Date: 2019-12-17
UNIV OF SCI & TECH BEIJING
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

When applying these processes, easily oxidized alloy powders, such as titanium, magnesium, copper, neodymium iron boron and other powders, are easy to react with oxygen due to their large surface energy, and the increase in oxygen content during the forming process leads to poor mechanical properties of the formed alloy parts , especially the finer the titanium alloy powder, the larger the specific surface area, and the more serious the oxygen increase, which will lead to oxidation when placed in the air at room temperature
Generally, injection molding and 3D printing have low oxygen content requirements for easily oxidized alloy powder raw materials, which leads to increased costs, and in the forming process, measures such as controlling the production conditions such as the forming atmosphere, temperature and sintering environment are generally used to control the oxygen of the alloy powder.
[0004] The current oxygen control methods for easily oxidized alloy powders mainly focus on the increase of oxygen and carbon in the process of processing, and seldom carry out surface modification on alloy powders.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment example 1

[0021] A stearic acid coated TC4 titanium alloy powder for gel casting.

[0022] (1) Prepare the coating solution: dissolve 25g of stearic acid in 500ml of dichloromethane, stir evenly, and prepare an organic coating solution with a solution concentration of 0.05g / ml;

[0023] (2) Powder coating: according to the mass percentage, the quality of the organic coating is 0.1% of the mass of the TC4 titanium alloy powder, weigh 100 g of the hydrogenated dehydrogenation TC4 titanium alloy powder of 45 μm, and measure the organic coating in step (1). Solution 200ml, mix the solution and titanium alloy powder evenly, so that the solution soaks all the powder, and the whole process is carried out under an argon atmosphere in a glove box;

[0024] (3) Powder treatment: Put the coated powder in a vacuum drying oven and dry at 30°C for 90 minutes, then take it out, put the dried coated powder into a ball mill jar and fill it with argon for atmosphere protection, Then the ball mill jar is...

Embodiment example 2

[0028] A pure copper powder coated with polyethylene glycol for compression molding.

[0029] (1) Prepare the coating solution: dissolve 10 g of polyethylene glycol in 1000 ml of water, stir evenly, and prepare an organic matter coating solution with a concentration of 0.01 g / ml;

[0030] (2) Powder coating: according to the mass percentage, the mass of the organic coating is 0.5% of the mass of the pure copper powder, weigh 50 g of 25 μm water atomized pure copper powder, and measure the organic coating solution in step (1) 25ml, add 100ml of deionized water to the weighed organic solution, then mix the solution with the titanium alloy powder evenly, so that the solution soaks all the powder, and the whole process is carried out under an argon atmosphere in a glove box;

[0031] (3) Powder treatment: Put the coated powder in a vacuum drying oven and dry it at 40°C for 90 minutes, then take it out, put the dried coated powder into a ball mill jar and fill it with argon for atm...

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Abstract

The invention provides a method for preparing high-performance powder metallurgy products by coating alloy powder with organic matter, which belongs to the field of powder metallurgy. The method of solution coating is used to coat a layer of organic film on the surface of the alloy powder, and the organic matter is dissolved in a solvent to form a liquid film on the surface of the alloy powder. After the solvent is removed, the organic matter can be evenly coated on the alloy powder without any chemical reaction. , Coating a layer of organic film on the surface of the alloy powder to achieve the purpose of isolating the easily oxidizable alloy powder from oxygen. The surface energy of easily oxidized alloy powder is large and easy to react with oxygen, and the increase of oxygen content in the forming process leads to poor mechanical properties of the formed alloy parts. The use of organic coating can effectively achieve the effect of oxygen control in the forming process, and in the forming process The coating treatment in the process can improve the oxidation resistance of the alloy powder, which is beneficial to maintain a low oxygen content and excellent mechanical properties after forming.

Description

technical field [0001] The invention belongs to the field of powder metallurgy and provides a method for preparing high-performance powder metallurgy products by coating alloy powder with organic matter. Background technique [0002] Powder materials in powder metallurgy, especially particles with smaller particle sizes, are easily oxidized due to their small size effect resulting in increased surface active sites, large specific surface area, and large specific surface energy. For oxygen-sensitive metal materials, when the metal powder is oxidized, the oxygen content of the raw material will increase, which will not only affect the press-formability of the powder, but also seriously affect the various properties of the final product. Taking titanium alloy as an example, the plasticity of titanium alloy will drop sharply with the increase of oxygen content. When the oxygen content increases from 0.3% to 0.4%, the elongation will drop from more than 10% to about 3%. Therefor...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B22F1/00B22F3/16
CPCB22F3/16B22F2998/10B22F2999/00B22F1/102B22F3/1007B22F2201/11B22F3/02B22F2009/043
Inventor 杨芳邵艳茹张策芦博昕郭志猛隋延力冯钊红陆天行李沛
Owner UNIV OF SCI & TECH BEIJING