Polyaniline-containing polyaspartate polyurea anti-corrosive paint and preparation method thereof

An aspartate and anti-corrosion coating technology, applied in anti-corrosion coatings, polyurea/polyurethane coatings, coatings, etc., can solve the problems of short anti-corrosion life, short gel time, short pot life, etc., and achieve chemical corrosion resistance. The effect of excellent performance, excellent corrosion resistance and excellent weather resistance

Inactive Publication Date: 2018-09-21
BEIHUA UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Traditional anti-corrosion coatings are mostly solvent-based coatings, which have the disadvantages of large VOC emissions, environmental pollution, and short anti-corrosion life. Therefore, in order to meet the special anti-corrosion requirements of emerging marine engineering, modern transportation, energy industry, large chemical enterprises, and municipal facilities , it is urgent to develop a new type of heavy-duty anti-corrosion coating
[0003] Traditional aromatic polyurea coatings are prone to yellowing and fading when used outdoors, the reaction speed is too fast, the gel time is short (3s~5s), the wetting ability to the substrate is weak, the adhesion is poor, and the application period is too short. A series of problems such as the use of special equipment for construction

Method used

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  • Polyaniline-containing polyaspartate polyurea anti-corrosive paint and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0027] 1) Preparation of component A: 90g polyaspartate resin F-520, 90g polyaspartate resin F-524, 16g propylene glycol methyl ether acetate, 8g intrinsic state polyaniline, 80g titanium dioxide , 60g mica powder, 40g zinc oxide, 5g organic bentonite, 5g ultraviolet absorber UV-0, 2g defoamer BYK-066N, 2g leveling agent BYK-354 and 2.5g wetting and dispersing agent BYK161, placed in the dispersing machine in turn Internal dispersion, the linear speed of the agitator in the disperser is above 15m / s, after mixing, add glass beads as the grinding medium, use a sand mill to grind to a fineness of ≤40um, filter and pack to obtain component A;

[0028] 2) Component B curing agent: weigh 100g-105g of aliphatic polyisocyanate N-3200 produced by Bayer as component B;

[0029] 3) Stir the above components A and B evenly before use to obtain a polyaniline-containing polyaspartate polyurea anticorrosion coating.

Embodiment 2

[0031] 1) Preparation of component A: 60g polyaspartate resin F-520, 100g polyaspartate resin F-524, 20g propylene glycol methyl ether acetate, 8g intrinsic state polyaniline, 80g titanium dioxide , 15g carbon black, 60g precipitated barium sulfate, 40g mica powder, 5g polyamide wax, 5g ultraviolet absorber UV-9, 2g defoamer BYK-A530, 2g leveling agent BYK-352 and 2.5g wetting and dispersing agent BYK -164, placed in the disperser in order to disperse, the linear speed of the agitator in the disperser is above 15m / s, after mixing, add glass beads as the grinding medium, use a sand mill to grind to a fineness of ≤40um, filter and pack, Get A component;

[0032] 2) Component B curing agent: weigh 85g~90g of aliphatic polyisocyanate N-3600 produced by Bayer Company as component B;

[0033] 3) Stir the above components A and B evenly before use to obtain a polyaniline-containing polyaspartate polyurea anticorrosion coating.

Embodiment 3

[0035] 1) Preparation of component A: 60g polyaspartate resin F-520, 100g polyaspartate resin F-420, 20g propylene glycol methyl ether acetate, 10g intrinsic polyaniline, 90g titanium dioxide , 10g carbon black, 40g zinc oxide, 40g mica powder, 20g precipitated barium sulfate, 5g organic bentonite, 5g ultraviolet absorber UV-24, 2g defoamer BYK-A530, 2g leveling agent BYK-358N and 2.5g wetting Dispersant BYK9077 is placed in the disperser in turn for dispersion. The linear speed of the agitator in the disperser is above 15m / s. After mixing, add glass beads as the grinding medium, use a sand mill to grind to a fineness of ≤40um, filter and pack , get A component;

[0036] 2) Component B curing agent: weigh 85g~90g of aliphatic polyisocyanate N-3200 produced by Bayer Company as component B;

[0037] 3) Stir the above components A and B evenly before use to obtain a polyaniline-containing polyaspartate polyurea anticorrosion coating.

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Abstract

The invention provides polyaniline-containing polyaspartate polyurea anti-corrosive paint and a preparation method thereof and belongs to the technical field of anti-corrosive paint. The paint is prepared from a component A and a component B, wherein the component A is prepared from polyaspartate resin, a solvent, eigenstate polyaniline, pigment, functional filler, a thixotropic agent, an ultraviolet absorbent and additives; and the component B is a curing agent. The preparation method comprises the following steps: preparing the component A; weighing the component B; respectively packaging the component A and the component B; and uniformly mixing the component A with the component B before use under the condition that the molar ratio of the hydroxyl group-OH of the component A to the isocyanate group-NCO of the component B is (1.0-1.2):1.0 so as to obtain the paint provided by the invention. The paint has excellent weather resistance, adhesive force and chemical corrosion resistance,the solid content reaches 90% or above, zero VOC emission or ultra-low VOC emission is realized, the required film thickness can be obtained by construction once, the construction frequency is reduced, the working efficiency is improved, the construction period is shortened, and the cost is greatly reduceed.

Description

technical field [0001] The invention belongs to the technical field of anticorrosion coatings, in particular to polyaniline-containing polyaspartate polyurea anticorrosion coatings and a preparation method thereof. Background technique [0002] At present, the economic loss caused by corrosion of metal materials in our country is relatively serious every year, accounting for about 5% of the gross national product, causing a large number of infrastructure equipment to be scrapped, which has become the most important cause of equipment loss. my country's current corrosion loss is higher than that of developed countries, and it is generally accepted internationally that the loss caused by marine corrosion is far greater than the loss caused by natural disasters. From the perspective of the economics of anti-corrosion treatment, the use of anti-corrosion coatings is the most economical and effective method. Traditional anti-corrosion coatings are mostly solvent-based coatings, ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09D175/02C09D179/02C09D5/08
CPCC08L2205/025C08L2205/03C09D5/08C09D175/02C08L75/02C08L79/02
Inventor 王岩
Owner BEIHUA UNIV
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