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Pretreatment process for gold extraction of gold ore

A pretreatment and gold mine technology, which is applied in the field of pretreatment process for gold extraction from gold mines, can solve the problems of potential safety hazards, impact on gold recovery, high operating costs, etc., to reduce production costs and environmental pressure, reduce sulfur dioxide production, The effect of convenient storage, transportation and sales

Inactive Publication Date: 2018-09-21
NORTHEASTERN UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The disadvantages are: ① release a large amount of SO 2 、As 2 o 3 and other toxic and harmful gases; ②The furnace gas dust collection and purification device is complicated, the operation cost is high, and the environment is seriously polluted; ③The process operation requirements are strict, and it is easy to cause "under-burning" or "over-burning", resulting in incomplete decomposition of sulfides or secondary packaging Gold, which affects the recovery rate of gold
The disadvantages are: high requirements on equipment, high temperature and high pressure, and potential safety hazards; high maintenance costs; strict process control conditions, and the elemental sulfur solution produced by the reaction wraps gold again, which affects gold recovery; it is not suitable for ores containing gold and carbon
The disadvantages are: the pretreatment time is long; the adaptability to raw materials is not strong, and it is not suitable for processing ores with high arsenic content and gold and carbon content
The disadvantages are: large amount of waste water, difficult treatment; poor adaptability to raw materials, not suitable for processing materials containing gold, carbon, arsenic and sulfur; large consumption of reagents; difficult recovery of arsenic, sulfur and other base metals

Method used

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  • Pretreatment process for gold extraction of gold ore

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0050] In this example, a refractory gold ore in Guangxi was selected, and the gold was encapsulated in sulfide in a fine-grained disseminated state. The specific operation steps and process parameters used in this example are as follows: take 100 grams of this refractory gold ore for crushing, ball milling and powdering, the particle size is less than 0.074mm, accounting for 95%, put it into a corundum crucible and put it into a closed heating furnace, pass nitrogen gas Oxygen-free roasting was carried out, the roasting temperature was controlled at 900°C, and the roasting time was 0.5 hours. The flue gas produced by roasting is cooled to obtain a sulfur-containing product, and the roasting slag is mixed with sulfuric acid for slurrying, and the weight ratio of liquid to solid is controlled to be 8:1. Sodium lignosulfonate was used as the agent, and the slurry after sizing was placed in a reactor for leaching. The leaching temperature was controlled to be 165 °C, the total pr...

Embodiment 2

[0055] In this example, a refractory gold ore in Yunnan is selected. The gold is in the form of fine-grained dissemination and is wrapped in sulfide and contains carbon with gold robbing effect. %, carbon 3.2%, arsenic 4.1%, antimony 1.1%. The specific operation steps and process parameters used in this example are as follows: take 100 grams of this refractory gold ore for crushing, ball milling and powdering, the particle size is less than 0.074mm, accounting for 65%, and place it in a heating furnace and pass into argon for roasting, and the roasting temperature is controlled at 750℃, calcination time is 3 hours. The flue gas produced by roasting is cooled to obtain sulfur-containing products, and the roasting residue is mixed with acid to make pulp. Calcium acid, the slurry after sizing is placed in the reactor for leaching, the leaching temperature is controlled to be 145°C, the total pressure is 1.3MPa, the partial pressure of oxygen is 0.7MPa, and the concentration of s...

Embodiment 3

[0060] In this example, a refractory gold ore in Liaoning was selected, and the gold was encapsulated in sulfide in a fine-grained disseminated state. The specific operation steps and process parameters adopted in this example are as follows: take 100 grams of this refractory gold ore for crushing, ball milling and powdering, the particle size is less than 0.074mm, accounting for 50%, and place it in a heating furnace and pass into hydrogen for roasting, and the roasting temperature is controlled at 550 ℃ ℃, the calcination time is 4 hours. The flue gas produced by roasting is cooled to obtain hydrogen sulfide and other products, and the roasting residue is mixed with acid to make pulp, and the weight ratio of liquid to solid is controlled to be 0.5:1, the concentration of sulfuric acid is 50g / L, and 0.1% of the weight of roasting residue is added. The desulfurizer lignin Potassium sulfonate, the slurry after sizing is placed in the reactor for leaching, the leaching temperatu...

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Abstract

The invention relates to a pretreatment process for gold extraction of gold ore, in particular to combined pretreatment of anaerobic roasting and medium-temperature oxygen leaching for the refractorygold ore. The pretreatment process particularly comprises the steps that S1, the gold ore is crushed, ball-milled and powdered to obtain gold ore powder; S2, the gold ore powder is placed in an oxygen-free gas atmosphere to be roasted to obtain a roasting slag and a flue gas; S3, the roasting slag is mixed with an acid and a desulfurizing agent for pulping, the pulped slurry is subjected to temperature control, pressurization, oxygenation and oxidative leaching in a reaction vessel to obtain a base metal leaching solution and a leaching slag; S4, the leaching slag is subjected to desulfurization and purification, and then a gold leaching agent is used for the gold extraction. The pretreatment process for the gold extraction of the gold ore has the advantages that the advantages of a roasting method and pressure leaching method are combined while avoiding the shortcomings of the roasting method and pressure leaching method, the raw material adaptability is high, the operating conditionsand equipment requirements are lower, and the environmental and economic benefits are remarkable.

Description

technical field [0001] The invention relates to a pretreatment process for gold extraction from gold ore, and belongs to the technical field of gold extraction. Background technique [0002] With the increasing use of gold and the increasing consumption, the easy-to-leach gold ores are decreasing day by day. The low-grade, arsenic-containing, organic carbon-containing, and fine-grained refractory metallurgical ores have become the main raw materials for gold production in my country. The reason why this kind of ore is difficult to extract gold is mainly manifested in: fine-grained gold or sub-microscopic gold exists in the sulfide ores in the form of encapsulation or dissemination, and the main gold-carrying sulfides are pyrite and arsenopyrite; It preferentially adsorbs the carbonaceous matter of gold, so that the gold is adsorbed by the carbonaceous matter during the cyanation process and cannot enter the solution. Therefore, it is necessary to pretreat such refractory ores...

Claims

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Application Information

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IPC IPC(8): C22B1/02C22B3/08C22B11/00C01B17/06C01B17/16
CPCC01B17/06C01B17/165C22B1/02C22B3/08C22B11/04Y02P10/20
Inventor 陈国宝路远航
Owner NORTHEASTERN UNIV