A kind of organic fluorine-containing industrial detergent and preparation method thereof

Abstract

The invention discloses an industrial detergent containing organic fluorine and a preparation method of the industrial detergent and belongs to the technical field of detergents. The industrial detergent containing organic fluorine comprises the following raw materials: a soap base, dodecylbenzene sulfonic acid, fatty alcohol-polyoxyethylene ether, cocoanut fatty acid diethanolamide, sodium citrate, sodium tripolyphosphate, carboxymethylcellulose, sodium silicate, 10% NaOH, NaCl, a fluorescent whitening agent, 10% 4-amino-3,5-dichloro-6-fluoro-pyridyl-2-sodium oxyacetate, deionized water, gibbsite-type aluminum hydroxide particles, benzoyl peroxide and sodium lignin sulfonate; and the industrial detergent containing organic fluorine is prepared by the steps such as mixing and stirring. The detergency and oil-water separation property of the industrial detergent containing organic fluorine are improved by taking the gibbsite-type aluminum hydroxide particles, benzoyl peroxide and sodium lignin sulfonate as reinforcing systems.

Description

technical field

[0001] The invention belongs to the technical field of detergents, and in particular relates to an industrial detergent containing organic fluorine and a preparation method thereof. Background technique

[0002] Among the existing various detergents, surfactants play a major role. The active principle is: in the molecular RH-X structure, RH is a hydrocarbon hydrophobic group, and X is a hydrophilic group. The compound of this structure can reduce the surface tension of its solution (generally an aqueous solution) and change the interface state of the system. When its solution reaches a certain concentration (carboxymethyl cellulose), micelles will be produced in the solution, thereby producing wetting, emulsification, foaming, solubilization and washing. At present, the formulas and relevant standards of various detergents at home and abroad stipulate that the content of surfactants should not be less than 10% for non-ionic types and not less than 15% for an...

Examples

preparation example Construction

[0027] The preparation method of said organic fluorine-containing industrial detergent comprises the following steps:

[0028] S1: prepare 10% NaOH, 10% 4-amino-3,5-dichloro-6-fluoro-pyridine-2-oxyacetic acid sodium solution for standby;

[0029] S2: Soap base, dodecylbenzenesulfonic acid, fatty alcohol polyoxyethylene ether, coconut oil fatty acid diethanolamide, sodium citrate, sodium tripolyphosphate, sodium silicate, 10% NaOH, NaCl, fluorescent Brightener, 10% 4-amino-3,5-dichloro-6-fluoro-pyridine-2-oxyacetic acid sodium, deionized water, sodium lignosulfonate are fully mixed, add carboxymethyl cellulose, The gibbsite type aluminum hydroxide particles are fully stirred and mixed;

[0030] S3: Add benzoyl peroxide and stir thoroughly, then store in a cool place.

Embodiment 1

[0032]An industrial detergent containing organic fluorine, comprising the following raw materials in parts by weight: 2 parts of soap base, 2 parts of dodecylbenzenesulfonic acid, 1.5 parts of fatty alcohol polyoxyethylene ether, 0.5 parts of coconut oil fatty acid diethanolamide 10 parts of sodium citrate, 5 parts of sodium tripolyphosphate, 1 part of carboxymethyl cellulose, 10 parts of sodium silicate, 2 parts of 10% NaOH, 1 part of NaCl, 0.1 part of fluorescent whitening agent, 10% 0.06 parts of sodium 4-amino-3,5-dichloro-6-fluoro-pyridine-2-oxoacetate, 65 parts of deionized water, 2 parts of gibbsite-type aluminum hydroxide particles, 0.03 parts of benzoyl peroxide 3 parts, 3 parts of sodium lignosulfonate. .

[0033] The primary particle diameter of the gibbsite-type aluminum hydroxide particles is 0.01 μm-0.3 μm.

[0034] The fluorescent whitening agent is bistriazine aminostilbene.

[0035] The soap base is formed by reacting sodium hydroxide and olive oil in water...

Embodiment 2

[0041] An industrial detergent containing organic fluorine, comprising the following raw materials in parts by weight: 1 part of soap base, 3 parts of dodecylbenzenesulfonic acid, 1 part of fatty alcohol polyoxyethylene ether, and 1 part of coconut oil fatty acid diethanolamide 5 parts of sodium citrate, 7 parts of sodium tripolyphosphate, 0.5 parts of carboxymethyl cellulose, 15 parts of sodium silicate, 1 part of 10% NaOH, 1.5 parts of NaCl, 0.05 parts of fluorescent whitening agent, 10% of 0.09 parts of sodium 4-amino-3,5-dichloro-6-fluoro-pyridine-2-oxoacetate, 60 parts of deionized water, 3 parts of gibbsite-type aluminum hydroxide particles, 0.02 parts of benzoyl peroxide , 4 parts of sodium lignosulfonate. .

[0042] The primary particle diameter of the gibbsite-type aluminum hydroxide particles is 0.01 μm-0.3 μm.

[0043] The fluorescent whitening agent is bistriazine aminostilbene.

[0044] The soap base is formed by reacting sodium hydroxide and palm oil in water....

technical field

[0001] The invention belongs to the technical field of detergents, and in particular relates to an industrial detergent containing organic fluorine and a preparation method thereof. Background technique

[0002] Among the existing various detergents, surfactants play a major role. The active principle is: in the molecular RH-X structure, RH is a hydrocarbon hydrophobic group, and X is a hydrophilic group. The compound of this structure can reduce the surface tension of its solution (generally an aqueous solution) and change the interface state of the system. When its solution reaches a certain concentration (carboxymethyl cellulose), micelles will be produced in the solution, thereby producing wetting, emulsification, foaming, solubilization and washing. At present, the formulas and relevant standards of various detergents at home and abroad stipulate that the content of surfactants should not be less than 10% for non-ionic types and not less than 15% for an...

Examples

preparation example Construction

[0027] The preparation method of said organic fluorine-containing industrial detergent comprises the following steps:

[0028] S1: prepare 10% NaOH, 10% 4-amino-3,5-dichloro-6-fluoro-pyridine-2-oxyacetic acid sodium solution for standby;

[0029] S2: Soap base, dodecylbenzenesulfonic acid, fatty alcohol polyoxyethylene ether, coconut oil fatty acid diethanolamide, sodium citrate, sodium tripolyphosphate, sodium silicate, 10% NaOH, NaCl, fluorescent Brightener, 10% 4-amino-3,5-dichloro-6-fluoro-pyridine-2-oxyacetic acid sodium, deionized water, sodium lignosulfonate are fully mixed, add carboxymethyl cellulose, The gibbsite type aluminum hydroxide particles are fully stirred and mixed;

[0030] S3: Add benzoyl peroxide and stir thoroughly, then store in a cool place.

Embodiment 1

[0032]An industrial detergent containing organic fluorine, comprising the following raw materials in parts by weight: 2 parts of soap base, 2 parts of dodecylbenzenesulfonic acid, 1.5 parts of fatty alcohol polyoxyethylene ether, 0.5 parts of coconut oil fatty acid diethanolamide 10 parts of sodium citrate, 5 parts of sodium tripolyphosphate, 1 part of carboxymethyl cellulose, 10 parts of sodium silicate, 2 parts of 10% NaOH, 1 part of NaCl, 0.1 part of fluorescent whitening agent, 10% 0.06 parts of sodium 4-amino-3,5-dichloro-6-fluoro-pyridine-2-oxoacetate, 65 parts of deionized water, 2 parts of gibbsite-type aluminum hydroxide particles, 0.03 parts of benzoyl peroxide 3 parts, 3 parts of sodium lignosulfonate. .

[0033] The primary particle diameter of the gibbsite-type aluminum hydroxide particles is 0.01 μm-0.3 μm.

[0034] The fluorescent whitening agent is bistriazine aminostilbene.

[0035] The soap base is formed by reacting sodium hydroxide and olive oil in water...

Embodiment 2

[0041] An industrial detergent containing organic fluorine, comprising the following raw materials in parts by weight: 1 part of soap base, 3 parts of dodecylbenzenesulfonic acid, 1 part of fatty alcohol polyoxyethylene ether, and 1 part of coconut oil fatty acid diethanolamide 5 parts of sodium citrate, 7 parts of sodium tripolyphosphate, 0.5 parts of carboxymethyl cellulose, 15 parts of sodium silicate, 1 part of 10% NaOH, 1.5 parts of NaCl, 0.05 parts of fluorescent whitening agent, 10% of 0.09 parts of sodium 4-amino-3,5-dichloro-6-fluoro-pyridine-2-oxoacetate, 60 parts of deionized water, 3 parts of gibbsite-type aluminum hydroxide particles, 0.02 parts of benzoyl peroxide , 4 parts of sodium lignosulfonate. .

[0042] The primary particle diameter of the gibbsite-type aluminum hydroxide particles is 0.01 μm-0.3 μm.

[0043] The fluorescent whitening agent is bistriazine aminostilbene.

[0044] The soap base is formed by reacting sodium hydroxide and palm oil in water....

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