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Dehydration process of the fluoro-rubber

A fluorine rubber and process technology, applied in the field of synthetic polymer chemistry and organic chemistry, can solve the problems of fluorine rubber, such as yellowing and darkening, unstable operation of equipment, and damage to product quality, to achieve full contact, large specific heat capacity, and difficulty in condensation and moisture return Effect

Active Publication Date: 2018-10-19
SICHUAN HOT PULSE MICROWAVE SCI & TECH CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0009] Although the above-mentioned prior art has realized faster continuous drying, there is still the problem of high local temperature, which will also cause the fluororubber to release a large amount of highly corrosive hydrofluoric acid, hydrogen chloride, etc., making the fluororubber yellowish and darker. Quality decline; at the same time, it will cause damage to the equipment, especially the corrosion of the extrusion screw of the main equipment, which will not only make the equipment unable to operate stably, but also cause a large amount of corroded metal impurities to be introduced into the material, seriously damaging the product quality

Method used

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  • Dehydration process of the fluoro-rubber

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1~4

[0054] The fluororubber with Mooney viscosity of 5-10 is selected and processed according to the fluororubber dehydration process described in the present invention.

[0055] Soak the fluororubber wet material in an ion-free water system; the temperature of the ion-free water system is 40-140° C., and the pressure of the ion-free water system is 0-3 bar g.

[0056] Water has a large specific heat capacity and high fluidity, so it can be used as a good heat transfer medium, so as to balance the material temperature well and prevent local overheating; fluororubber has very high requirements on purity, and solutes in ordinary water may contaminate the material. After drying, these solutes will remain in the material, which is like scale in layman's terms; at the same time, the material contains residual hydrofluoric acid, hydrogen chloride, and other impurities, etc., which are harmful components, and they dissolve in water to become corresponding ions , the use of ion-free water...

Embodiment 5~8

[0064] Fluorine rubber with a Mooney viscosity of 10-39 is selected and processed according to the dehydration process of the fluorine rubber described in the present invention.

[0065] Soak the fluororubber wet material in an ion-free water system; the temperature of the ion-free water system is 40-140° C., and the pressure of the ion-free water system is 0-3 bar g.

[0066] Then it is put into the calendering equipment for roller calendering, and calendering obtains a thin sheet with a thickness of 0.2-3.0 mm; the calendering equipment is placed in an ion-free water system; the temperature of the ion-free water system is 40 ° C ~ 140 ° C, the The pressure of the ion-free water system is 0-3 bar g.

[0067] Finally, put the flakes into the microwave drying equipment for drying, and dry for 1-10 minutes to obtain the finished fluorine rubber; during the drying process, feed microwaves into the microwave drying equipment, and at the same time, pass hot dry air into the microwa...

Embodiment 9~12

[0070] Fluorine rubber with a Mooney viscosity of 61-100 is selected and processed according to the dehydration process of the fluorine rubber described in the present invention.

[0071] Soak the fluororubber wet material in an ion-free water system; the temperature of the ion-free water system is 40-140° C., and the pressure of the ion-free water system is 0-3 bar g.

[0072] Then it is put into the calendering equipment for roller calendering, and the calendering obtains a sheet with a thickness of 0.2-3.0 mm; the calendering equipment is placed in an ion-free water system; the temperature of the ion-free water system is 40 ° C ~ 140 ° C, the The pressure of the ion-free water system is 0-3 bar g.

[0073] Finally, put the flakes into the microwave drying equipment for drying, and dry for 1-10 minutes to obtain the finished fluorine rubber; during the drying process, feed microwaves into the microwave drying equipment, and at the same time, pass hot dry air into the microwa...

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Abstract

The present invention discloses a dehydration process of the fluoro-rubber, which belongs to technical field. The present dehydrating the fluoro-rubber by three steps of: heating and softening in water bath, calendering and dehydrating in water, microwave composite, and drying. Finally obtaining a finished product with a water content of less than or equal to 0.1 wt%. At the same time, according to the method of dehydration process of the fluoro-rubber, the gasification dehydration level is low, the strength is low, the energy is saved, the drying efficiency is high, the speed is fast, and thecycle is short. The low-strength and rapid drying can effectively prevent material discoloration and quality degradation. The fluoro-rubber obtained by dehydrating in the invention has low moisture content less than or equal to 0.1 wt%, its color is pure white without yellow, and the application indexes such as tensile strength and elongation are superior to the conventional drying.

Description

technical field [0001] The invention relates to a fluororubber dehydration process, which belongs to the technical field of organic chemistry, and specifically relates to the fluororubber treatment technology in the technical field of synthetic polymer chemistry. Background technique [0002] Fluorine rubber refers to a synthetic polymer elastomer in which fluorine atoms are connected to carbon atoms in the main chain or side chain. This type of new polymer material has the characteristics of heat resistance, oil resistance, solvent resistance, strong oxidant resistance, etc., and has good physical and mechanical properties. It has become an indispensable and alternative basic material in modern industry, especially in high-tech fields, and is widely used in national defense. , military industry, aerospace, automobile, petrochemical and many other fields. [0003] At present, more than 60% of the world's fluororubber production is used in the automobile industry. However, w...

Claims

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Application Information

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IPC IPC(8): B29B13/06B29B13/08F26B9/06F26B23/08F26B3/347F26B21/04F26B21/08
CPCB29B13/06B29B13/08F26B3/347F26B9/06F26B21/04F26B21/08
Inventor 周昆游俊曾涛廖丰杰康琪
Owner SICHUAN HOT PULSE MICROWAVE SCI & TECH CO LTD