Preparation method of intensity-improvable glass ceramics

A glass-ceramic and strength technology, which is applied in glass manufacturing equipment, glass molding, manufacturing tools, etc., can solve the problem that the strength cannot be improved well, and temperature control has a great influence on the performance of glass-ceramic, which is not very good, etc. problems, to achieve the effect of improving strength, improving resource utilization, and promoting nucleation and crystallization

A glass-ceramic and strength technology, which is applied in glass manufacturing equipment, glass molding, manufacturing tools, etc., can solve the problem that the strength cannot be improved well, and temperature control has a great influence on the performance of glass-ceramic, which is not very good, etc. problems, to achieve the effect of improving strength, improving resource utilization, and promoting nucleation and crystallization

CN108675640AInactive Publication Date: 2018-10-19合肥钢骨玻璃制品有限公司

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0026] A method for preparing glass-ceramics whose strength can be improved in this embodiment includes the following steps:

[0027] Step 1, take the following raw materials corresponding to the weight percentage for later use: SiO 2 32%, Al 2 o 3 26%, MgO 12%, Fe 2 o 3 0.3%, electrolytic manganese slag 18%, tin phosphorus compound 0.02%, rare earth element 0.01%, strength additive 0.01%;

[0028] Step 2: mix the raw materials in step 1 evenly and put them into a corundum crucible for smelting, then put them into a mold for casting, then anneal, and then cool to room temperature at 20°C / min to obtain the high performance glass-ceramic.

[0029] The preparation method of the electrolytic manganese slag in step 1 of this embodiment is to send the electrolytic manganese slag into a refiner with water for beating, then pickling, and then washing with ethanol until the solution is neutral, and then sending it into a filter press for pressing. Filtration, and then placed in a...

Embodiment 2

[0038] A method for preparing glass-ceramics whose strength can be improved in this embodiment includes the following steps:

[0039] Step 1, take the following raw materials corresponding to the weight percentage for later use: SiO 2 38%, Al 2 o 3 30%, MgO 18%, Fe 2 o 3 0.5%, electrolytic manganese slag 18%, tin phosphorus compound 0.06%, rare earth element 0.05%, strength additive 0.03%;

[0040] Step 2: Mix the raw materials in step 1 evenly and put them into a corundum crucible for smelting, then put them into a mold for casting, then anneal, and then cool to room temperature at 30°C / min to obtain the high performance glass-ceramic.

[0041] The preparation method of the electrolytic manganese slag in step 1 of this embodiment is to send the electrolytic manganese slag into a refiner with water for beating, then pickling, and then washing with ethanol until the solution is neutral, and then sending it into a filter press for pressing. Filtration, and then placed in a...

Embodiment 3

[0050] A method for preparing glass-ceramics whose strength can be improved in this embodiment includes the following steps:

[0051] Step 1, take the following raw materials corresponding to the weight percentage for later use: SiO 2 35%, Al 2 o 3 28%, MgO 15%, Fe 2 o 3 0.4%, electrolytic manganese slag 15%, tin phosphorus compound 0.04%, rare earth element 0.03%, strength additive 0.02%;

[0052] Step 2: Mix the raw materials in step 1 evenly and put them into a corundum crucible for smelting, then put them into a mold for casting, then anneal, and then cool to room temperature at 25°C / min to obtain the high performance glass-ceramic.

[0053] The preparation method of the electrolytic manganese slag in step 1 of this embodiment is to send the electrolytic manganese slag into a refiner with water for beating, then pickling, and then washing with ethanol until the solution is neutral, and then sending it into a filter press for pressing. Filtration, and then placed in a...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

PropertyMeasurementUnit
particle size (mesh)aaaaaaaaaa
Login to View More

Abstract

The invention discloses a preparation method of intensity-improvable glass ceramics. The method comprises the following step of 1, weighing the following raw materials in corresponding percentage by weight for later use: 32 to 38 percent of SiO2, 26 to 30 percent of Al2O3, 12 to 18 percent of MgO, 0.3 to 0.5 percent of Fe2O3, 14 to 18 percent of electrolytic manganese residue, 0.02 to 0.06 percentof tin phosphorus compounds, 0.01 to 0.05 percent of rare earth elements and 0.01 to 0.03 percent of intensity auxiliary agents. The preparation method of the intensity-improvable glass ceramics hasthe advantages that the intensity of the glass ceramics is greatly improved through being compared with that in the prior art; high use values and good application prospects are realized.

Description

technical field [0001] The invention relates to the technical field of glass-ceramics preparation, in particular to a preparation method of glass-ceramics whose strength can be improved. Background technique [0002] Glass-ceramic refers to the addition of some nucleating substances to the glass, and through heat treatment, light irradiation, or chemical treatment, a large number of tiny crystals are uniformly precipitated in the glass to form a multi-phase dense microcrystalline phase and glass phase. Composite, by controlling the types and sizes of crystallites, transparent glass-ceramics, glass-ceramics with zero expansion coefficient, surface-strengthened glass-ceramics, glass-ceramics of different colors or machinable glass-ceramics can be obtained. Composition of glass phase and crystal phase, the distribution of the two changes with their ratio. When the proportion of glass phase is large, the glass phase is a continuous matrix, and the crystal phase is evenly distrib...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
19 Oct 2018
Publication
CN108675640A
IPC
C03C10/00; C03C6/10; C03B19/02
CPC
C03B19/02; C03C1/002; C03C10/0045
Inventors
朱明静