High-resilience closed flame-retardant foam silicon rubber material and preparation method thereof

A technology of flame-retardant foam and silicone rubber, which is applied in the field of high-resilience closed-cell flame-retardant silicone rubber foam and its preparation, and can solve the problem of reducing the shock absorption performance of silicone rubber foam, uneven cell size, and enlarged cells. problem, achieve the effect of reducing cell size, optimizing cell distribution, and reducing cell diameter

Inactive Publication Date: 2018-11-02
JIAXING ZHONGYI CARBON TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The former can be realized at room temperature, the formula is simple, and the products produced are relatively single, and the products are cured by pouring molding or rubber production technology, which is difficult to achieve continuous production, so the product processing performance is poor and the application range is relatively narrow. and niche
Such as Chinese patent CN104559190A discloses a kind of preparation method of two-component foamed silica gel composite material, this method adopts the microcapsule of shell polyvinyl chloride resin to encapsulate isobutane as foaming agent, mix A, B component at room temperature The cross-linking and foaming reaction can be carried out. This invention can effectively solve the problem of poor impact resistance and protection performance of the existing foamed silica gel, but the sample processing performance is poor, and it is difficult to realize continuous production.
Although the method of high-temperature vulcanization and foaming can realize continuous production, it is difficult to match the speed of crosslinking and foaming, and the degree of crosslinking between the surface layer and the interior is inconsistent, which can easily lead to uneven cell size and affect the recovery of samples. Elasticity and other properties, as far as the field of shock absorption is concerned, are far from meeting the needs of the market
Chinese patent CN105331117A uses a mixed gas of air, oxygen and carbon dioxide as a foaming agent. Although the prepared silicone rubber foam cells are relatively uniform, the cells are large, the resilience performance is not good, and the molding process is single, so it can only be used Suitable for industrial injection molding
[0003] In addition, the flame retardancy of silicone rubber foam is generally achieved by adding a large amount of flame retardants. The addition of a large amount of flame retardants will further affect the uniformity of the cells, resulting in larger cells or even broken cells. Significantly reduces the shock-absorbing properties of silicone rubber foam

Method used

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preparation example Construction

[0030] The present invention also provides a preparation method of a high-resilience closed-cell flame-retardant foamed silicone rubber material, which comprises the following steps:

[0031] Step 1. Add 40-60% of silicone rubber, 30-50% of additives, 0.5-2% of foaming agent, 0.5-2% of catalyst, 0.5-2% of inhibitor, and 0.5-1.5% of colorant into the planet by weight percentage In the stirrer, vacuumize and mix at 110°C-160°C for 30-40min, and let the mixture return to room temperature;

[0032] Step 2. Add 1~3% of crosslinking agent to the mixture in the planetary mixer, turn on the cold circulation system, control the temperature at 5°C-10°C, and quickly mix and stir for 10-20 minutes until the mixture is uniform to obtain the spare rubber;

[0033] Step 3: Cover the upper and lower parts of the spare rubber obtained in Step 2 with a layer of polyester film and calender through a double-roller calender, and then enter a high-temperature oven through a conveyor belt, and perfo...

Embodiment 1

[0037]Step 1. Add 40% of silicone rubber, 50% of additives, 2% of foaming agent, 2% of catalyst, 2% of inhibitor and 1% of coloring agent into the planetary mixer by weight percentage, and vacuumize and mix at 110°C for 40 min, let stand until the mixture returns to room temperature;

[0038] Step 2: Add 3% cross-linking agent to the mixture in the planetary mixer, turn on the cold circulation system, control the temperature at 5°C, and quickly mix and stir for 20 minutes until the mixture is evenly mixed to obtain the spare rubber;

[0039] Step 3: Cover the upper and lower parts of the spare rubber obtained in Step 2 with a layer of polyester film and calender through a double-roller calender, and then enter a high-temperature oven through a conveyor belt, and perform normal pressure foaming and vulcanization at 60°C for 15 minutes. The continuous foamed silica gel sheet is rolled to obtain a high-resilience closed-cell flame-retardant foamed silicone rubber material coil. ...

Embodiment 2

[0041] Step 1. Add 60% of silicone rubber, 30% of additives, 2% of foaming agent, 2% of catalyst, 2% of inhibitor, and 1% of coloring agent into the planetary mixer by weight percentage, and vacuumize and mix at 160°C for 30 min, let stand until the mixture returns to room temperature;

[0042] Step 2. Add 3% crosslinking agent to the mixture in the planetary mixer, turn on the cold circulation system, control the temperature at 10°C, and mix and stir quickly for 10 minutes until the mixture is evenly mixed to obtain the spare rubber;

[0043] Step 3: Cover the upper and lower parts of the spare rubber obtained in Step 2 with a layer of polyester film and calender through a double-roller calender, then enter a high-temperature oven through a conveyor belt, and perform normal-pressure foaming and vulcanization at 120°C for 5 minutes to form The continuous foamed silica gel sheet is rolled to obtain a high-resilience closed-cell flame-retardant foamed silicone rubber material co...

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Abstract

The invention discloses a high-resilience closed flame-retardant foam silicon rubber material. The high-resilience closed flame-retardant foam silicon rubber material is prepared from the following components in parts by weight: 40-60% of silicon rubber, 30-50% of additive, 0.5-2% of foaming agent, 1-3% of crosslinking agent, 0.5-2% of catalyst, 0.5-2% of inhibitor and 0.5-1.5% of coloring agent.

Description

technical field [0001] The invention relates to a silicone rubber foam material and a preparation method thereof, in particular to a high-resilience closed-cell flame-retardant silicone rubber foam material and a preparation method thereof. Background technique [0002] Under the background of energy constraints and environmental pollution, various automobile manufacturers also regard new energy vehicles as an important strategic direction to seize the commanding heights of the future automobile industry. As the core part of the entire new energy vehicle, the battery is also particularly important for its environmental sealing and shock-absorbing components. The high-resilience closed-cell flame-retardant silicone rubber foam can not only reduce the external vibration suffered by the battery, but also ensure the safety of the battery under cold and heat cycles. The expansion and contraction of the battery can provide stable performance for a long time, and it can also avoi...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L83/04C08L83/07C08K13/06C08K9/04C08K7/00C08K7/08C08K3/36C08K3/26C08K7/26C08K3/22C08J9/06C08J9/08C08J9/10C08J9/14C08J9/236
CPCC08J9/0066C08J9/0085C08J9/009C08J9/065C08J9/08C08J9/103C08J9/141C08J9/236C08J2203/02C08J2203/04C08J2203/22C08J2205/052C08J2383/04C08J2383/07C08K3/2279C08K3/36C08K7/00C08K7/08C08K7/26C08K9/04C08K13/06C08K2003/2224C08K2003/2227C08K2003/2241C08K2003/265
Inventor 高兰李平
Owner JIAXING ZHONGYI CARBON TECH
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