Nanogold-based NIMPLY logic gate and application thereof in visual detection of DNA
A nano-gold and logic gate technology, applied in the field of analysis and detection, can solve the problems of difficult integration of logic gates and complicated modification process, and achieve the effects of simple and fast preparation process, diversified signal reading, and high detection sensitivity
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Embodiment 1
[0029] (1) Preparation of gold nanoparticles: All glassware used in the following process were soaked in aqua regia, ultrasonicated twice with distilled water, rinsed with ultrapure water, and dried. An aqueous solution of chloroauric acid (0.1 M, 0.25 mL) was mixed with 100 mL of ultrapure water and heated to boiling under reflux under magnetic stirring. Then trisodium citrate solution (1%, 1.5 mL) was quickly added into the mixed solution for reaction under stirring, and the stirring reaction was continued until wine-red nano-gold sol was generated. The reaction solution was gradually cooled to room temperature under stirring, and stored in the dark at 4° C., which could remain relatively stable for at least 20 days. The average particle diameter of the gold nanometer obtained by transmission electron microscopy is 18nm, and the concentration calculated according to Lambert-Beer's law is 0.30nM.
[0030] (2) Construction of NIMPLY logic gate: Add 50 μL of ultrapure water to...
Embodiment 2
[0032] (1) The preparation of nano gold is the same as in Example 1.
[0033] (2) Construction of NIMPLY logic gate: Add 25 μL of DNA with a concentration of 0.8 μg / mL to 25 μL of ultrapure water, react at room temperature for 5 minutes, then add to 450 μL of nano-gold, mix well, and immediately observe with the naked eye, the solution turns red. That is, when the input signal form is (0 / 1), the output signal is 0 (see figure 1 ).
Embodiment 3
[0035] (1) The preparation of nano gold is the same as in Example 1.
[0036] (2) Construction of NIMPLY logic gate: Add 25 μL of ultrapure water to 25 μL of palmatine with a concentration of 90 μM, react at room temperature for 5 minutes, then add to 450 μL of nano-gold, mix well, and immediately observe with the naked eye, the solution turns blue . That is, when the input signal is in the form of (1 / 0), the output signal is 1 (see figure 1 ).
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