Composite structure comprising fabric layer and spherical activated carbon layer and preparation method thereof

A spherical activated carbon, composite structure technology, used in textiles and papermaking, clothing, fiber processing, etc.

Pending Publication Date: 2018-11-09
SHENZHEN GLOBAL GREENLAND NEW MATERIALS CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, practice has proved that the structure of the existing protective clothing is difficult to

Method used

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  • Composite structure comprising fabric layer and spherical activated carbon layer and preparation method thereof
  • Composite structure comprising fabric layer and spherical activated carbon layer and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

preparation example 1

[0107] 1.1 Preparation of spherical polymer matrix

[0108] Add 18 liters of water into a 50-liter polymerization kettle, heat it to 45°C, add 10g of magnesium carbonate, 20g of gelatin and 0.15g of methylene blue under stirring, and add 3kg of methylstyrene and 1kg of dipentamyl olefin and 20g of benzoyl peroxide mixed into the oil phase, then add 1.0kg of paraffin, close the polymerization kettle, feed clean compressed air into the polymerization kettle, and keep the gas phase pressure in the kettle at 0.02MPa. Then, start the stirring, adjust the liquid beads in the kettle to an appropriate particle size, raise the temperature to 80°C, keep the temperature for 12 hours, then raise the temperature to 100°C, keep the temperature for 20 hours, filter, wash, dry and sieve to obtain the white spherical polymer 2.35 kg.

[0109] 1.2 Sulfonation and carbonization

[0110] Mix the spherical polymer obtained in step 1.1 with a mass ratio of 1:1 with concentrated sulfuric acid, the...

preparation example 2

[0120] 2.1 Preparation of spherical polymer matrix

[0121] Add 20 liters of water into a 50 liter polymerization kettle, heat it to 40°C, add 10g of calcium carbonate, 20g of polyvinyl alcohol and 0.15g of petroleum calcium sulfonate under stirring, and add 3kg of styrene and 1kg of isoprene ethylene and 20g of azobisisobutyronitrile mixed into the oil phase, then add 1.6kg of glycerin, close the polymerization kettle, feed clean compressed air into the polymerization kettle, and keep the gas phase pressure in the kettle at 0.04MPa. Then, start stirring, adjust the liquid beads in the kettle to an appropriate particle size, raise the temperature to 80°C, keep it warm for 12 hours, then raise the temperature to 100°C, keep it warm for 20 hours, filter, wash, dry and sieve to obtain a white spherical polymer 2.67 kg.

[0122] 2.2 Sulfonation and carbonization

[0123] The spherical polymer obtained in step 2.1 with a mass ratio of 1:1.5 and SO 3 Mix, then put the mixture int...

preparation example 3

[0133] 3.1 Preparation of spherical polymer matrix

[0134] Add 20 liters of water into a 50-liter polymerization kettle, heat to 40°C, add 12g of magnesium carbonate, 25g of sodium carboxymethylcellulose and 0.18g of calcium dodecylbenzenesulfonate under stirring, and add the 3.6kg divinylbenzene, 1.2kg diethylene glycol divinyl ether and 25g sodium persulfate mixed oil phase, then add 2.2kg sodium carbonate, close the polymerization kettle, feed clean compressed air into the polymerization kettle, Keep the gas phase pressure in the kettle at 0.05MPa. Then, start the stirring, adjust the liquid beads in the kettle to an appropriate particle size, raise the temperature to 90°C, keep the temperature for 9 hours, then raise the temperature to 120°C, keep the temperature for 20 hours, filter, wash, dry and sieve to obtain the white spherical polymer 3.12 kg.

[0135] 3.2 Sulfonation and carbonization

[0136] Add the polymer obtained in step 3.1 into a 50-liter reactor, add 10...

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Abstract

The invention belongs to the technical field of functional fabrics, and particularly relates to a composite structure comprising a fabric layer and a spherical activated carbon layer and a preparationmethod thereof. The composite structure comprising the fabric layer and the spherical activated carbon layer is characterized in that the surface of the fabric layer facing spherical activated carbonis provided with a depression extending from the surface to the inside of the fabric layer; at least part of the outer surface of the spherical activated carbon is bonded to at least part of the inner surface of the depression. By adopting the composite structure, clogging of fabric and difficulty in breathing of skin caused by excessive adhesives can be avoided, and the human body comfort is improved remarkably. Moreover, the composite structure can significantly improve the bonding area of the fabric and the activated carbon, and greatly improve the washing fastness of protective clothing.Moreover, the preparation method of the composite structure and clothing is convenient, and has a broad prospect for large-scale production.

Description

technical field [0001] The invention belongs to the technical field of functional fabrics, in particular to a composite structure comprising a fabric layer and a spherical activated carbon layer and a preparation method thereof. Background technique [0002] With the development of the chemical industry, many highly toxic chemicals have emerged, and the current chemical industry uses a large amount of highly dangerous chemicals. During the production, storage and handling of these toxic chemicals, people's lives will be endangered due to leakage or accidents. In addition, people also face the threat of chemical weapons, biological weapons and terrorism. In 1995, the Japanese cult organization "Akumo Shinrikyo" released sarin gas in the Tokyo subway, which was the first time in human history that chemical warfare agents were used to launch terrorist attacks against civilians. In 2001, the anthrax mail terrorist incident in the United States shocked the world. In the event ...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
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Application Information

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IPC IPC(8): D06M11/74D06M23/00A41D13/00D06M101/32
CPCA41D13/00D06M11/74D06M23/00D06M2101/32
Inventor 常明珠
Owner SHENZHEN GLOBAL GREENLAND NEW MATERIALS CO LTD
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