The invention relates to a concrete mixture for large volume concrete construction in autumn period and a construction method of poured walls thereof. The concrete mixture comprises the following raw materials in parts by weight: 182-218 parts of cement, 775 parts of medium sand, 1048 parts of cobblestones, 170 parts of water, 145-181 parts of a mineral admixture, and 7.8 parts of an additive. The mineral admixture comprises coal ash and slag powder, the usage amount of the coal ash is 39-40% of the usage amount of a gelling material, the gelling material comprises cement and the mineral admixture, the additive comprises a water reducer, a water-proofing agent, and an expanding agent, and the mass ratio of the water reducer to the water-proofing agent to the expanding agent is 5:2:3. The construction method comprises the following steps: preparation before construction, weighing of raw materials, stirring of raw materials, pouring, vibrating and maintenance. Under the prerequisite that concrete strength is guaranteed, double mixing technology is employed, in order to reduce the usage amount of the total gelling material, reduce the absolute usage amount of cement, and improve the usage amount of the admixture; the usage amount of the coal ash in the admixture is improved, in order to reduce hydration heat and adiabatic temperature rise of the concrete, and reduce cracking risk of the concrete.