A kind of extremely thin double-sided adhesive tape and preparation method thereof
A double-sided tape, extremely thin technology, used in adhesives, pressure-sensitive films/sheets, film/sheet-like adhesives, etc. and other problems, to achieve good bonding effect, stickiness and durability, and improve the effect of cohesion
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Embodiment 1
[0042] Embodiment 1, the preparation of modified epoxy resin
[0043] Glycidyl methacrylate, butyl methacrylate and vinyl acetate were subjected to a copolymerization reaction at a temperature of 70° C. for 8 hours, and the weight percentages of glycidyl methacrylate, butyl methacrylate and vinyl acetate were: 22% of glycidyl methacrylate, 46% of butyl methacrylate, 32% of vinyl acetate.
Embodiment 2
[0044] Embodiment 2, the preparation of cationic polyepoxysuccinic acid
[0045] A. maleic anhydride is added to dissolve in water, the molar ratio of maleic anhydride to water is 1:9, sodium hydroxide is added to adjust the pH value to 5~6, to obtain maleic acid solution;
[0046] B. Add sodium tungstate to maleic acid solution, heat to 90°C, and continuously add aqueous hydrogen peroxide solution with a volume concentration of 35%. The amount of aqueous hydrogen peroxide added is the total amount of maleic acid solution 1.5 times the volume, while adding sodium hydroxide to adjust the pH value to 5-6 to obtain sodium epoxy succinate;
[0047] C. Add calcium hydroxide to the sodium epoxysuccinate obtained in step B and polymerize at 100°C for 100 minutes. The weight ratio of sodium epoxysuccinate to calcium hydroxide is 1:0.8, acidify to obtain polyepoxysuccinic acid ;
[0048] D. When the temperature of the polyepoxysuccinic acid obtained in step C is raised to 35°C, dimet...
Embodiment 3
[0049] Embodiment 3, a kind of extremely thin double-sided adhesive tape
[0050] The ultra-thin double-sided adhesive tape includes a PET single-sided release film, an acrylic pressure-sensitive adhesive layer and a PET transparent film, and the upper and lower surfaces of the PET transparent film are respectively attached with an acrylic pressure-sensitive adhesive layer. The outer surface is covered with a PET single-sided release film; the acrylic pressure-sensitive adhesive layer is composed of the following preparation raw materials and parts by weight thereof:
[0051] 80 parts of acrylic adhesive, 5 parts of thinner, 5 parts of modified epoxy resin, 2 parts of trimethylolpropane triacrylate, 2 parts of dispersant and 2 parts of isocyanate curing agent; Toluene forms by weight ratio 2:5; Described modified epoxy resin is the modified epoxy resin that embodiment 1 makes; Described cationic polyepoxysuccinic acid is the cationic polyepoxysuccinic acid that embodiment 2 ma...
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