946 results about "Triacrylate ester" patented technology

Provided is lithium secondary battery comprising a cathode, an anode, and an electrolyte or separator-electrolyte assembly disposed between the cathode and the anode, wherein the anode comprises: (a) a foil or coating of lithium or lithium alloy; and (b) a thin layer of a high-elasticity polymer disposed between the foil/coating and the electrolyte (or separator-electrolyte assembly), having a recoverable tensile strain no less than 2%, a lithium ion conductivity no less than 10⁻⁶ S/cm at room temperature, and a thickness from 1 nm to 10 μm, wherein the high-elasticity polymer contains a cross-linked network of polymer chains having an ether linkage, nitrile-derived linkage, benzo peroxide-derived linkage, ethylene oxide linkage, propylene oxide linkage, vinyl alcohol linkage, cyano-resin linkage, triacrylate monomer-derived linkage, tetraacrylate monomer-derived linkage, or a combination thereof in the cross-linked network of polymer chains.

There is provided an electrophotographic photoconductor which contains at least a conductive substrate, a photoconductive layer comprising a charge generating material and charge transport material, and a surface layer disposed on the photoconductive layer, disposed in this order, wherein the surface layer is a cross-linked resin which contains at least trimethylolpropane triacrylate, a charge transport material having a heat-curable or radical-polymerizable functional group, a silicone compound having a radical-polymerizable functional group, a fluorinated surfactant having a radical-polymerizable functional group, and a silicone compound removing material having a radical-polymerizable functional group having a wettability of 55 mN/m or more to less than 65 mN/m with the silicone compound.

The invention relates to a preparation method of an in-situ polymerization solid-state battery. The preparation method comprises the following steps: step S1, mixing electrolyte salt, an organic solvent, 1-10 percent of acrylic ester and 0.1-1 percent of an initiating agent AIBN to prepare a mixture I, wherein the acrylic ester is one of or more of isopentyl tetraacrylate, pentaerythritol triacrylate and allyl hydroxyethyl ether; step 2, weighing an active substance, acetylene black and positive pole piece made by PVDF according to the mass ratio of 6:3:1, taking a lithium sheet as a negativeelectrode, taking the mixture I as an electrolyte and taking a polypropylene thin film as a diaphragm assembly battery; step S3, putting the battery in a drying box and maintaining for 1-30 minutes after the battery is heated to 40-80 DEG C. The preparation method provided by the invention has the benefit that by adopting an in-situ heat curing technology, the interface problem between the electrolyte and a battery anode and cathode can be better solved.

The present invention discloses nanometer SiO2 modifying process of UV ray cured adhesive. The long chain polyether silane coupler in the general expression of (R1O)3SiCH2CH2CH2O(CH2CH2O)a(CH2CH(CH3)O)bC=OC(R2)=CH2 is first used in surface modifying SiO2 of grain size of 5-50 nm inside isopropyl alcohol dispersing medium; the obtained composite pre-polymer is then mixed with epoxy acrylate, hydroxyethyl methacrylate or hydroxypropyl methacrylate, trimethylopropane-3ethoxyl -triacrylic ester, acrylic cid or acrylate with acid functional radical, photoiniitator, KH570, triethanolamine and maleic acid through stirring to obtain the UV adhesive product. The present invention has improved SiO2 dispersivity and stability, and the UV adhesive product has greatly raised adhesion performance.

The invention provides an ultraviolet light cured silk screen snowflake printing ink and a preparation method thereof. The ultraviolet light cured silk screen snowflake printing ink which has a viscosity of 1500-3000cps at the temperature of 25 DEG C is prepared by materials of 50-60 parts of ultraviolet light curable resins, 5-8 parts of photoinitiators, 0.5-1 part of defoamers, 0.5-1 part of flatting agents, 0.1-0.2 part of polymerization inhibitors, 9-13 parts of wax powders, 5-15 parts of trimethylolpropane triacrylate, 5-15 parts of 1, 6-hexanediol diacrylate and 7.3-12.4 parts of colored printing ink which are firstly subjected to a predispersion at a medium speed of 200rpm to 500rpm for 30 minutes in a disc mixer, and then subjected to a dispersion at a high speed of 3000rpm to 3500rpm for one hour. The ultraviolet light cured silk screen snowflake printing ink has the advantages that the appearance is unique, the decorative pattern is delicate, the weather resistance is good, the smell is mild, the printing ink is environment-friendly, printed products touch smooth, and the like.

Provided is a preparation method for an antifogging thin film coating with high light transmission. M-phthalic acid triethylene glycol ester-5-sodium sulfonate (self made), polyethylene glycol 400, isophorone diisocyanate and pentaerythritol triacrylate are employed as main raw materials, dibutyltin dilaurate is employed as a catalyst, dimethylolpropionic acid is employed as a chain extender, acetone is employed as a solvent, and hydrophilic UV prepolymers are prepared; ethyl orthosilicate is employed as a precursor, gamma-methacryloxy propyl trimethoxysilane is employed as a modifier, a sol-gel method is employed, and uniform and stable modified SiO2 sol is prepared; the hydrophilic UV prepolymers and the modified SiO2 sol are subjected to hybridization through a UV curing way, and a thin film coating is obtained. The prepared thin film coating has good hardness and adhesive force, water resistance and high light transmission and good antifogging effects, and can be used for antifog of surfaces of glass and eyeglass. The preparation technology of the thin film coating accords with green environmental protection concepts, curing and film forming are fast, and comprehensive performances are good. The antifogging thin film coating has good market prospect and is suitable for popularization and application.

Single domain wafer-scale colloidal crystals and macroporous polymers are formed by dispersing concentrated solutions of colloids, desirably mondisperse silica colloids, in a viscous monomer, desirably ethoxylated trimethylolpropane triacrylate, and spin-coating them onto a substrate. Subsequent photopolymerization produces three-dimensionally ordered colloidal crystals trapped inside a polymer matrix. Selective removal of the polymer matrix, such as by oxygen plasma treatment, or removal of the silica spheres, such as by wet etching, produces large-area colloidal crystals and macroporous polymers, respectively.

The present invention relates to an environmentally friendly shell powder functional coating, a preparation method therefor and uses thereof. The coating comprises: bisphenol A-epon, modified shell powder, vegetable extract, propyl silicone emulsion, a nano additive, a modified organic micro powder agent, a surfactant, dioctylphthalate, 3, 3'-(4-trifluoromethyl methyl)-bi-4-hydroxy coumarin, 2,2,4-amino trimethyl-1,3-isoprene glycol mono iso-butyl methacrylate, butyl acetate, ethanol, trimethylol propane triacrylate, N-ammonia amino ethyl piperazine, polydimethylsiloxane and deionized water. In the present invention, by modification of a variety of components and materials, selection and collocation of specific components and a specific preparation method, the variety of components exert a synergistic effect, so as to make the prepared coating have significant antimicrobial, environmental-cleaning and wear-resisting properties. The coating has a huge application potential and extensive value in industrial production.

The invention provides acrylic ester rubber and a preparation method thereof. The acrylic ester rubber is characterized by comprising the following components by weight: 70-90 portions of tri-acrylate rubber AR840, 10-30 portions of butyronitrile rubber NBR, 55-75 portions of fast extruding carbon black N550, 1-2 portions of anti-aging agent RD, 1-2 portions of anti-aging agent MB, 0.5-1 portion of anti-scorching agent CTP, 3-5 portions of dioctyl phthalate DOP, 1-2 portions of dispersant rhine powder-42, 0.3-0.5 portion of common sulphur, 0.2-0.4 portion of tetramethyl thiuram disulfide TMTD, 3.5-4.0 portions of sodium stearate and 0.3-0.5 portion of potassium stearate. The sticking phenomenon is reduced and the elasticity, extensile intensity and low temperature resistance of the acrylic ester rubber are improved.

The invention relates to a method for radiation curing of a pure organic silicone coated fabric by using electron beams. The method comprises the following steps of: dispersing vinyl silicone oil, dimethyl silicone oil, hydrogen-containing silicone oil, a silane coupling agent, trimethylolpropane triacrylate, nanoscale silica, a flatting agent and a surface active agent in a vacuum kneading machine, mixing evenly to obtain a coating, finishing a fabric with certain humidity by a rubber blanket preshrinking machine, hot pressing the fabric through a hot pressing roller of a mirror glazing calendar to obtain base cloth, evenly coating the coating on the base cloth, and placing the base cloth on a transmission beam rack of a low-energy electron accelerator through a transmission roller for radiation curing to obtain the fabric. The fabric produced by the method is silky and soft in hand feel, waterproof, anti-seepage, and good in breathability and moisture permeability, and can be widely used in clothing, outdoor, fashionable fabrics and the like; the clothing does not have wrinkles, is easy to iron, and has stretching and recovering properties, and outdoor textiles can withstand the invasion of sun, wind and water; and the coating provided by the invention does not contain any solvent, and is environment-friendly, safe, non-toxic, pollution-free, simple in preparation technology, convenient in operation and construction, and low in energy consumption.

An acrylic urethane prepolymer composition and an unsaturated polyester resin composition to which the prepolymer has been added. The prepolymer composition includes an acrylic urethane prepolymer prepared by the reaction of diisocyanate, such as MDI, with an hydroxyl-containing acrylate monomer, such as a pentaerythritol triacrylate. The prepolymer composition contains a styrene monomer and an inhibitor, such as benzoquinone, to retard the reaction of the prepolymer and styrene monomer prior to the addition of the prepolymer composition into the polyester resin composition and a photoinitiator to promote the polymerization of the resin by exposure to radiant energy. The employment of the urethane prepolymer composition provides for the reduction in the amount of styrene monomer used in the unsaturated resin composition and also provides for improved chemical and physical properties of the photocured, unsaturated resin composition.

A preparation method of biaxially oriented polyester (BOPET) film surface wear-resistant scratch-resistant coating relates to a preparation method of a BOPET film surface coating and solves the problems of high cost and poor wear resistance and scratch resistance of the coating when preparing the BOPET film surface wear-resistant scratch-resistant coating in the prior art. The preparation method of the invention includes the following steps of: uniformly mixing polyurethane hexa-acrylate, epoxy modified acrylate, dipentaerythritol monohydroxy hexa-acrylate, trimethylolpropane tri-acrylate, tripropylene glycol diacrylate, butyl titanate and compound cracking light trigger to obtain coating material; then coating the coating material on the BOPET film surface done with corona treatment, and finally obtaining the (BOPET) film surface wear-resistant scratch-resistant coating after ultraviolet curing. The BOPET film surface wear-resistant scratch-resistant coating has low cost and good wear resistance and scratch resistance, and the coating performance pencil hardness is over 3H.

The invention discloses a high gloss high abrasion resistance ultra-violet (UV) curing overprinting varnish of mobile phone and a preparation method thereof. The method of the invention uses low-viscosity polyester acrylate and aliphatic polyurethane acrylate as base resin which combines with ethoxylated pentaerythritol tetraacrylate, Trimethylolpropane triacrylate, Tri(propylene glycol) diacrylate, 1,6-hexanediol diacrylate and 2-ethylhexyl acrylate which are used as active diluent, alcohol and ethyl acetate which are used as diluent, benzophenone and 1-hydroxycyclohexyl phenyl ketone which are used as photoinitiator, reactive amine coinitiator, defoaming agent, flatting agent, slip agent and other agents to mix evenly and prepare the UV overprinting varnish. The overprinting varnish of the invention adopts the special raw material formula and has good lustrousness, adhesive force and mechanical stability; as some polyfunctional resins and resins with special functional groups are added, the crosslink density of the UV varnish is increased in the curing process and the hardness of the product is up to 5-7H; and as solid wax powder used as the slip agent is added, the coefficients of friction can be reduced and the product can have extremely high wear resistance.

The invention discloses a pressure sensitive adhesive, a preparation method thereof and protective films using same. The formula of the pressure sensitive adhesive comprises 20 to 30 parts of butyl methacrylate, 20 to 30 parts of 2-ethylhexyl acrylate, 5 to 10 parts of methyl methacrylate, 2 to 5 parts of hydroxypropyl acrylate, 0 to 15parts of silicon-modified acrylic resin, 0 to 1 parts of trimethylol propyl triacrylate or 0 to 1 part of polyethylene glycol diacrylate, 0.2 to 5.0 parts of polyether-modified polyisocyanate and 50 to 60 parts of ester solvent. The pressure sensitive adhesive is coated on a PE or PP protective film substrate for manufacturing the protective films of optical thin films. The protective films can be directly used for processing raw films of the optical thin films, functional optical films, backlight modules and liquid crystal displayers. The protective films can protect the optical thin films from being polluted and scraped by dust and avoid damaging the intrinsic optical property of the optical thin films.

The invention belongs to a method for preparing pentaerythritol trimethylacrylate, comprising the steps as follows: (1) pentaerythritol, acrylic acid, catalyst, solvent and polymerization inhibitor are put into a reaction kettle to be fully mixed and stirred so as to form a miscible liquid; (2) a steam valve of the reaction kettle is opened to slowly heat the miscible liquid, and the temperature is controlled and maintained at 70-90 DEG C for a 20-40min reaction; (3) the mixture is continued to be heated, when the temperature is increased to 80-115 DEG C, reflow is carried out for 3-5h and then the reaction is finished; (4) soda water solution and sodium chloride water solution are added into the mixture and after washing the upper organic phase is extracted; (5) the upper organic phase is separated from the solvent; (6) and filter pressing is carried out to obtain the end product. The method has simple process, good quality, activity and flexibility, low shrinking percentage and color intensity and high yield coefficient, and produces few by-products or little waste water.

The invention relates to an optical diffusion barrier which comprises a substrate, a diffusion layer and a back layer, wherein the diffusion layer is ultraviolet-cured on any one of the surfaces of the substrate by coating solution comprising optical diffusion particles A, resin A and photo-initiator, wherein the resin A consists of epoxy acrylate resin and urethane acrylate with 8 degrees of functionality in the weight ratio of 1:9-9:1; the back layer is ultraviolet-cured on the other surface of the substrate by coating solution comprising optical diffusion particles B, resin B, photo-initiator and antistatic agent, wherein the resin B consists of pentaerythritol triacrylate and caprolactone modified dipentaerythritol penta/hexa-acrylate in the weight ratio of 1:9-9:1; the optical diffusion particles A consist of high polymer micro-spheres in particle sizes of 10-25 microns and inorganic particles in the particle sizes of 1-4 microns, in the weight ratio of 2:1-4:1; the optical diffusion particles B are inorganic particles in the particle sizes of 2-4 microns; and the diffusion barrier has high hardness, thin coating layer and high transmittance, full diffusion performance and good antistatic property and can meet the development direction of a flat panel display in large size, thinning, light weight and low cost.

The invention discloses ultraviolet curing vacuum coating metal primer capable of achieving electrostatic spraying and a preparation method thereof.The ultraviolet curing vacuum coating metal primer capable of achieving electrostatic spraying is prepared from, by weight, 5-20 parts of urethane acrylate, 10-20 parts of epoxy acrylate, 0-5 parts of pure acrylate, 5-10 parts of polyesteracrylate, 30-40 parts of trimethylolpropane triacrylate, 10-20 parts of low-functionality active diluted monomers, 2-5 parts of photoinitiator, 0.05-0.1 part of a flatting agent, 0.05-0.5 part of adhesion promoter, 0.01-0.5 part of a conductive agent and 3-5 parts of electrostatic thinner.The ultraviolet curing vacuum coating metal primer prepared through the method can be used for electrostatic spraying, has the advantages of being good in coating performance, good in adhesion, high in salt fog resistance, high in production efficiency, high in paint utilization rate and the like, and has wide market prospects.

The invention provides a hydrolyzable UV (ultraviolet) protection ink, which is prepared by mixing the following components in parts by weight: 30-48 parts of modified organosilicon acrylic resin, 6-15 parts of modified epoxy acrylic resin, 5-12 parts of isobornyl acrylate, 10-15 parts of trimethylolpropane triacrylate, 5-12 parts of chlorinated rubber, 7-15 parts of grass green pigment, 2-5 parts of silane coupling agent, 0.1-0.5 part of defoaming agent, 0.5-1.0 part of leveling agent, 0.02-0.04 part of polymerization inhibitor, 5-15 parts of calcium carbonate and 2-8 parts of 369 photoinitiator. The UV protection ink provided by the invention is a hydrolyzable UV curing protection ink of which the curing time can be obviously shortened. In addition, after finishing processing touch screen cover plate glass or ITO glass, the protective film can be removed by soaking in alkaline water. The UV protection ink has the advantage of no residue, can be peeled easily, and thus, has wide application prospects.

An UV curing luminescent panel consists of a luminescent layer and a reflective layer. The luminescent layer with the thickness of 0.02-5.0mm consists of light-cured resin (10-40 percent of resins such as epoxy acrylic resin, polyurethane acrylic resin, polyester acrylic resin and the like), photosensitive diluent (photosensitive diluent is 10-20 percent of resins of ethoxylated acrylic ester, propoxylated neopentyl glycol diacrylate, TMPTA and the like), photoinitiator (2-10 percent of beans development kit BDK and the like), luminescent materials (10-65 percent) and additive (0-5 percent). The UV curing luminescent panel has the advantages of no solvent emission, saving energy due to instant drying of UV curing, high production efficiency due to on-line processing, and being applicable to base materials sensitive to heat; furthermore, the prepared luminescent panel is characterized by high brightness, long luminescent time, excellent acid and alkali resistance and weatherability, good printing performance, non-toxicity, no radiation and stable physicochemical performance.

The invention relates to a transparent foam sole formulation, made from magnesium carbonate, a white foaming agent, bis(tert-butylperoxy) diisopropyl benzene, 2,6-di-tert-butyl-4-methylphenol or butylated hydroxytoluene, transparent zinc oxide, stearic acid, trimethylolpropane triacrylate, silane coupling agent, ethylene-vinyl acetate copolymer, olefin block copolymer, styrene-butadiene-styrene triblock copolymer, and ethylene-propylene-diene monomer rubber, wherein the magnesium carbonate is powdery and has particle size of 40-80 mesh. A sole made by comprehensively selecting formulations and processes is pervious to light, and can meet the requirements of soles in terms of physical parameters such as elasticity, yellowing resistance, and compression set deformation.

In order to solve the problem of no conductivity and poor mechanical properties in the photosensitive resin for 3D printing in the prior art, the invention provides a conducting photosensitive resin for 3D printing, which comprises a photosensitive prepolymer, a monomer, a crosslinking agent, a photoinitiator, a surfactant conducting particles. On the basis of the total weight of the conducting photosensitive resin, the content of the photosensitive prepolymer is 30-60 wt%, the content of the monomer is 10-40 wt%, the content of the crosslinking agent is 10-30 wt%, the content of the photoinitiator is 1-5 wt%, the content of the organosilicon surfactant is 1-5 wt%, and the content of the conducting particles is 15-40 wt%. The monomer is phenoxyethyl acrylate, the crosslinking agent is trihydroxymethyl tripropane triacrylate, and the viscosity of the conducting photosensitive resin is 80-400 mPa.s. The invention also provides a preparation method of the conducting photosensitive resin. The conducting photosensitive resin provided by the invention is suitable for 3D printing equipment, and has excellent conductivity and mechanical properties after being cured.

The invention relates to high wear-resistant epoxy coating, a preparation method of high wear-resistant epoxy coating and a high wear-resistant epoxy coating layer. The high wear-resistant epoxy coating provided by the invention is characterized by being prepared from an A component and a B component, wherein (1) the A component is prepared from the following raw materials in percentage by mass: 45 to 55 percent of epoxy resin, 3 to 5 percent of toughening agent, 3 to 5 percent of diluting agent, 5 to 10 percent of accelerator, 2 to 5 percent of silane coupling agent, 20 to 25 percent of abrasive aggregates, 5 to 10 percent of filler and appropriate percent of pigment; (2) the B component is prepared from the following raw materials in percentage by mass: 15 to 20 percent of MXDA (M-Xylylenediamine), 15 to 20 percent of IPDA (Isophorone Diamine), 3 to 5 percent of 1,3-BAC (1,3-bis(aminomethyl)-cyclohexan), 25 to 35 percent of polyether amine D230, 25 to 30 percent of styrenated phenol and 5 to 10 percent of TMPTA (Trimethylolpropane triacrylate); the A component and the B component are mixed according to a proportion of 1:5. The high wear-resistant epoxy coating disclosed by the invention has excellent wear resistance, high hardness, good heat resistance and water resistance, good chemical reagent corrosion resistance, high fullness, high construction efficiency, convenience in construction and a wide application range.

The invention discloses ultraviolet cured wood paint and a preparation method thereof. The raw material formula of the ultraviolet cured wood paint comprises the following components in percentage by weight: 30 to 35 percent of modified unsaturated polyester resin, 10 to 20 percent of polyester acrylate, 10 to 15 percent of 1,6-hexanediol diacrylate, 5 to 10 percent oftrimethylolpropane propoxylate triacrylate, 3 to 5 percent of polyhydroxyethyl methacrylate, 0.2 to 0.6 percent of settling agent, 10 to 20 percent of transparent powder, 3 to 6 percent of talcpowder, 0.5 to 1.5 percent of photoinitiator 1, 3 to 5 percent of photoinitiator 2 and 0.2 to 0.6 percent of flatting agent. The ultraviolet cured wood paint can be used as a transparent base coat, is low in cost, simple in preparationmethod and environmentally-friendly, has high transparency, high film performance, high rubbing property and high leveling property, and can create huge economic and social benefit.