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Water-based transfer laser paint and preparation method thereof

A technology for transferring lasers and coatings, applied in polyurea/polyurethane coatings, coatings, latex paints, etc., which can solve the problems of lack of in-depth research on molecular structure and characteristic applications, insufficient scratch resistance, and low laser brightness. Achieve the effect of green production process, reduce material cost and avoid the danger of explosion

Inactive Publication Date: 2018-12-11
YANTAI BOYUAN TECH MATERIALS
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] At present, the coatings used in the transfer method are mainly solvent-based systems, which are coated on the base film by roller coating, and are dried and cured at high temperature to form a film. There are many problems in the use process: poor environmental performance and poor safety.
[0004] In the above patents, a lot of research and improvement have been done on the component selection and formula composition of water-based transfer laser coatings, but no in-depth research has been done on the molecular structure and characteristic application of the main resin. In application, there are problems such as poor leveling, insufficient scratch resistance, mold sticking or pasting, and low laser brightness. Therefore, water-based transfer laser coatings have not yet been applied in batches.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0043] Select branched polyester Boltorn H20, maleic anhydride, polyethylene adipate diol, toluene diisocyanate, acetone, dioxane, triethanolamine for use in the present embodiment to prepare three-dimensional structure waterborne polyurethane resin, then It is compounded with water-based acrylic resin, deionized water, film-forming additives, and functional additives to obtain water-based transfer laser coatings.

[0044] About the preparation of three-dimensional structure waterborne polyurethane resin:

[0045]Step 1: Preparation of stereostructure precursor: In a 100mL round bottom flask equipped with a thermometer, reflux condenser and water separator, add 17.5g branched polyester Boltorn H20, 8.5g acetone, 9.0g dioxane, Raise the temperature to 60°C and stir to dissolve evenly, then add 9.8g of maleic anhydride until it is completely dissolved, raise the temperature and control the temperature at 100°C, and carry out the modification reaction for 2 hours under nitrogen p...

Embodiment 2

[0051] Select branched polyester Boltorn H30, acetic anhydride, polybutylene adipate diol, isophorone diisocyanate, acetone, dimethylformamide, diethanolamine to prepare three-dimensional structure waterborne polyurethane resin in the present embodiment, Then compound with water-based acrylic resin, deionized water, film-forming additives and functional additives to obtain water-based transfer laser paint.

[0052] Preparation of three-dimensional structure waterborne polyurethane resin:

[0053] Step 1: Preparation of stereostructure precursor: In a 300mL round bottom flask equipped with a thermometer, reflux condenser and water separator, add 36.0g branched polyester Boltorn H30, 36.0g acetone, 18.0g dimethylformamide , raise the temperature to 70°C and stir to dissolve evenly, then add 20.4g of acetic anhydride until completely dissolved, raise the temperature and control the temperature at 100°C, carry out the modification reaction for 3 hours under the protection of nitro...

Embodiment 3

[0059] Select branched polyester Boltorn H40, phthalic anhydride, polyethylene adipate diol, hexamethylene diisocyanate, acetone, dimethyl sulfoxide, triethanolamine to prepare the three-dimensional structure in the present embodiment Water-based polyurethane resin, and then compounded with water-based acrylic resin, deionized water, film-forming additives, and functional additives to obtain water-based transfer laser coatings;

[0060] Preparation of three-dimensional structure waterborne polyurethane resin:

[0061] Step 1: Preparation of stereostructure precursor: In a 300mL round bottom flask equipped with a thermometer, reflux condenser and water separator, add 70.0g branched polyester Boltorn H40, 35.0g acetone, 35.0g dimethyl sulfoxide , raise the temperature to 80°C, stir and dissolve evenly, then add 44.5g of phthalic anhydride until completely dissolved, raise the temperature and control the temperature at 120°C, carry out the modification reaction under nitrogen pro...

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PUM

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Abstract

The invention belongs to the technical field of transfer paint, and in particular relates to water-based transfer laser paint and a preparation method thereof. The water-based transfer laser paint isprepared from following components in parts by weight: 30% to 60% of three-dimensional water-based polyurethane resin, 20% to 30% of water-based acrylic resin, 10% to 50% of deionized water, 1% to 3%of a film forming aid and 0 to 1% of a functional additive. For the preparation of the water-based transfer laser paint, the following steps are carried out: Step 1, preparation of a three-dimensionalprecursor; Step 2, preparation of a polyurethane prepolymer; Step 3, preparation of a three-dimensional water-based polyurethane resin; Step 4, preparation of water-based transfer laser paint; Step 5, filtering and removing the impurities to eliminate the bubbles, detecting and adjusting the viscosity of the water-based transfer laser paint to meet the requirements of application on a machine toachieve a finished product. The preparation method makes the paint have excellent coating performance, temperature resistance, moldability and printing adaptability by a reasonable combination of resins, thereby providing a brand new solution for the transfer laser paint in aspects of green property, safety and environmental protection.

Description

technical field [0001] The invention belongs to the technical field of transfer paint, and in particular relates to a water-based transfer laser paint and a preparation method thereof. Background technique [0002] Laser paper is widely used in various high-end packaging due to its colorful color effects, noble and beautiful metal texture, stable and reliable anti-counterfeiting, and degradable and recyclable environmental protection performance. Generally, there are two main production processes of laser paper: direct method and transfer method. The direct method has high requirements on raw materials and equipment, and it is difficult to realize high quantitative paper; the transfer method uses film as the medium to transfer laser information to paper. Wen laser effect design diversification advantages. [0003] At present, the coatings used in the transfer method are mainly solvent-based systems, which are coated on the base film by roller coating and dried and cured at...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09D175/04C09D175/14C09D133/00C09D5/02C08G18/10C08G18/42C08G18/73C08G18/75C08G18/76C08G63/91
CPCC08G18/10C08G18/4202C08G18/4238C08G18/73C08G18/755C08G18/7614C08G63/91C09D5/024C09D175/04C09D175/14C08G18/42C08L33/00
Inventor 黄立朋王海平阚方俊王刚薛守成杨建青
Owner YANTAI BOYUAN TECH MATERIALS
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