Water-based transfer laser paint and preparation method thereof
A technology for transferring lasers and coatings, applied in polyurea/polyurethane coatings, coatings, latex paints, etc., which can solve the problems of lack of in-depth research on molecular structure and characteristic applications, insufficient scratch resistance, and low laser brightness. Achieve the effect of green production process, reduce material cost and avoid the danger of explosion
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Embodiment 1
[0043] Select branched polyester Boltorn H20, maleic anhydride, polyethylene adipate diol, toluene diisocyanate, acetone, dioxane, triethanolamine for use in the present embodiment to prepare three-dimensional structure waterborne polyurethane resin, then It is compounded with water-based acrylic resin, deionized water, film-forming additives, and functional additives to obtain water-based transfer laser coatings.
[0044] About the preparation of three-dimensional structure waterborne polyurethane resin:
[0045]Step 1: Preparation of stereostructure precursor: In a 100mL round bottom flask equipped with a thermometer, reflux condenser and water separator, add 17.5g branched polyester Boltorn H20, 8.5g acetone, 9.0g dioxane, Raise the temperature to 60°C and stir to dissolve evenly, then add 9.8g of maleic anhydride until it is completely dissolved, raise the temperature and control the temperature at 100°C, and carry out the modification reaction for 2 hours under nitrogen p...
Embodiment 2
[0051] Select branched polyester Boltorn H30, acetic anhydride, polybutylene adipate diol, isophorone diisocyanate, acetone, dimethylformamide, diethanolamine to prepare three-dimensional structure waterborne polyurethane resin in the present embodiment, Then compound with water-based acrylic resin, deionized water, film-forming additives and functional additives to obtain water-based transfer laser paint.
[0052] Preparation of three-dimensional structure waterborne polyurethane resin:
[0053] Step 1: Preparation of stereostructure precursor: In a 300mL round bottom flask equipped with a thermometer, reflux condenser and water separator, add 36.0g branched polyester Boltorn H30, 36.0g acetone, 18.0g dimethylformamide , raise the temperature to 70°C and stir to dissolve evenly, then add 20.4g of acetic anhydride until completely dissolved, raise the temperature and control the temperature at 100°C, carry out the modification reaction for 3 hours under the protection of nitro...
Embodiment 3
[0059] Select branched polyester Boltorn H40, phthalic anhydride, polyethylene adipate diol, hexamethylene diisocyanate, acetone, dimethyl sulfoxide, triethanolamine to prepare the three-dimensional structure in the present embodiment Water-based polyurethane resin, and then compounded with water-based acrylic resin, deionized water, film-forming additives, and functional additives to obtain water-based transfer laser coatings;
[0060] Preparation of three-dimensional structure waterborne polyurethane resin:
[0061] Step 1: Preparation of stereostructure precursor: In a 300mL round bottom flask equipped with a thermometer, reflux condenser and water separator, add 70.0g branched polyester Boltorn H40, 35.0g acetone, 35.0g dimethyl sulfoxide , raise the temperature to 80°C, stir and dissolve evenly, then add 44.5g of phthalic anhydride until completely dissolved, raise the temperature and control the temperature at 120°C, carry out the modification reaction under nitrogen pro...
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