Silicone special optical fiber inner layer coating with ultra-low glass transition temperature and preparation method thereof

A glass transition temperature, special optical fiber technology, applied in anti-corrosion coatings, conductive coatings, polyurea/polyurethane coatings, etc., can solve the problems of optical performance degradation, overall optical fiber performance degradation, and dynamic fatigue parameter Nd value degradation.

Active Publication Date: 2018-12-11
武汉长盈鑫科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

With the gradual thinning of optical fibers, the requirements for operating temperature are becoming wider and wider, and the requirements for optical fiber coatings are also getting higher and higher. After using the existing optical fiber coatings to p...

Method used

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  • Silicone special optical fiber inner layer coating with ultra-low glass transition temperature and preparation method thereof
  • Silicone special optical fiber inner layer coating with ultra-low glass transition temperature and preparation method thereof
  • Silicone special optical fiber inner layer coating with ultra-low glass transition temperature and preparation method thereof

Examples

Experimental program
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Effect test

Embodiment 1

[0061] An ultra-low glass transition temperature organosilicon special optical fiber inner layer coating, the content of each component is: organosilicon prepolymer 70%, additives 2%, photoinitiator 4%, low temperature active monomer Body 16%, interface activated resin 8%.

[0062] The organosilicon prepolymer is the PUA-PP1 synthesized above.

[0063] The composition of the auxiliary agent is calculated by weight percentage: its component content is 80% of antioxidant CHINOXGM, 10% of polymerization inhibitor p-methoxyphenol, and 10% of antistatic agent SN.

[0064] The composition of the photoinitiator by weight percentage is: 50% photoinitiator TPO, 30% photoinitiator 184, and 20% photoinitiator 819.

[0065] The composition of the low-temperature active monomer is calculated by weight percentage: 10% lauryl methacrylate, 90% heptadecyl acrylate.

[0066] The interface-active resin is J-1 synthesized above.

[0067] The preparation method of the above-mentioned ultra-low...

Embodiment 2

[0073] An ultra-low glass transition temperature organosilicon special optical fiber inner layer coating, the content of each component is: organosilicon prepolymer 60%, auxiliary agent 2.5%, photoinitiator 3.5%, low temperature active monomer Body 31%, interface activation resin 3%.

[0074] The composition of the organosilicon prepolymer by weight percentage is: 30% PUA-PP1, 70% PUA-PP2.

[0075] The composition of the auxiliary agent is calculated by weight percentage: its component content is 80% of antioxidant CHINOXGM, 10% of polymerization inhibitor hydroquinone, and 10% of defoamer BYK-1790.

[0076] The composition of the photoinitiator by weight percentage is: 70% photoinitiator TPO, 30% photoinitiator 907.

[0077] The composition of the low-temperature active monomer is calculated by weight percentage: 10% lauryl methacrylate, 10% heptadecyl acrylate, and 80% isocecyl acrylate.

[0078] The interface-active resin is J-2 synthesized above.

[0079] The preparation ...

Embodiment 3

[0085] An ultra-low glass transition temperature organosilicon special optical fiber inner layer coating, the content of its components is as follows: organosilicon prepolymer 65%, additives 1.7%, photoinitiator 4.5%, low temperature active monomer Body 23.8%, interface activation resin 5%.

[0086] The composition of the organosilicon prepolymer by weight percentage is: 100% PUA-PP2.

[0087] The composition of the auxiliary agent is calculated by weight percentage: its component content is 90% of antioxidant CHINOXGM, and 10% of polymerization inhibitor 2,6-di-tert-butyl-4-methylphenol.

[0088] The composition of the photoinitiator by weight percentage is: 70% photoinitiator 819, 30% photoinitiator 184.

[0089] The composition of the low-temperature active monomer is calculated by weight percentage: 10% lauryl methacrylate, 85% isotridecyl acrylate, and 5% isocecyl acrylate.

[0090] The interface-active resin is J-2 synthesized above.

[0091] The preparation method of...

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Abstract

The invention discloses a silicone special optical fiber inner layer coating with ultra-low glass transition temperature and a preparation method thereof. According to the invention, a prepolymer structure is introduced to phenyl silicone, which improves the refractive index and anti-aging property of the coating; and interface activated resin is introduced to enhance the mechanical strength and long-term reliability of optical fiber. The silicone special optical fiber inner layer coating comprises the following components by weight percent: 40-80% of silicone prepolymer, 0.1-10% of auxiliary,2-10% of a photoinitiator, 10-50% of low temperature active monomer, and 0.5-10% of interface activated resin, wherein the total percentage is 100%. The inner layer coating has the characteristics oflow glass transition temperature, high refractive index after curing, good adhesion to optical fibers, good aging resistance, high and low temperature impact resistance, and the like, and can be cured and shaped under radiation of LED ultraviolet lamps or conventional ultraviolet lamps.

Description

technical field [0001] The invention relates to the technical field of optical fiber and optical fiber coating, in particular to an ultra-low glass transition temperature organosilicon special optical fiber inner layer coating and a preparation method thereof. Background technique [0002] Special optical fiber refers to a type of optical fiber that is different from traditional single-multimode communication optical fibers. It can be subdivided into many varieties according to the application field, such as polarization maintaining optical fiber, circular optical fiber, large core diameter optical fiber, radiation-resistant optical fiber, etc. These special optical fibers have the characteristics of high price, difficult manufacturing technology, narrow application fields, high requirements on optical fiber performance, but relatively small demand. Special fiber optic coatings are required during the manufacture of these fibers. The special optical fiber is mainly composed...

Claims

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Application Information

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IPC IPC(8): C09D183/12C09D175/14C09D5/24C09D5/08C09D7/63
CPCC09D5/08C09D5/24C09D7/63C09D175/14C09D183/12C08K5/5455
Inventor 黄星余晓梦皮亚斌崔丽云万欢
Owner 武汉长盈鑫科技有限公司
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