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Calcium fumarate phosphate, preparation method thereof and application of phosphate

A technology of calcium fumarate phosphate and fumaric acid, which is applied in the preparation of carboxylate, the preparation and application of carboxylate, etc., can solve the problems of corrosive equipment and pipelines, ammonium chloride is easy to absorb moisture and agglomerate, and it is easy to volatilize. Operating environment and other problems, to achieve the effect of convenient operation, moderate price, and improved product purity

Active Publication Date: 2019-01-04
XINGJIA BIO ENG CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

During the reaction process, both ammonia water and concentrated hydrochloric acid are volatile and affect the working environment, and are also easy to corrode equipment and pipelines
The generated by-product ammonium chloride is easy to absorb moisture and agglomerate, and if there is a large amount of residue in the product, it will also easily lead to agglomeration of the product

Method used

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  • Calcium fumarate phosphate, preparation method thereof and application of phosphate
  • Calcium fumarate phosphate, preparation method thereof and application of phosphate
  • Calcium fumarate phosphate, preparation method thereof and application of phosphate

Examples

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Effect test

Embodiment 1

[0060] A kind of calcium fumarate phosphate of the present invention, molecular formula can be expressed as Ca 2 (C 4 h 3 o 4 )PO 4 , the structural formula is Ca(C 4 h 3 o 4 ) 2 · Ca 3 (PO 4 ) 2 , its preparation method comprises the following steps:

[0061] at 5m 3 Add 2t of water into the reaction kettle, add 232kg of fumaric acid into the water, heat up to 60°C, add 310.2kg of tricalcium phosphate to react, stir and react for 3.5h, and use calcium oxide to control the pH value to 6.5 throughout the process, so that it can fully react completely Afterwards, cooling and crystallization, followed by solid-liquid separation, washing, drying and pulverizing the precipitated crystals after solid-liquid separation to obtain about 551 kg of calcium fumarate phosphate product.

[0062]During cooling and crystallization, the operation steps for judging the completion of crystallization include: take a small amount of reaction system solution, filter to remove the crysta...

Embodiment 2

[0065] A kind of calcium fumarate phosphate of the present invention, molecular formula can be expressed as Ca 2 (C 4 h 3 o 4 )PO 4 , the structural formula is Ca(C 4 h 3 o 4 ) 2 · Ca 3 (PO 4 ) 2 , its preparation method comprises the following steps:

[0066] at 2m 3 Add 0.93t of water into the reaction kettle, add 116kg of fumaric acid into the water, heat up to 30°C, add 136kg of calcium hydrogen phosphate to react, stir for 2.0h, and use calcium hydroxide to control the pH value to 5.0 throughout the process to make it fully react After completion, cool and crystallize, and then carry out solid-liquid separation, wash, dry, and pulverize the precipitated crystals after solid-liquid separation to obtain about 263.9 kg of calcium fumarate phosphate product.

[0067] During cooling and crystallization, the operation steps for judging the completion of crystallization include: take a small amount of reaction system solution, filter to remove the crystallization pro...

Embodiment 3

[0071] A kind of calcium fumarate phosphate of the present invention, molecular formula can be expressed as Ca 2 (C 4 h 3 o 4 )PO 4 , the structural formula is Ca(C 4 h 3 o 4 ) 2 · Ca 3 (PO 4 ) 2 , its preparation method comprises the following steps:

[0072] at 2m 3 Add 1.16t of water into the reaction kettle, add 232kg of fumaric acid into the water, heat up to 70°C, add 234kg of calcium dihydrogen phosphate to react, stir for 1.0h, and use calcium oxide to control the pH value to 6.0 throughout the process to make it fully react After completion, cool and crystallize, and then carry out solid-liquid separation, wash, dry, and pulverize the precipitated crystals after solid-liquid separation to obtain about 562.6 kg of calcium fumarate phosphate product.

[0073] During cooling and crystallization, the operation steps for judging the completion of crystallization include: take a small amount of reaction system solution, filter to remove the crystallization produ...

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Abstract

The invention discloses calcium fumarate phosphate. The molecular formula of the calcium fumarate phosphate is Ca2 (C4H3O4)PO4. A preparation method of the calcium fumarate phosphate includes the steps: adding fumaric acid into water; adding calcium-containing phosphate to react in a stirring manner; adding a calcium source to control pH (potential of hydrogen) to reach weak acid; performing cooling crystallization and solid-liquid separation after mixture is completely reacted; washing, drying and crushing precipitated crystals to obtain the calcium fumarate phosphate. The calcium fumarate phosphate takes the calcium-containing phosphate as a main calcium source and contains calcium and phosphorus, the content of the calcium is high, the calcium-phosphorus ratio meets calcium-phosphorus ratio in most of feed, calcium and phosphorus are synergistically absorbed in animal bodies, and absorption effects are good. The invention further discloses an application of the calcium fumarate phosphate to chicken feed, laying rate of laying hens can be remarkably increased, egg weight and eggshell strength can be remarkably improved, the calcium content of a tibia and the length of the tibia can be remarkably improved, and the growth performance of meat chickens can be promoted.

Description

technical field [0001] The invention belongs to the technical field of preparation of feed additives, in particular to calcium fumarate phosphate and its preparation method and application. Background technique [0002] Bolduan (1988) defined acidity: the number of millimoles of hydrochloric acid required to reduce the pH value of 100 grams of feed to 4.0. Laying hens suffer from indigestion due to insufficient secretion of gastric juice, often causing diarrhea or stunted growth. In order to improve the diarrhea or growth retardation of laying hens, an acidifier is usually added from an external source to reduce the pH value of the stomach of laying hens, activate the pepsin source, improve the digestibility of protein, and indirectly reduce the acidity of the feed system. Of course, coating acidifiers are also currently used to adjust the pH of the hindgut of laying hens and change the microbial flora. [0003] Fumaric acid (fumaric acid), also known as fumaric acid, viol...

Claims

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Application Information

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IPC IPC(8): C07C57/15C07C51/41A23K20/26A23K50/75
CPCA23K20/26A23K50/75C07C51/412C07C57/15
Inventor 向阳葵黄逸强邓敏彭红星夏飞辉苏军姚亚军张亚伟
Owner XINGJIA BIO ENG CO LTD
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