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Preparation method of patterned graphene flexible strain sensor

A strain sensor and graphene technology, applied in the field of sensors, can solve problems such as difficult control, reduced pattern resolution, cumbersome process, etc., and achieve the effect of avoiding easy damage and wide application range

Inactive Publication Date: 2019-01-08
INST OF ELECTRONICS ENG CHINA ACAD OF ENG PHYSICS
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Among them, the inkjet printing process has a serious coffee ring effect (referring to the phenomenon that a ring-shaped stain is sometimes formed on the edge of the droplet after the solution or suspension droplet evaporates on the solid surface), and the graphene solution is formed into a film. It will cause the uniformity of graphene oxide film to decrease, and the existence of coffee ring will reduce the pattern resolution, which hinders the realization of micro-nano level patterning process of graphene film.
The graphene ink used in the screen printing process is generally a slurry with a high viscosity, and the introduction of adhesives limits the conductivity of graphene.
[0004] Therefore, the current methods for preparing patterned graphene sensors in this field are cumbersome, difficult to control, and cannot adapt to complex curved surfaces, and cannot process fine patterns, which hinders the development of flexible strain sensors.

Method used

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  • Preparation method of patterned graphene flexible strain sensor
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  • Preparation method of patterned graphene flexible strain sensor

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preparation example Construction

[0033] The invention provides a method for preparing a patterned graphene flexible strain sensor, comprising the following steps:

[0034] (1) Prepare a predetermined microstructure relief pattern on the surface of the hard substrate material by photolithography to obtain a patterned mold;

[0035] (2) mixing the elastomer and the curing agent to obtain a mixed slurry;

[0036] (3) coating the anti-adhesive agent on the surface of the patterned mold to form an anti-adhesive layer, then pouring the mixed slurry on the surface of the anti-adhesive layer to cure, and peeling off the cured parts to obtain a microfluidic mold;

[0037] (4) A flexible substrate is provided, the microfluidic mold is covered on the surface of the flexible substrate to form a microfluidic member, the microfluidic member is immersed in a dopamine solution, and then the microfluidic mold is uncovered to obtain a pattern Chemically modified flexible substrates;

[0038] (5) Coating the graphene-graphene...

Embodiment 1

[0068] (1) Fabrication of patterned molds: Microstructure relief patterns are produced on silicon substrates by photolithography, and a layer of anti-sticking agent is coated on the surface of the pattern. The anti-sticking agent is selected from 1H, 1H, 2H, 2H-perfluorooctane Heating 1H, 1H, 2H, 2H-perfluorooctyltriethoxysilane at 100°C to make it volatilize steam, fumigate the pattern side of the silicon substrate, and the fumigation time is 6h , that is, successful conformal coating on the mold surface to form an adhesive layer.

[0069] (2) Preparation of microfluidic mold: mix PDMS basic components with curing agent (mixing mass ratio is 10:1), stir well with a stirrer, and then ultrasonically in an ultrasonic cleaner for 5-10 minutes until the bubbles completely disappear, Then pour it on the surface of the anti-adhesive layer of the patterned mold, place it in an oven at 60°C for 1 hour to cure, and the cured PDMS can be easily peeled off from the surface of the pattern...

Embodiment 2

[0077] Other steps are identical with embodiment 1, only change the volume of the N-methylpyrrolidone dispersion liquid of graphene into 0.06mL in step (4), change the volume of the N-methylpyrrolidone dispersion liquid of graphene oxide into 0.04mL. Using XPS spectrum to test, the content of oxygen-containing functional groups in the mixed solution can be found to be 25-35%.

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Abstract

The invention provides a preparation method of a patterned graphene flexible strain sensor. The method comprises the following steps: firstly, preparing a predetermined pattern on the surface of a hard substrate material by using photoetching to obtain a patterned mold, and then pouring mixed slurry of polymer material elastomer and a curing agent onto the surface of the patterned mold for curingto obtain a micro-channel mold; and then covering the surface of a flexible substrate with the micro-channel mold, performing patterned modification on the flexible substrate by using dopamine, preparing a graphene sensitive layer on the surface of the modified substrate, and finally coating conductive silver paste and bonding a conducting wire to obtain the patterned graphene flexible strain sensor. According to the preparation method provided by the invention, no photoetching needs to be performed on the flexible substrate, so that the main body structure of the flexible substrate is not damaged, the preparation method is suitable for complex curved surfaces, large-area manufacturing and fine pattern processing, and the requirements for the own material, the shape and the surface structure of the flexible substrate are reduced.

Description

technical field [0001] The invention relates to the technical field of sensors, in particular to a method for preparing a patterned graphene flexible strain sensor. Background technique [0002] Graphene patterned film formation has important application value for the fine processing and performance regulation of micro-nano devices, and has aroused extensive research interest. The traditional graphene patterning method is to spin-coat graphene oxide on the surface of the substrate, and then perform photolithography to form a pattern, and then reduce the patterned graphene oxide. This method requires a photolithography step, which is cumbersome and costly, will cause certain damage to the substrate surface, and has strict requirements on the substrate material and surface morphology. And when the spin-coating process drops the graphene oxide reagent on the rotating substrate, the interaction force between graphene oxide and the substrate will affect the film formation, and t...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): G01B7/16
CPCG01B7/18
Inventor 杨婷婷徐炜代刚李小石杜亦佳
Owner INST OF ELECTRONICS ENG CHINA ACAD OF ENG PHYSICS
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