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High-temperature-resistant anti-oxidation anti-abrasion low-heat-expansion-coefficient aluminum tantalite ceramic material as well as preparation method and application thereof

A low thermal expansion coefficient, anti-oxidation technology, applied in the field of materials, can solve the problems of coating failure, huge thermal stress, high thermal expansion coefficient, and achieve the effect of low porosity, low preparation cost and high purity

Pending Publication Date: 2019-03-08
KUNMING UNIV OF SCI & TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Currently widely used are mainly rare earth silicates (RE 2 Si 2 o 7 ), etc., but there are certain deficiencies: RE 2 Si 2 o 7 High coefficient of thermal expansion, much higher than the base material to be protected
Many oxide ceramics with excellent thermal properties have been discovered, such as rare earth cerates (RE 2 Zr 2 o 7 ), rare earth phosphate (REPO 4 ) and rare earth zirconates (RE 2 Zr 2 o 7 ), etc., but their coefficients of thermal expansion are higher about 8~10×10 -6 K -1 (1200 ℃), which is much higher than the thermal expansion coefficient of the SiC material to be protected by 5~6×10 -6 K -1 (1200 ℃), the ratio matching of thermal expansion coefficient will generate huge thermal stress and lead to coating failure

Method used

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  • High-temperature-resistant anti-oxidation anti-abrasion low-heat-expansion-coefficient aluminum tantalite ceramic material as well as preparation method and application thereof
  • High-temperature-resistant anti-oxidation anti-abrasion low-heat-expansion-coefficient aluminum tantalite ceramic material as well as preparation method and application thereof
  • High-temperature-resistant anti-oxidation anti-abrasion low-heat-expansion-coefficient aluminum tantalite ceramic material as well as preparation method and application thereof

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Experimental program
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Effect test

Embodiment 1

[0041] Weigh 2.0000 g of alumina and 8.6611 g of tantalum oxide, mix them in absolute ethanol, and mill them in a high-energy ball mill (the speed of the ball mill is 300 r / min, and the milling time is 720 min), and then the milled solution is mixed at 100 After drying at ℃ for 12 h, it passed through a 300-mesh sieve, and then it was pressed into a mold (holding pressure of 20 MPa and holding time of 10 min). After pressing, it was pre-fired at 1000 °C for 10 h.

[0042] After the first calcination of the raw material, the sample was taken out and cooled to room temperature, the mixture was ground evenly and passed through a 500-mesh sieve, and then pressed into a mold (the holding pressure was 6 MPa, and the holding time was 5 minutes). After pressing, It was calcined at 1550°C for 12 hours and cooled to room temperature to obtain the desired dense block aluminum tantalate (AlTaO 4 ) High temperature ceramic materials.

[0043] The bulk aluminum tantalate (AlTaO) prepared i...

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Abstract

The invention discloses a high-temperature-resistant anti-oxidation anti-abrasion low-heat-expansion-coefficient aluminum tantalite ceramic material as well as a preparation method and application thereof. The high-temperature-resistant anti-oxidation anti-abrasion low-heat-expansion-coefficient aluminum tantalite ceramic material is prepared from aluminum oxide and tantalum pentoxide as raw materials; the compactness of the high-temperature-resistant anti-oxidation anti-abrasion low-heat-expansion-coefficient aluminum tantalite material is 98 percent; the heat diffusion coefficient is 0.6 to2.4mm<2> / s (25 to 900 DEG C); the heat conduction rate is 2.2 to 6.2W.K<-1>(25 to 900 DEG C); the hardness is 9.0 GPa; the phase change cannot occur at the temperature of 25 to 1200 DEG C. The preparation method comprises the steps of pretreatment and sintering. The application is the application of the high-temperature-resistant anti-oxidation anti-abrasion low-heat-expansion-coefficient aluminumtantalite ceramic material to the preparation of a coating with thermal and mechanical property.

Description

technical field [0001] The invention belongs to the technical field of materials, and in particular relates to an aluminum tantalate ceramic material with high temperature resistance, oxidation resistance, wear resistance and low thermal expansion coefficient, a preparation method and application thereof. Background technique [0002] Environmental coatings are mainly used in the aero-engine industry. They have the advantages of low thermal conductivity, low thermal expansion coefficient, anti-sintering, and good high-temperature stability. They mainly serve to prevent thermal corrosion, reduce thermal mismatch between the ceramic layer and the substrate (SiC), It can effectively resist the impact of particles and protect the parts of aero-engine high-temperature areas. Currently widely used are mainly rare earth silicates (RE 2 Si 2 o 7 ), etc., but there are certain deficiencies: RE 2 Si 2 o 7 The coefficient of thermal expansion is high, much higher than that of the...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C04B35/495C04B35/622
CPCC04B35/495C04B35/62222C04B2235/3217C04B2235/77C04B2235/96C04B2235/9607
Inventor 冯晶陈琳
Owner KUNMING UNIV OF SCI & TECH
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