3D printing material and preparation method thereof

A 3D printing and raw material technology, applied in the direction of additive processing, etc., can solve the problems of difficult degradation and poor functionality, and achieve the effect of high tensile strength and high impact resistance

Active Publication Date: 2019-03-29
福建万象三维科技有限公司
View PDF7 Cites 2 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Materials are an important factor restricting 3D printing, so researchers in this field are working on the research and development of 3D printing materials. However, the existing 3D printing materials still have many shortcomings, such as poor mechanical properties, poor functionality, and not easy to degrade.

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • 3D printing material and preparation method thereof
  • 3D printing material and preparation method thereof
  • 3D printing material and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

preparation example Construction

[0020] The preparation method of described 3D printing material, it comprises the following steps:

[0021] (1) Preparation of primary mixture: toluene, carbon disulfide, nano-titanium dioxide, γ-aminopropyltriethoxysilane, 2-chlorophenyloxirane, ethyl 2-chloromethylbenzoate, 1, 4-dichloro-2-butene and graphene oxide are heated and mixed to obtain an initial mixture;

[0022] (2) Ball milling: Add the initial mixture obtained in step (1) and 1-ethyl-3-methylimidazolium tetrafluoroborate into a ball mill, and use the ball mill to mill at a speed of 500-800r / min for 1-2h , to get the ball milled product;

[0023] (3) Preparation of blend A: mix the ball-milled product obtained in step (2) with epoxy acrylate, 2,6-di-tert-butyl-4-methylphenol, 2-(2'-hydroxyl-3' , 5'-di-tert-phenyl)-5-chlorinated benzotriazole heated and stirred to obtain blend A;

[0024] (4) Preparation of blend B: Blend A, nano-calcium carbonate powder, and ferrocene derivatives of step (3) gained are mixed ...

Embodiment 1

[0034]A 3D printing material, which includes the following raw materials in parts by weight: 200 parts of toluene, 400 parts of carbon disulfide, 7 parts of nano-titanium dioxide, 10 parts of γ-aminopropyltriethoxysilane, 2-chlorophenyl ring 50 parts of oxyethane, 90 parts of ethyl 2-chloromethylbenzoate, 25 parts of 1,4-dichloro-2-butene, 80 parts of graphene oxide, 1-ethyl-3-methylimidazolium tetrafluoro 10 parts of borate, 40 parts of epoxy acrylate, 2 parts of 2,6-di-tert-butyl-4-methylphenol, 2-(2'-hydroxy-3',5'-di-tert-phenyl)- 6 parts of 5-chlorinated benzotriazole, 7 parts of nano calcium carbonate powder, 35 parts of ferrocene derivatives, 3 parts of benzoyl peroxide;

[0035] Wherein, the structural formula of the ferrocene derivative is:

[0036]

[0037] The average particle diameter of the nano-calcium carbonate powder is 100 nanometers.

[0038] The average particle diameter of the nano-titanium dioxide is 80 nanometers.

[0039] The preparation method of t...

Embodiment 2

[0051] A 3D printing material, which includes the following raw materials in parts by weight: 280 parts of toluene, 300 parts of carbon disulfide, 9 parts of nano-titanium dioxide, 5 parts of γ-aminopropyltriethoxysilane, 2-chlorophenyl ring 60 parts of oxyethane, 80 parts of ethyl 2-chloromethylbenzoate, 35 parts of 1,4-dichloro-2-butene, 70 parts of graphene oxide, 1-ethyl-3-methylimidazolium tetrafluoro 15 parts of borate, 30 parts of epoxy acrylate, 5 parts of 2,6-di-tert-butyl-4-methylphenol, 2-(2'-hydroxy-3',5'-di-tert-phenyl)- 5 parts of 5-chlorinated benzotriazole, 9 parts of nano calcium carbonate powder, 25 parts of ferrocene derivatives, 8 parts of benzoyl peroxide;

[0052] Wherein, the structural formula of the ferrocene derivative is:

[0053]

[0054] The average particle size of the nano-calcium carbonate powder is 500 nanometers.

[0055] The average particle diameter of the nano-titanium dioxide is 20 nanometers.

[0056] The preparation method of descr...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

PUM

PropertyMeasurementUnit
particle sizeaaaaaaaaaa
particle sizeaaaaaaaaaa
particle sizeaaaaaaaaaa
Login to view more

Abstract

The invention relates to a 3D printing material and a preparation method thereof. The 3D printing material comprises the following raw materials: toluene, carbon disulfide, a ferrocene derivative, nano-titanium dioxide, gamma-aminopropyl triethoxysilane, 2-chlorophenyl ethylene oxide, ethyl 2-chloromethylbenzoate, 1, 4-dichloro-2-butene, graphene oxide, 1-ethyl-3-methylimidazolium tetrafluoroborate, epoxy acrylate, 2, 6-di-tert-butyl-4-methylphenol, 2-(2'-hydroxy-3', 5'-di-tert-phenyl)-5-benzotriazole chloride, nano-calcium carbonate powder and benzoyl peroxide. The 3D printing material has the advantages of rapid shaping, electric conduction, high impact resistance, high strength and high tensile strength. The 3D printing material also has the advantage of degradability, thus being an environment-friendly material.

Description

technical field [0001] The invention relates to a 3D printing material and a preparation method thereof. Background technique [0002] With the emergence of 3D printing products, 3D printing technology is gradually being understood by people. 3D printing is also called rapid prototyping manufacturing technology. Its manufacturing process is to process the three-dimensional model layered and discretely, and transmit the data of each layer to the 3D printer. Metal and ceramic powders are processed by laser, ultraviolet light, and hot-melt nozzles. Materials such as plastics, cell tissues, etc. are piled up layer by layer and then bonded to shape, and finally the entire material or device is manufactured. 3D printing has the characteristics of simple manufacturing process, short product development cycle, easy to manufacture complex shape parts, multiple parts can be integrally formed, small part processing allowance, and material saving. Printing materials, which are the cor...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

Application Information

Patent Timeline
no application Login to view more
Patent Type & Authority Applications(China)
IPC IPC(8): C08L63/10C08K13/06C08K9/06C08K9/04C08K3/04C08K5/3475C08K5/3445B33Y70/00
CPCB33Y70/00C08K5/3445C08K5/3475C08K9/04C08K9/06C08K13/06C08K3/042C08L63/10
Inventor 陈威陈灼莺张细明
Owner 福建万象三维科技有限公司
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Try Eureka
PatSnap group products

Browse by: Latest US Patents, China's latest patents, Technical Efficacy Thesaurus, Application Domain, Technology Topic.

© 2024 PatSnap. All rights reserved.Legal|Privacy policy|Modern Slavery Act Transparency Statement|Sitemap