Method for in-situ preparation of copper-based shape memory alloy through additive manufacturing
A memory alloy, in-situ preparation technology, applied in additive manufacturing, additive processing, process efficiency improvement and other directions, can solve the problems of slow cooling speed, many gaps, poor mechanical properties, etc., to reduce the formation of pores and improve the weight. Melting zone, the effect of increasing the density
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Embodiment 1
[0041] A method for preparing Cu-17Al-10Mn copper-based shape memory alloy of arbitrary shape through pre-alloyed powder, comprising the following steps:
[0042] (1) Put the high-purity alloy of elements Cu and Al in the alloy into a vacuum melting furnace for melting according to the mass ratio, and repeat the melting three times to obtain the original ingot, and pass the ingot into the vacuum melting furnace while melting at a high temperature The argon gas impacts the melt, and the melt is dispersed by the impact to form small droplets. After cooling, the required alloying powder raw material is formed. The particle size of the powder is 19.5-46.7 μm, and the average particle size is 30.5 μm. The high-purity alloy powder of Mn element is mechanically mixed with the above-mentioned pre-alloyed powder according to the mass ratio to obtain a uniform powder;
[0043] (2) The prepared mixed powder is used as the raw material, a continuous YAG laser is used as the energy source,...
Embodiment 2
[0048] A method for preparing Cu-17Al-10Mn copper-based shape memory alloy of arbitrary shape through pre-alloyed powder, comprising the following steps:
[0049] (1) Put the high-purity alloy of elements Cu and Mn in the alloy into a vacuum melting furnace according to the mass ratio for melting, repeat the melting three times to obtain the original ingot, and pass the ingot into the vacuum melting furnace while melting at high temperature The argon gas impacts the melt, and the melt is dispersed by the impact to form small droplets. After cooling, the required alloying powder raw material is formed. The particle size of the powder is 16.3-57.5 μm, and the average particle size is 31.2 μm. The high-purity alloy powder of Al element is mechanically mixed with the above-mentioned pre-alloyed powder according to the mass ratio to obtain a uniform powder;
[0050] (2) The prepared mixed powder is used as the raw material, a continuous YAG laser is used as the energy source, the l...
Embodiment 3
[0055] A method for preparing Cu-10.2Al-8.5Mn-0.3La copper-based shape memory alloy of arbitrary shape by pre-alloyed powder, comprising the following steps:
[0056] (1) Put the high-purity alloy of elements Cu and Al in the alloy into a vacuum melting furnace for melting according to the mass ratio, and repeat the melting three times to obtain the original ingot, and pass the ingot into the vacuum melting furnace while melting at a high temperature The argon gas impacts the melt, and the melt is dispersed by the impact to form small droplets. After cooling, the required alloying powder raw material is formed. The particle size of the powder is 8.63-50.2 μm, and the average particle size is 26.4 μm. The high-purity alloy powder of Mn and La elements is mechanically mixed with the above-mentioned pre-alloyed powder according to the mass ratio to obtain a uniform powder;
[0057] (2) Using the prepared mixed powder as the raw material, using high-energy electron beam as the ene...
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