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Low-cost and high-precision preparation method of carbon-based and metal-based electrode arrays

An electrode array, metal-based technology, applied in the direction of metal processing equipment, non-metal elements, chemical instruments and methods, etc., can solve the problems of complex preparation process of template filter membrane, difficulty in applying conductive materials, complicated filter devices, etc., and achieve structural composition Easy to adjust, wide range of substrates, good uniformity and reproducibility

Active Publication Date: 2019-04-23
WUHAN UNIV
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  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

However, the above scheme also has deficiencies. Lee fixes the non-adhesive template to the surface of the filter membrane, and its filter device is complicated and difficult to apply to large-volume dilute solutions of conductive materials; Such schemes require the use of expensive wax-jet printers, the template membrane preparation process is relatively complicated, and the use of paraffin wax as the template material also has problems such as poor high-temperature stability.

Method used

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  • Low-cost and high-precision preparation method of carbon-based and metal-based electrode arrays
  • Low-cost and high-precision preparation method of carbon-based and metal-based electrode arrays
  • Low-cost and high-precision preparation method of carbon-based and metal-based electrode arrays

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preparation example Construction

[0039] Preparation of conductive material dispersion:

[0040] Dispersion 1

[0041] Add 60mg of single-walled carbon nanotubes (SWNTs) to 500mL of 5mM sodium dodecyl sulfate water (SDS) solution, ultrasonically disperse in a 50W ultrasonic instrument for 2 hours, and leave the black solution at room temperature for 2 days, collect The upper layer black solution, obtains the single-walled carbon nanotube stock solution dispersed in the SDS aqueous solution.

[0042] Dispersion 2

[0043] Add 2.5g of graphite powder to 500mL of N-methylpyrrolidone (NMP) solvent, ultrasonically disperse it in a 50W ultrasonic instrument for 6 hours, and leave the resulting black solution at room temperature for 2 days, collect the upper layer of the black solution, and obtain a solution dispersed in NMP Graphene stock solutions in .

[0044] Dispersion 3

[0045] Add 25mg of acetylene black to 5mL of N-methylpyrrolidone (NMP) solvent, ultrasonically disperse in a 50W ultrasonic instrument fo...

Embodiment 1

[0069] The filter template 1 was installed on the M50 cup filter of Shanghai Mosu Company, and its original 50mm diameter stainless steel backing plate was replaced by a porous titanium sheet with a diameter of 50mm and a pore diameter of 0.45 μm. Add 10mL of Dispersion 1 to 100mL of deionized water and stir evenly, ultrasonicate for 5 minutes, pour the solution directly into the filter cup of M50 cup filter, filter and dry under reduced pressure, then add 400mL of deionized water to wash several times, to remove residual SDS. The kraft paper template filter membrane with the conductive layer of single-walled carbon nanotubes deposited in the electrode array area was placed in a vacuum oven at 60°C and dried for 2 hours to obtain a single-walled carbon nanotube electrode array with a mixed cellulose filter membrane as a carrier and kraft paper partitions. Membrane resistance about 30Ω / sq (see figure 2 ).

Embodiment 2

[0071] Install the filter template 2 on the M50 cup filter of Shanghai Mosu Company, and wet it with 25% ethanol aqueous solution by volume, and replace the original 50mm stainless steel backing plate with a porous titanium sheet with a diameter of 50mm and a pore size of 0.45μm. Add 10mL of Dispersion 1 to 100mL of deionized water and stir evenly. Sonicate for 5 minutes. Pour the solution directly into an M50 filter cup equipped with a template filter membrane, filter under reduced pressure and drain, then add 400mL of deionized water to wash several times. , to remove residual SDS. Soak the PET template filter membrane with the conductive layer of single-walled carbon nanotubes deposited in the electrode array area in ethanol for 1 minute, carefully peel off the PET tape from the nitrocellulose filter membrane, and dry it in a vacuum oven at 60°C for 2 hours to obtain nitric acid The cellulose filter membrane is the single-walled carbon nanotube electrode array of the carrie...

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Abstract

The invention discloses a low-cost and high-precision preparation method of carbon-based and metal-based electrode arrays. The low-cost and high-precision preparation method comprises the steps that laser engraving, photosensitive seal and other formwork construction technologies are adopted, an independently designed electrode array filtering area is constructed on the surface of a filtering membrane, a formwork filtering principle is used for controlling a conductive material and a modified material to form an electrode array on the surface of the filtering membrane, and the carbon-based andmetal-based electrode arrays of different types are prepared in batch through subsequent rendition or packaging treatment. According to the low-cost and high-precision preparation method of the carbon-based and metal-based electrode arrays, the preparation process is simple, the precision is high, the materials are saved, the pollution is low, the cost is low, a conductive material dispersion solution of a low concentration can be used, and the electrode arrays of various materials can be rapidly prepared in batch. The prepared electrode arrays have the advantages that the resistance is low (resistance of carbon-based electrode arrays is less than 30 omega / sq, and resistance of metal-based electrode arrays is less than 2omega / sq of), the structural composition is easy to adjust and control, the suitable substrates are wide, the homogeneity and the reproducibility are good, various deficiencies of commercial silk-screen printing electrodes can be effectively overcome, and the low-costand high-precision preparation method of the carbon-based and metal-based electrode arrays have wide application prospects in fields of environmental protection, food safety, disease diagnosis and thelike.

Description

technical field [0001] The invention relates to the field of electronic device preparation, in particular to a low-cost and high-precision preparation method of carbon-based and metal-based electrode arrays. Background technique [0002] According to relevant statistics, the scale of my country's in vitro diagnostic market has reached tens of billions of RMB per year. At present, optical detection methods such as chemiluminescence are mostly used in in vitro diagnosis, and the detection cost is relatively high, and the core technology is monopolized by foreign multinational companies. Compared with optical methods, electrochemical sensing technology has the characteristics of portable equipment, convenient use, and low detection cost. The large-scale popularization of electrochemical blood glucose meters has proved its application advantages in low-cost, portable, and rapid biochemical analysis. However, the screen-printed carbon electrodes used in electrochemical blood glu...

Claims

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Application Information

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IPC IPC(8): G01N27/30G01N27/327B82Y30/00
CPCB23K26/362B82Y30/00C01B2202/02C01B2202/22C01P2006/40G01N27/308G01N27/327
Inventor 胡成国宋梦梦
Owner WUHAN UNIV
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