Three-source one-body intumescent flame retardant, hybrid intumescent flame retardant grafted by using three-source one-body intumescent flame retardant as well as preparation method and application of three-source one-body intumescent flame retardant and hybrid intumescent flame retardant

Abstract

The invention discloses a three-source one-body intumescent flame retardant, a hybrid intumescent flame retardant grafted by using the three-source one-body intumescent flame retardant as well as a preparation method and application of the three-source one-body intumescent flame retardant and the hybrid intumescent flame retardant, wherein the structural general formulas of the three-source one-body intumescent flame retardant and the hybrid intumescent flame retardant are respectively as shown in the specification, and the three-source one-body intumescent flame retardant or the hybrid intumescent flame retardant is used for a thermoplastic elastomer, rubber, polyolefin plastic and aliphatic polyester, the epoxy resin and the unsaturated resin are not required to be compounded when used in flame retardancy, the proportion of phosphorus, nitrogen and carbon elements is appropriate, the flame-retardant efficiency is high, the addition amount of the flame retardant can be greatly reduced, the cost is reduced, the influence on the mechanical property of the base material is small, the water resistance is better, and the initial decomposition temperature is higher.

Description

technical field [0001] The invention belongs to the technical field of a three-source intumescent flame retardant, a hybrid intumescent flame retardant and a polyurethane elastomer grafted with it, and their preparation technology, and specifically relates to a class of three-source intumescent flame retardant, The organic-inorganic hybrid expansion flame retardant formed by grafting layered double hydroxides and their preparation method and application. Background technique [0002] Thermoplastic polyurethane, abbreviated as TPU. The excellent comprehensive performance of TPU determines that it has a wide range of applications, and can be used in wire and cable, automobiles, construction, mining, mechanical devices, footwear products, medical and aerospace and other fields. However, like most polymer materials, TPU has flammable characteristics, burns rapidly and violently, and the flame spreads quickly. The combustion process releases a large amount of heat and toxic gase...

AI Technical Summary

Problems solved by technology

However, there are not only few reports on the three-source intumescent flame retardant at present, but also in the limited reports, the three-source intumescent flame retardant still has high addition, low thermal stability, high water solubility and compatibility with polymers. gender issues

Such as CN107652324A has announced a kind of synthesis method and application of three sources in one, although it has been confirmed that the intumescent flame retardant of three sources in one has better flame retardant effect than the intumescent flame retardant formed by adding independently, but on the one hand the amount of addition It is still high and has a significant impact on the mechanical properties of polymers. On the other hand, its initial decomposition temperature is low, which is not suitable for the flame retardancy of most polymers. In addition, because its structure contains more ionic bonds, its water-soluble High resistance, resulting in flame retardants easy to absorb moisture and fail

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