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Solvent-free UV (ultraviolet) adhesive and preparation method of automobile shipment and paint surface protective film using same

An adhesive and solvent-free technology, applied in the direction of coating, etc., can solve the problems of inconvenient cleaning of the surface of the car body, poor bonding of the curved surface, and rising bond strength, etc., and achieve a product that is not easy to shrink, has high ductility and toughness, and is easy to spray. Effect

Inactive Publication Date: 2019-06-14
新纶电子材料(常州)有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] In the domestic market, protective films for automobile shipments are mainly PE protective films, mainly multi-layer PE co-extruded self-adhesive protective films or coated with acrylic glue on PE film materials. Part of the residual glue caused by peeling off the film due to factors such as light, heat, and oxygen will be affected by heat, oxygen, and ultraviolet rays during automobile transportation, and the bonding strength of the adhesive layer to the automobile body will increase significantly
When the protective film needs to be peeled off from the body, the adhesive will remain on the surface of the body more or less, causing unnecessary pollution, which makes cleaning the surface of the body inconvenient
Of course, this kind of PE protective film cannot be used as a car paint protection film; as a mainstream car paint protection film in the market, the product material is a polyurethane film, which contains anti-UV polymers, anti-yellowing, and has super strong Excellent toughness, wear resistance, non-yellowing, anti-collision, after installation, it can isolate the car paint surface from the air, prevent acid rain, anti-oxidation, resist scratches, and protect the paint surface of the car for a long time. Wet film, and then slowly use a soft scraper to remove water vapor and air bubbles, which is more inconvenient to operate

Method used

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  • Solvent-free UV (ultraviolet) adhesive and preparation method of automobile shipment and paint surface protective film using same
  • Solvent-free UV (ultraviolet) adhesive and preparation method of automobile shipment and paint surface protective film using same
  • Solvent-free UV (ultraviolet) adhesive and preparation method of automobile shipment and paint surface protective film using same

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0024] Prepare solvent-free UV adhesive composition: put 43g aliphatic urethane acrylate 654 (double bond chemical), 35g propylene oxide neopentyl glycol diacrylate EM2251 (Changxing Chemical Co., Ltd.), 10g ethyl acetate into a 250ml shading barrel Oxidized trimethylolpropane triacrylate EM2380 (Changxing Chemical Co., Ltd.) and 0.2g light stabilizer 292 (BASF), 0.5g anti-blocking agent MEK-AB-402 (Nano silica slurry, Nissan Chemical Co., Ltd.) , 1g fluorine additives (Daikin Fluorochemicals), 0.5g UV3510 (BYK Chemie) and 8g photoinitiator 184 (Tianjin Tianjiao Chemical Co., Ltd.), after adding, stir at 300rpm for 60min, then let stand for more than 60min Naturally defoams to obtain a solvent-free UV coating composition;

[0025] Spraying solvent-free UV adhesive process: Use a sprayer to spray UV adhesive on the imitation car paint surface to form a uniform UV adhesive layer with a thickness of 50μm, and then irradiate it with a UV lamp with an ultraviolet light intensity of 15...

Embodiment 2

[0027] To prepare a solvent-free UV adhesive composition: put 50g aliphatic urethane acrylate 654 (double bond chemical), 30g propylene oxide neopentyl glycol diacrylate EM2251 (Changxing Chemical Co., Ltd.), 9g ethyl acetate in a 250ml shading barrel Oxidized trimethylolpropane triacrylate EM2380 (Changxing Chemical Co., Ltd.) and 0.5g light stabilizer 292 (BASF), 1.2g anti-blocking agent MEK-AB-402 (Nano silica slurry, Nissan Chemical Co., Ltd.) , 1.5g fluorine additives (Daikin Fluorochemicals), 1.0g UV3500 (BYK Chemie) and 6.8g photoinitiator 184 (Tianjin Tianjiao Chemical Co., Ltd.), after adding, stir at a medium speed of 300rpm for 60min, then statically Leave for more than 60 minutes to defoam naturally to obtain a solvent-free UV coating composition;

[0028] Spraying solvent-free UV adhesive process: Use a sprayer to spray UV adhesive on the imitation car paint surface to form a uniform UV adhesive layer with a thickness of 50μm, and then irradiate it with a UV lamp wit...

Embodiment 3

[0030] Prepare solvent-free UV adhesive composition: put 60g aliphatic urethane acrylate 654 (double bond chemical), 25g propylene oxide neopentyl glycol diacrylate EM2251 (Changxing Chemical Co., Ltd.), 3g ethyl acetate into a 250ml shading barrel Oxidized trimethylolpropane triacrylate EM2380 (Changxing Chemical Co., Ltd.) and 0.8g light stabilizer 292 (BASF) 2.0g anti-blocking agent MEK-AB-402 (Nano silica slurry, Nissan Chemical Co., Ltd.), 2.0g fluorine additives (Daikin Fluorochemicals), 2.0g UV3500 (BYK Chemical) and 4g photoinitiator 184 (Tianjin Tianjiao Chemical Co., Ltd.), after adding, stir at 300rpm medium speed for 60min, then let stand for more than 60min Naturally defoams to obtain a solvent-free UV coating composition;

[0031] Spraying solvent-free UV adhesive process: Use a sprayer to spray UV adhesive on the imitation car paint surface to form a uniform UV adhesive layer with a thickness of 50μm, and then irradiate it with a UV lamp with an ultraviolet light i...

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Abstract

The invention discloses a solvent-free UV (ultraviolet) adhesive, which comprises the following components in percentage by mass: 45-60% of acrylate oligomer; 25-35% of a diluent monomer A; 3-10% of adiluent monomer B; 0.2-0.8% of a light stabilizer; 4-10% of a photoinitiator; 0.5-2% of a surface auxiliary agent A; 1-2% of a surface auxiliary agent B; and 0.5-2% of a surface auxiliary agent C. According to the solvent-free UV (ultraviolet) adhesive provided by the invention, coating a base material is not needed; the solvent-free UV adhesive is uniformly sprayed on the surface of the automobile in a direct spraying manner; after being irradiated by a low-strength UV lamp, the adhesive is crosslinked to form a film, a uniform and compact transparent protective film is formed on the surfaceof automobile paint, the adhesive is not afraid of the curved surface and dead angles of an automobile body, and a uniform and compact coating can be perfectly formed on the surface of the automobilebody by 360 degrees without dead angles, so that common automobile shipment protective films and paint surface protective films on the market are replaced.

Description

Technical field [0001] The invention belongs to the technical field of adhesives, and in particular relates to a solvent-free UV adhesive and a method for preparing an automobile shipping and paint protective film using the adhesive. Background technique [0002] With the improvement of living standards, more and more cars are entering ordinary households, and the number of cars in the market is getting higher and higher. After the automobile is assembled by the production enterprise, it enters the transportation channel and is sent to all parts of the country. During transportation, the car body is hit by sunlight, dust, stones, and sand, and the paint on the surface of the car will be damaged, causing unnecessary trouble in the sales link. This requires a surface for the car during transportation. Protection to prevent damage to the surface of the car body. Because of this, the protective film for automobile shipments came into being, which effectively solves the problem of d...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09D4/02C09D7/61
Inventor 夏有贵王恒龙冲顾叶梅倪惠峰
Owner 新纶电子材料(常州)有限公司
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