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Structure with oxide thin film and its preparation method

A technology of oxide film and oxide layer, applied in semiconductor/solid-state device manufacturing, electrical components, circuits, etc., can solve problems such as device failure, device failure, device performance degradation, etc., to ensure that it will not fail, ensure effect of function

Active Publication Date: 2022-01-21
SHANGHAI ADVANCED RES INST CHINESE ACADEMY OF SCI
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0007] These oxygen vacancies will cause changes in the properties of the oxide film such as electrical conductivity, work function, and refractive index, which will cause the device to fail to achieve certain functions, that is, cause the performance of the device to decay, and seriously cause the failure of the entire device

Method used

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  • Structure with oxide thin film and its preparation method
  • Structure with oxide thin film and its preparation method
  • Structure with oxide thin film and its preparation method

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Experimental program
Comparison scheme
Effect test

Embodiment 1

[0072] see Figure 1 to Figure 3 , the invention provides a method for preparing a structure with an oxide film, the method for preparing a structure with an oxide film includes the following steps:

[0073] 1) Provide the substrate;

[0074] 2) forming the oxygen atom diffusion barrier layer on the upper surface of the substrate;

[0075] 3) forming the oxide film on the upper surface of the oxygen atom diffusion barrier layer.

[0076] In step 1), see figure 1 , providing a substrate 3 .

[0077] As an example, the substrate 3 may include, but not limited to, a silicon (Si) substrate.

[0078] In step 2), see figure 2 , forming the oxygen atom diffusion barrier layer 2 on the upper surface of the substrate 3 .

[0079] As an example, the upper surface of the substrate 3 may be treated by using a nitric acid oxidation treatment process, an ultraviolet light-induced oxidation process, an ozone-containing water wet oxidation process, a dry oxidation process, an ozone tre...

Embodiment 2

[0086] read on image 3 , the present invention also provides a structure with an oxide film, the structure with an oxide film comprising:

[0087] Oxide film 1;

[0088] Oxygen atom diffusion barrier layer 2, the oxygen atom diffusion barrier layer 2 is located on the lower surface of the oxide film 1;

[0089] A substrate 3 , the substrate 3 is located on the lower surface of the oxygen atom diffusion barrier layer 2 .

[0090] As an example, the oxide thin film 1 may include any oxide layer that can be used as a functional layer such as a carrier transport layer or an insulating layer. For example, the oxide film 1 may include but not limited to molybdenum oxide (MoO 3 )film.

[0091] As an example, the substrate 3 may include but not limited to a silicon substrate.

[0092] As an example, the oxygen atom diffusion barrier layer 2 may include a silicon oxide layer, and the thickness of the oxygen atom diffusion barrier layer 2 may include 1 nanometer (nm) to 10 nanomet...

Embodiment 3

[0095] see Figure 4 to Figure 9 , the present invention also provides a method for preparing a structure with an oxide film, the method for preparing a structure with an oxide film includes the following steps:

[0096] 1) preparing the oxide film;

[0097] 2) Forming the oxygen atom diffusion barrier layer on the upper surface of the oxide film.

[0098] As an example, see Figure 4 , before performing step 1), the following step is also included: providing a substrate 3 .

[0099] As an example, the substrate 3 may include, but not limited to, a silicon (Si) substrate.

[0100] In step 1), see Figure 5, preparing the oxide thin film 1 . Specifically, the oxide thin film 1 is prepared on the upper surface of the substrate 3 .

[0101] As an example, the oxide thin film 1 may be formed on the upper surface of the oxygen atom diffusion barrier layer 2 by using techniques such as sputtering, evaporation, chemical vapor deposition (CVD) or atomic layer deposition (ALD). ...

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Abstract

The invention provides a structure with an oxide film and a preparation method thereof, comprising the following steps: preparing the oxide film, at least one surface of the oxide film is formed with an oxygen atom diffusion barrier layer. In the present invention, by forming an oxygen atom diffusion barrier layer on at least one surface of the oxide film, the direct contact between the oxide film and the substrate or the metal electrode can be avoided, and the oxygen atoms in the oxide film will not be captured by the substrate or the metal electrode. Ensure that the conductivity, work function and refractive index of the oxide film will not change, so as to ensure the function of the device and ensure that the device will not fail.

Description

technical field [0001] The invention belongs to the technical field of semiconductor materials and device preparation, and in particular relates to a structure with an oxide film and a preparation method thereof. Background technique [0002] Oxide thin films are widely used in semiconductor devices as carrier transport layers, insulating layers and other functional layers. Oxide thin films can be deposited by sputtering, chemical vapor deposition (Chemical Vapor Deposition, CVD), atomic layer deposition (Atomic Layer Deposition, ALD) and other techniques are prepared on the surface of the substrate (such as Si). The quality of the interface between the oxide film and the substrate greatly affects the performance of the device. [0003] When the oxide film is grown on a Si substrate, according to the Gibbs free energy formula: [0004] ΔG=ΔH-TΔS [0005] When the enthalpy of formation of the oxide film is greater than that of SiO 2 (-859.4kJ / mol) (ΔH<0,ΔG<0), Si wi...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): H01L21/02
Inventor 李东栋李敬业殷敏曹双迎鲁林峰方小红黄淳陈小源
Owner SHANGHAI ADVANCED RES INST CHINESE ACADEMY OF SCI