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High-corrosion-resistant Cu alloy and preparation method thereof

A technology of copper alloy and high corrosion resistance, which is applied in the field of high corrosion resistance copper alloy and its preparation, can solve the problems that the corrosion resistance of copper-nickel alloy does not meet this standard, and achieve good resistance to sulfur-containing corrosion, enhanced corrosion resistance Atmospheric corrosion ability, effect of improving strength

Inactive Publication Date: 2019-07-05
GRIMAT ENG INST CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0004] In recent years, high-corrosion-resistant copper-nickel alloys have been increasingly used in various fields. According to reports in foreign books, high-corrosion-resistant copper-nickel alloys containing 3.5% Cl - +0.5%S 2- The corrosion rate of seawater can reach below 10μm / a, while the corrosion resistance of domestic copper-nickel alloys has not yet reached this standard

Method used

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preparation example Construction

[0020] The preparation method of the high corrosion-resistant copper alloy of the present invention comprises the following steps: batching-melting and casting-hot extrusion-hot forging-finished product. Its specific process steps include:

[0021] (1) Billet melting and casting: use pure copper, pure iron, pure manganese, pure nickel, pure zinc and other metals with a purity greater than 99.9% as raw materials, and melt them in an intermediate frequency induction melting furnace according to the alloy composition, and the melting temperature is 1150-1270 ℃, after heat preservation, pour into a copper ingot of Φ250mm at a temperature of 1200-1250℃;

[0022] (2) Hot extrusion process: After the copper ingot is peeled, it is hot-extruded at a temperature of 600-900°C, and extruded into a copper rod of Φ50mm;

[0023] (3) Hot forging process: the extruded copper alloy bar is forged and deformed at 500-900°C, first forged in one direction, and the pass reduction is 20-30%; then t...

Embodiment 1

[0025] Its production process is as follows: ingredients - casting - hot extrusion - hot forging - finished product

[0026] The specific process is as follows: smelting in an intermediate frequency induction melting furnace, the ingredients are distributed as shown in Table 1, and the smelting temperature is 1180°C. Before smelting, the cathode copper and alloy materials such as iron, manganese, nickel and zinc are evenly added into the furnace, and the large and small material blocks are placed as evenly as possible, and the materials are as dense as possible. During smelting, it is kept at 1200°C for standing still, and after slag removal, it is poured into a Φ250mm ingot at a temperature of 1200°C. After the ingot is peeled, it is hot-extruded at a temperature of 860°C, and extruded into a Φ50mm copper rod. Then, hot forging the copper alloy bar at 500°C for 4 times, turning the billet 90° after each forging, with a reduction of 20% per pass and a total reduction of 80%, ...

Embodiment 2

[0028] Its production process is as follows: ingredients - casting - hot extrusion - hot forging - finished product

[0029] The specific process is as follows: smelting in an intermediate frequency induction melting furnace, the ingredients are distributed as shown in Table 1, and the smelting temperature is 1200°C. Before smelting, the cathode copper and alloy materials such as iron, manganese, nickel and zinc are evenly added into the furnace, and the large and small material blocks are placed as evenly as possible, and the materials are as dense as possible. During smelting, it is kept at 1200°C for standing still, and after slag removal, it is poured into a Φ250mm ingot at a temperature of 1250°C. After the ingot is peeled, it is hot-extruded at a temperature of 700°C and extruded into a Φ50mm copper rod. Then, hot forging the copper alloy bar at 850°C for 3 times, turning the billet 90° after each forging, with a reduction of 30% per pass and a total reduction of 90%, a...

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Abstract

The invention relates to a high-corrosion-resistant Cu alloy and a preparation method thereof, and belongs to the technical field of metal materials and preparation thereof. The high-corrosion-resistant Cu alloy comprises the following components in percentage by mass: 8-15% of Ni, 1.0-2.0% of Fe, 0.2-1.0% of Mn, 0.05% of Zn and the balance Cu. The preparation method comprises the following steps:composition; fusion and casting; hot extrusion; hot forging; and finished product manufacturing. Through the addition of Fe, Mn, Ni, Zn and other elements, the corrosion-resistant property of the high-corrosion-resistant Cu alloy in sulfur-containing seawater can be improved; meanwhile, the high processability of the high-corrosion-resistant Cu alloy can be guaranteed; under the circumstance of 3.5%Cl(-)+0.5%S(2-), the corrosion rate of the high-corrosion-resistant Cu alloy, namely a Cu alloy material prepared through the preparation method, is less than 10 micrometers / a, far below those of other common corrosion-resistant Cu alloy materials; and accordingly, the high-corrosion-resistant Cu alloy is particularly applicable to the manufacturing of large corrosion-resistant pipes in ocean engineering.

Description

technical field [0001] The present invention relates to a kind of high anti-corrosion copper alloy and its preparation method, especially to a kind of 3.5% Cl at room temperature - +0.5%S 2- A copper alloy with high corrosion resistance under certain conditions and a preparation method thereof belong to the technical field of metal materials and its preparation. Background technique [0002] At present, high corrosion-resistant copper alloys are widely used for cladding ship hulls, ship rudders, seawater desalination pipelines, fire water pipelines, compressed air pipelines, auxiliary condenser condenser tubes of steam ships, lubricating oil cooling pipelines, refrigeration devices and Heat exchange tubes for seawater desalination devices, etc., are widely used in the field of marine engineering. The research on corrosion-resistant copper alloys used in marine environments has a long history abroad, and a variety of high-corrosion-resistant copper alloy pipes have been dev...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C22C9/06C22C1/02C22F1/08
CPCC22C1/02C22C9/06C22F1/08
Inventor 王强松刘冬梅刘芳
Owner GRIMAT ENG INST CO LTD