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Low-odor rolling oil for steel cold rolling and use method of rolling oil

A technology for rolling oil and peculiar smell, applied in the field of rolling oil, can solve the problems affecting the lubricity of rolling oil, low peculiar smell, and no special explanation, and achieve the effect of reducing atomization effect and reducing peculiar smell

Inactive Publication Date: 2019-08-20
BAOSHAN IRON & STEEL CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] ZL201510362873.1, a cold-rolled emulsion odor gas purification device and method, this technology uses technology to filter or centrifugally collect the odor-rich rolling oil and other substances in the emulsion to remove the gas with low odor, Then, the catalyst rich in iron and manganese is used to further decompose the odorous chemical substances in the gas. Professional catalyst, the overall technical and economic efficiency is low, it is not suitable for large-scale promotion and use
[0007] ZL201610173105.7, a water-based metalworking lubricant containing nano-molybdenum disulfide and its preparation method, mainly uses various water-soluble lubricating compounds, such as triethanolamine, aqueous sodium polyacrylate, silane coupling agent and sodium diacetate and other substances, and then use nano-molybdenum disulfide powder as a cold-rolling lubricant. Since this technology completely uses water-soluble substances, it can avoid the odor problem of traditional cold-rolling emulsions. However, due to the use of nano-molybdenum disulfide in such substances Molybdenum sulfide particles, which will affect the subsequent strip coating performance after the strip remains, so it is difficult to apply and promote
[0008] ZL201280012958.1, an artificially synthesized compound that effectively masks odors, mainly 1-(2-hydroxyphenyl)-3-(pyridin-4-yl)propan-1-one / salt, etc., although such substances have Good odor masking effect, but the price is relatively expensive, and it will significantly affect the lubricity of rolling oil when used in cold rolling oil, so it is not practical
[0009] To sum up, the odor elimination of cold-rolled emulsion is mainly through the post-treatment of the discharged gas, and for various chemical reagents that can eliminate the odor of cold-rolled emulsion, there will be high cost in the cold-rolling process. , problems that affect production performance, there is no special elaboration on the optimization of the components of rolling oil itself to reduce the generation of peculiar smell

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0037] Natural oils: palm oil 0;

[0038] Synthetic Lubricant: Trimethylolpropane Hexadecanoate 90%;

[0039] Surfactant: nonylphenol polyoxyethylene ether 1.5%, tallow amine polyoxyethylene ether 1.5%;

[0040] Extreme pressure antiwear agent: neopentyl glycol oleic acid synthetic ester 2.5%, phosphoric acid ester 3%

[0041] Antioxidant additive: 2,6-diisobutyl p-cresol 1.5%

[0042] Apply the emulsion prepared by the above-mentioned rolling oil to the scene, control the temperature of the emulsion at 55°C, the concentration is 1.5% in the #1-#4 stand of the cold rolling mill, and the iron powder concentration in the emulsion is controlled at 120ppm; The #5 rack of the continuous rolling mill uses a concentration of 0.7%, and the iron powder concentration of the emulsion is controlled at 65ppm.

[0043] The emulsion odor concentration measured in the equipment exhaust chimney of the cold rolling mill is 41.

Embodiment 2

[0045] Natural oils: palm oil 18%;

[0046] Synthetic Lubricant: Trimethylolpropane Hexadecanoate 75%;

[0047] Surfactant: 1% nonylphenol polyoxyethylene ether, 1% fatty alcohol polyoxyethylene ether with 16 carbon atoms;

[0048] Extreme pressure antiwear agent: Phosphate 4%

[0049] Antioxidant additive: 2,6-diisobutyl p-cresol 1%

[0050]Apply the emulsion prepared by the above-mentioned rolling oil to the field, control the temperature of the emulsion at 50°C, the concentration is 2.5% in the #1-#4 stands of the cold rolling mill, and the concentration of iron powder in the emulsion is controlled at 230ppm; The #5 rack of the continuous rolling mill uses a concentration of 0.8%, and the iron powder concentration of the emulsion is controlled at 95ppm.

[0051] The emulsion odor concentration measured in the equipment exhaust chimney of the cold rolling mill is 70%.

Embodiment 3

[0053] Natural oils: palm oil 25%;

[0054] Synthetic lubricating ester: trimethylolpropane hexadecanoate 67%;

[0055] Surfactant: nonylphenol polyoxyethylene ether 0.5%, octylphenol polyoxyethylene ether 0.5%, tallow amine polyoxyethylene ether 1%;

[0056] Extreme pressure antiwear agent: neopentyl glycol oleic acid synthetic ester 4.5% sulfurized

[0057] Antioxidant additive: 2,6-diisobutyl p-cresol 1.5%

[0058] Apply the emulsion prepared by the above-mentioned rolling oil to the field, control the temperature of the emulsion at 52°C, the concentration is 1.7% in the #1-#4 stands of the cold rolling mill, and the concentration of iron powder in the emulsion is controlled at 200ppm; The #5 rack of the continuous rolling mill uses a concentration of 0.8%, and the iron powder concentration of the emulsion is controlled at 87ppm.

[0059] The emulsion odor concentration measured in the equipment exhaust chimney of the cold rolling mill is 173.

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PUM

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Abstract

The invention discloses low-odor rolling oil for steel cold rolling. The rolling oil comprises the following components in percentage by mass: 0-30% of natural oil, 50-90% of synthetic lubricating grease, 0.8-4.5% of a surfactant, 2.0-6.5% of an extreme-pressure antiwear agent and 0.5-1.5% of an antioxidation additive. An emulsion prepared by using the rolling oil can effectively reduce the smellcaused by the natural oil with stink in the rolling oil, and the odor of the rolling oil is controlled to be at a very low level through reducing use of active sulfur compounds.

Description

technical field [0001] The invention relates to rolling oil, in particular to a low-odor rolling oil for cold rolling of steel and its application method. Background technique [0002] In the production of modern cold rolling mills, usually in the production of cold rolling technology, a complex emulsion system is used to spray a certain amount of emulsion on the roll gap and the surface of the strip. After the emulsion enters the rolling deformation zone, it first adheres to the The surface of the roll and the strip forms a thin lubricating oil film for lubrication, and the water can take away the heat of deformation and friction during the rolling process to play a role in cooling. The so-called cold rolling emulsion is a chemical product obtained by mixing 1-3% rolling oil and 97-99% water according to mass percentage. [0003] The cold rolling emulsion is sprayed in large quantities during production (usually >20m 3 / h), under the action of a large amount of heat fr...

Claims

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Application Information

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IPC IPC(8): C10M169/04C10N40/24
CPCC10M169/044C10M2207/023C10M2207/2835C10M2207/401C10M2209/104C10M2209/108C10M2217/06C10M2219/024C10M2223/04C10N2040/24C10N2030/24C10N2040/246
Inventor 邢德茂沈青福王康健叶学卫瞿培磊
Owner BAOSHAN IRON & STEEL CO LTD
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