Energy-saving cordierite zircon multiphase material and preparation method thereof

A zircon and cordierite technology, which is applied in the field of energy-saving cordierite-zircon composite phase materials and its preparation, can solve the problem that densification affects the uniformity of the temperature distribution of the green body, reduces the content of the cordierite crystal phase, and is safe. The impact is difficult to predict and other problems, to achieve the effects of green environmental protection large-scale production, good thermal shock stability and low production cost

Inactive Publication Date: 2019-09-06
WUHAN UNIV OF SCI & TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] "A method for synthesizing cordierite with solid waste" (ZL200810239264.7) patented technology, although coal gangue is used to synthesize cordierite in this technology, the carbon in coal gangue is oxidized at high temperature and forms a large number of holes, which reduces the strength of the product And cause uneven temperature distribution inside the green body; "A cordierite material prepared by using rare earth tailings and its manufacturing method" (ZL201210491530.1) patent technology, although this technology uses rare earth tailings to prepare cordierite, but the rare earth tailings The impact of radioactive elements in sand on the safety of personnel on site is difficult to predict
"Method for preparing cordierite ceramics from serpentine tailings" (ZL201210076854.9) patented technology, although this technology uses kaolin as the main raw material to synthesize cordierite, but a large number of pores formed by kaolin burning out affect the densification and also affect the inner body of the green body. Uniformity of temperature distribution
"Mulite lightweight insulation brick based on kyanite tailings and its preparation method" (ZL201410132749.1) patent technology, although this technology uses kyanite tailings containing zirconia as the main raw material to produce mullite lightweight Insulation products, but the introduction of a large amount of kyanite can easily cause cracks on the surface of the green body during high temperat

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0026] An energy-saving cordierite zircon composite phase material and a preparation method thereof. The preparation method described in this example is:

[0027] First, 40-45wt% of zircon tailings, 41-45wt% of talc fine powder and 13-15wt% of alumina fine powder are used as raw materials, and then 40-43wt% of water, 2-3wt% of the raw materials are added. Polyvinyl alcohol and 0.4-0.6wt% cerium oxide fine powder are mixed, ball-milled for 6-8 hours to obtain slurry; then the slurry is spray granulated to obtain granular powder; then the granular powder is machine-pressed into shape , under the condition of 1350-1370 ℃, heat preservation for 8-10 hours, and natural cooling to obtain energy-saving cordierite-zircon composite phase material.

[0028] The energy-saving cordierite-zircon composite phase material prepared in this example is analyzed by X-ray diffraction: the main crystalline phase is cordierite, and the secondary crystalline phase is zircon. The prepared energy-sa...

Embodiment 2

[0030] An energy-saving cordierite zircon composite phase material and a preparation method thereof. The preparation method described in this example is:

[0031] First, 45-50wt% of zircon tailings, 39-43wt% of talc fine powder and 11-13wt% of alumina fine powder are used as raw materials, and then 43-46wt% of water and 3-4wt% of the raw materials are added. Polyvinyl alcohol and 0.4-0.6wt% cerium oxide fine powder are mixed, ball-milled for 6-8 hours to obtain slurry; then the slurry is spray granulated to obtain granular powder; then the granular powder is machine-pressed into shape , heat preservation for 8 to 10 hours at 1360 to 1380 ° C, and natural cooling to obtain an energy-saving cordierite zircon composite material.

[0032] The energy-saving cordierite-zircon composite phase material prepared in this example is analyzed by X-ray diffraction: the main crystalline phase is cordierite, and the secondary crystalline phase is zircon. The prepared energy-saving cordieri...

Embodiment 3

[0034] An energy-saving cordierite zircon composite phase material and a preparation method thereof. The preparation method described in this example is:

[0035] First, 50-55wt% zircon tailings, 36-40wt% talc fine powder and 9-11wt% alumina fine powder are used as raw materials, and then 46-49wt% water and 2-3wt% of the raw materials are added. Polyvinyl alcohol and 0.6-0.8wt% cerium oxide fine powder are mixed, ball-milled for 6-8 hours to obtain a slurry; then the slurry is spray granulated to obtain a granular powder; then the granular powder is machine-pressed , heat preservation for 8 to 10 hours at 1370 to 1390 ° C, and natural cooling to obtain an energy-saving cordierite-zircon composite material.

[0036] The energy-saving cordierite-zircon composite phase material prepared in this example is analyzed by X-ray diffraction: the main crystalline phase is cordierite, and the secondary crystalline phase is zircon. The prepared energy-saving cordierite zircon composite ...

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Abstract

The invention relates to an energy-saving cordierite zircon multiphase material and a preparation method thereof. According to the technical scheme, firstly, 40-60 wt% of zircon tailings, 35-50 wt% offine talc powder and 5-15 wt% of fine aluminium oxide powder are taken as raw materials, the raw materials of 40-50 wt% of water, 2-4 wt% of polyvinyl alcohol and 0.4-0.8 wt% of fine cerium oxide powder are additionally added, mixing is carried out, and ball-milling is carried out for 6-8 hours to obtain pulp; then the pup is subjected to spray granulation to obtain granular powder, then the granular powder is press-formed, heat preservation is carried out for 8-10 hours at 1350-1420 DEG C, natural cooling is carried out, and the energy-saving cordierite zircon multiphase material is obtained. The preparation method of the energy-saving cordierite zircon multiphase material has the advantages that the production cost is low, the method is green and environmentally friendly, and the scaleproduction is facilitated; the prepared energy-saving cordierite zircon multiphase material not only has high strength, an obvious energy-saving effect and good thermal shock resistance, but also hasa wide application range.

Description

technical field [0001] The invention belongs to the technical field of cordierite zircon composite phase materials. Specifically, it relates to an energy-saving cordierite zircon composite phase material and a preparation method thereof. Background technique [0002] Tailings are one of the products of sorting operations in beneficiation, in which the content of target components is too low to be used for production. In fact, tailings are not completely useless waste and often contain components that can be used for other purposes. Realizing the resource utilization of tailings is not only to improve the utilization efficiency of mineral resources, but also an effective way to protect the ecological environment. Cordierite has extremely low thermal expansion coefficient, excellent shock stability and good chemical stability, and is widely used in high temperature kiln furniture and other fields. [0003] "A method of synthesizing cordierite from solid waste" (ZL2008102392...

Claims

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Application Information

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IPC IPC(8): C04B35/195C04B35/622
CPCC04B35/195C04B35/62204C04B2235/3217C04B2235/3229C04B2235/3427C04B2235/349C04B2235/77C04B2235/96
Inventor 向若飞李远兵李淑静王海路李仕祺
Owner WUHAN UNIV OF SCI & TECH
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