Thermochromic fiber and preparation method and application thereof

A technology of thermochromic and thermochromic materials, which is applied in fiber processing, fiber chemical characteristics, rayon manufacturing, etc., can solve the problems of single structure of thermochromic fibers, limited selection of raw materials, high preparation cost, etc., and achieve structural design Diversification, ensuring cycle stability, and high production efficiency

Inactive Publication Date: 2019-09-06
HUAZHONG UNIV OF SCI & TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] Aiming at the above defects or improvement needs of the prior art, the present invention provides a thermochromic fiber, its preparation and application, which obtains the core of the thermochromic fiber with a core-wrapped structure by adopting the thermosoftening drawing method in the optical fiber preparation process Layer, thereby solving the technical problems of the existing technology to prepare thermochromic fibers with single structure, high preparation cost, limited range of raw material selection and slow production speed.

Method used

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  • Thermochromic fiber and preparation method and application thereof
  • Thermochromic fiber and preparation method and application thereof
  • Thermochromic fiber and preparation method and application thereof

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preparation example Construction

[0047] The invention provides a method for preparing a thermochromic fiber, the thermochromic fiber is a fiber with a core-wrapped structure, the core layer of the core-wrapped structure is a thermochromic layer, the cladding is a protective layer, and the clad The layer is located outside the core layer; the thermochromic layer is prepared by adopting a thermosoftening wire drawing method, specifically: first obtain a preform rod of the thermochromic layer, and then perform thermosoft wire drawing on the preform rod to obtain the Thermochromic layer fibers; the thermosoftening drawing is a thermosoftening drawing method adopted in the optical fiber preparation process. After heating and softening the preform of the thermochromic layer, it is drawn into a fine thermochromic layer fiber whose diameter meets the requirement.

[0048] In some embodiments, the material used in the thermochromic layer includes a polymer-based composite material obtained by doping the first polymer ...

Embodiment 1

[0104] In the embodiment of the present invention, a thermochromic fiber with a sheath-core structure is firstly provided, which has certain stability, rubbing resistance and color fastness to washing, is suitable for wearing, and has a thermochromic temperature of 31°C.

[0105] figure 1 It is a schematic diagram of a thermochromic fiber with a circular cross-section prepared in this embodiment, wherein 1 is the core layer of the thermochromic fiber, and 2 is the cladding layer.

[0106] Wherein, the thermochromic fiber color-changing layer material is a composite material of thermochromic microcapsules and polymethyl methacrylate, the diameter of the color-changing layer is 100 μm, the cladding material is polymethyl methacrylate, and the thickness is 50 μm.

[0107] An embodiment of the present invention provides a thermochromic fiber method including: preparation of a thermochromic composite material, preparation of a preform and thermal drawing of the fiber.

[0108] The...

Embodiment 2

[0116] In the embodiment of the present invention, a thermochromic fiber with a sheath-core structure is firstly provided, which has certain stability, rubbing resistance and color fastness to washing, is suitable for wearing, and has a thermochromic temperature of 31°C.

[0117] Wherein, the thermochromic fiber color-changing layer material is a composite material of thermochromic microcapsules and polymethyl methacrylate, the diameter of the color-changing layer is 1000 μm, the cladding material is polymethyl methacrylate, and the thickness is 50 μm.

[0118] An embodiment of the present invention provides a thermochromic fiber method including: preparation of a thermochromic composite material, preparation of a preform and thermal drawing of the fiber.

[0119] The preparation method of thermochromic material comprises the following steps: (1) take by weighing 100g polymethyl methacrylate, and measure 200ml dimethylacetamide to mix, and place on the magnetic stirrer heating ...

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Abstract

The invention belongs to the field of functional fiber, and particularly relates to thermochromic fiber and a preparation method and application thereof. The thermochromic fiber is of a core-claddingstructure, a core layer of the core-cladding structure is a thermochromic layer, and the cladding layer is a protection layer and positioned outside the core layer. The thermochromic layer is preparedby adopting a thermal softening drawing method. The preparation method includes: obtaining a prefabricated rod of the thermochromic layer, and performing thermal softening drawing on the prefabricated rod to obtain the thermochromic layer fiber, wherein thermal softening drawing is a thermal softening drawing method adopted in an optical fiber preparation process. Compared with existing thermochromic fiber preparation methods, the drawing process is wide in thermochromic material and polymer base material selection range and diverse in structure design; fiber different in section structure can be designed, distribution of different thermochromic materials in the fiber can be controlled accurately, and the preparation method is high in production efficiency and suitable for large-scale production.

Description

technical field [0001] The invention belongs to the field of functional fibers, and more specifically relates to a thermochromic fiber, its preparation and application. Background technique [0002] People's requirements for the functionalization and intelligence of materials are getting higher and higher, and the market for textile and clothing functions is gradually expanding. Controllable color-changing smart fabrics have become a hot field of exploration and research by scholars from all over the world. In addition to being beautiful, the combination of smart color-changing clothing and sensor devices can also achieve emotional expression and health monitoring. Color-changing fibers are the basis of intelligent color-changing fabrics. The color of this material will change when it is stimulated by external light, heat, humidity, electricity, etc. The color-changing fiber first originated in the United States, and a photochromic fiber was developed to meet the requiremen...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): D01F8/10D01F1/10D01D5/12D01D5/34D02J3/00
CPCD01D5/12D01D5/34D01F1/10D01F8/10D02J3/00
Inventor 陶光明李攀董英琴吴嘉威
Owner HUAZHONG UNIV OF SCI & TECH
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