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Titanium alloy boronizing method

A titanium alloy and boronizing technology, applied in metal material coating process, coating, solid-state diffusion coating, etc., can solve the problems of long processing time, insufficient thickness of boronizing layer, environmental pollution, etc., and reach the thickness of boronizing layer Improved effect

Inactive Publication Date: 2019-11-29
HOHAI UNIV CHANGZHOU
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

However, chemical heat treatment is usually carried out in a boronizing agent and a boronizing catalyst configured in a certain proportion. The production environment is harsh and it is easy to pollute the environment.
At the same time, there are defects such as long processing time, insufficient boronizing layer thickness, subsequent processing and high cost in the prior art.

Method used

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  • Titanium alloy boronizing method
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Experimental program
Comparison scheme
Effect test

Embodiment 1

[0018] First, take 2 / 3 of deionized water in a 10L tank, dissolve 200g of cetyltrimethylammonium bromide and 4000g of triethanolamine in turn, and after all the reagents in the tank are dissolved, 3000g of titanium fluoroborate and 4000g of hydroxide Pour the sodium into the bath solution under rapid stirring until it is completely mixed, and finally add water to 10L to obtain an oxidation electrolyte, and put the titanium alloy Ti-6Al-4V into the prepared oxidation electrolyte for the first micro-arc plasma deal with. The first micro-arc plasma treatment used Ti-6Al-4V as the anode and graphite as the cathode. The pulse width of the pulse voltage of the first micro-arc plasma treatment and the second micro-arc plasma treatment is 10ns, and the pulse voltage amplitude is 800V. After applying the pulse voltage for 3 seconds, the Ti-6Al-4V was taken out for the second micro-arc plasma treatment. In the second micro-arc plasma treatment, Ti-6Al-4V was used as the cathode and gr...

Embodiment 2

[0020] First, take 2 / 3 of deionized water in a 10L tank, dissolve 300g of tetramethylammonium hydroxide, 2000g of triethanolamine in sequence, and after all the reagents in the tank are dissolved, put 2000g of nickel fluoroborate and 1500g of potassium hydroxide in a fast Pour it into the bath solution under stirring until it is completely mixed, and finally add water to 10L to obtain an oxidation electrolyte. The titanium alloy Ti-2Al-2.5Zr was put into the prepared oxidation electrolyte for the first micro-arc plasma treatment. The first micro-arc plasma treatment used Ti-2Al-2.5Zr alloy as the anode and graphite as the cathode. The pulse width of the pulse voltage of the first micro-arc plasma treatment and the second micro-arc plasma treatment is 100 ns, and the pulse voltage amplitude is 1000V. After applying the pulse voltage for 3 seconds, the Ti-2Al-2.5Zr was taken out and subjected to the second micro-arc plasma treatment. In the second micro-arc plasma treatment, T...

Embodiment 3

[0022] First, take 2 / 3 of deionized water in a 10L tank, dissolve 150g of cetyltrimethylammonium bromide and 3000g of glycerol in turn, and after all the reagents in the tank are dissolved, mix 2500g of nickel fluoroborate and 1200g of hydrogen Sodium oxide was poured into the bath solution under rapid stirring until it was completely mixed, and finally water was added to 10L to obtain an oxidation electrolyte, and Ti3Al was put into the prepared solution for the first micro-arc plasma treatment. The first micro-arc plasma treatment uses Ti3Al as the anode, graphite as the cathode, the nanosecond pulse width is 50 ns, and the pulse voltage amplitude is 1500V, that is, Ti3Al is placed in the solution, and the nanosecond pulse voltage is applied forward for 5 seconds Then take it out and carry out the second micro-arc plasma treatment. The second micro-arc plasma treatment uses Ti3Al as the cathode, graphite as the anode, and applies a pulse voltage for 8 minutes. The thickness ...

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Abstract

The invention discloses a titanium alloy boronizing method and belongs to the technical field of surface treatment. The titanium alloy boronizing method comprises the following steps that treatment fluid is prepared; first-time micro-arc plasma treatment is carried out; and second-time micro-arc plasma treatment is carried out by taking a titanium alloy with the first-time micro-arc plasma treatment being completed as a cathode. The thickness of a boronizing layer can be effectively increased.

Description

technical field [0001] The invention relates to a titanium alloy boronizing method, which belongs to the technical field of surface treatment. Background technique [0002] Titanium alloy has the advantages of high specific strength and good corrosion resistance, but its surface hardness is low, so its application in aerospace, marine equipment and other fields is limited. Therefore, most of the existing technologies carry out surface treatment on titanium alloys to improve their surface hardness. Commonly used surface treatment processes include chemical heat treatment, magnetron sputtering and thermal spraying. However, chemical heat treatment is usually carried out in a boronizing agent and boronizing catalyst configured in a certain proportion, and the production environment is harsh and easy to pollute the environment. At the same time, the prior art has defects such as long processing time, insufficient boronizing layer thickness, subsequent processing, and high cost...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C23C8/42
CPCC23C8/42
Inventor 蒋永锋包晔峰陈秉岩杨可
Owner HOHAI UNIV CHANGZHOU