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Preparation method of novel glass slag filter material with negatively charged modified surface

A negatively charged surface and filter material technology, which is applied in the fields of material science and adsorption science, can solve the problems of upper filter material loss, high production costs of water plants, and biofilm growth, so as to improve the filtration and adsorption effect and be economical. The effect of value and environmental significance

Inactive Publication Date: 2019-12-10
天津华清环宇环保科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

During the actual use of ordinary quartz sand filters, it is found that the quartz sand filter material has biofilm growth, low mechanical strength, and consumes a lot of flushing water. It often needs to be cleaned and backwashed regularly, and the filter material is replenished regularly to maintain its continuous filtration. Effect
It is found that after the quartz sand filter material has been used for a period of time, the biggest problem is the growth of biofilm. Due to the pores and ravines on the surface of ordinary quartz sand, the biofilm often fits closely with the surface of the filter material, making the intensity of backwashing and backwashing time It is getting bigger and bigger, which leads to the loss of the upper filter material, the continuous increase of the backwash water volume, the high production cost of the water plant, and the final replacement of the saturated filter material.

Method used

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  • Preparation method of novel glass slag filter material with negatively charged modified surface
  • Preparation method of novel glass slag filter material with negatively charged modified surface
  • Preparation method of novel glass slag filter material with negatively charged modified surface

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0018] Step 1. Pretreatment of glass slag surface hydroxylation: a. Take 5 g of 24-mesh glass slag raw material, and use superior grade pure (GR) 99.8% ethanol to repeatedly clean the glass slag raw material for 6 times; b. Wash the cleaned glass Put the slag raw materials into beakers filled with deionized water, ethanol, and acetone in turn for 10 minutes; c. use nitrogen to completely dry the glass slag raw materials after ultrasonic cleaning; d. put the glass slag raw materials after nitrogen blowing into Add 100ml of "cannibal acid" solution (the volume ratio of concentrated sulfuric acid and hydrogen peroxide is 7:3), and then put it in a water bath at 95°C for 2h; After rinsing with sulfuric acid, put it in ethanol and save it for later use.

[0019] Step 2. Silane coupling on the surface of glass slag: a. Prepare a toluene solution of γ-methacryloxypropyltrimethoxysilane (MPS) (silane coupling agent) (the ratio of toluene to MPS: 8ml Toluene, 8mg MPS, and then use ace...

Embodiment 2

[0022] Step 1. Pretreatment of glass slag surface hydroxylation: a. Take 5 g of 40-mesh glass slag raw material, and use superior grade pure (GR) 99.8% ethanol to repeatedly clean the glass slag raw material for 6 times; b. Wash the cleaned glass Put the slag raw materials into beakers filled with deionized water, ethanol, and acetone in turn for 10 minutes; c. use nitrogen to completely dry the glass slag raw materials after ultrasonic cleaning; d. put the glass slag raw materials after nitrogen blowing into Add 100ml of "cannibal acid" solution (the volume ratio of concentrated sulfuric acid and hydrogen peroxide is 7:3), and then put it in a water bath at 95°C for 2h; After rinsing with sulfuric acid, put it in ethanol and save it for later use.

[0023] Step 2. Silane coupling on the surface of glass slag: a. Prepare a toluene solution of γ-methacryloxypropyltrimethoxysilane (MPS) (silane coupling agent) (the ratio of toluene to MPS: 8ml Toluene, 8mg MPS, and then use ace...

Embodiment 3

[0026]Take 24 mesh glass slag raw materials, 24 mesh modified new glass slag filter materials with negative charges on the surface, and ordinary quartz sand, each about 30g, and place them in the filter column. The thickness of the filter layer is about 13cm. The incoming river water was subjected to filtration experiments, and the raw water before filtration and the effluent after filtration were both tested for turbidity with a turbidity meter. The results are shown in Table 1:

[0027] Table I:

[0028]

[0029] In order to illustrate the effect of the present invention, the inventor provides comparative experiments as follows:

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Abstract

The invention discloses a preparation method of a novel glass slag filter material with a negatively charged modified surface, wherein the preparation method includes the following steps: step S101, hydroxylation pretreatment of a glass slag surface: a, repeatedly cleaning a glass slag raw material for 5-6 times with 99.8% high-grade pure (GR) ethanol; b, successively putting the cleaned glass slag raw material into beakers containing deionized water, ethanol and acetone respectively, and carrying out ultrasonic treatment for 10 min respectively; c, completely blow-drying the glass slag raw material after ultrasonic cleaning with nitrogen; and d, putting the glass slag raw material after nitrogen blow-drying into an 'piranha' solution (with the volume ratio of concentrated sulfuric acid tohydrogen peroxide of 7:3), and then bathing in water for 1-2 h at the temperature of 95 DEG C. The novel filter material based on recycling of waste glass resources is achieved. Compared with a traditional filter material of quartz sand, the novel filter material has the advantages of backwash water saving and good filtering effect, has filter material which is not easy to lose, and is of great significance to reduce the production cost and running and operation difficulty of water plants and other use enterprises.

Description

technical field [0001] The invention relates to the fields of material science and adsorption science, in particular to a method for preparing a modified surface negatively charged novel glass slag filter material. Background technique [0002] Filtration is a widely used process in water treatment (purification of drinking water and treatment of wastewater). In the process of water treatment, filtration generally refers to the technological process of intercepting suspended impurities in water with a granular filter layer such as quartz sand, so that the water is clarified. Filtration can not only remove suspended solids in water, thereby reducing turbidity, but also reduce BOD, COD, heavy metal ion concentration, oil content and chromaticity with the removal of suspended solids. In the traditional water quality filtration process, ordinary quartz sand is generally used as the filter material in the filter tank. Later, light filter materials such as anthracite and ceramsit...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01D39/06C02F1/00C03C23/00
CPCB01D39/06B01D2239/0414B01D2239/0435C02F1/001C03C23/0075C03C23/0095
Inventor 赵鹏史全滨马骁腾
Owner 天津华清环宇环保科技有限公司
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