Oil-in-water type environment-friendly spray adhesive and preparation method thereof

An oil-in-water type, environmentally friendly technology, applied in the direction of adhesives, adhesive types, rosin adhesives, etc., can solve the problems of poor antifreeze performance of water-based spray adhesives, high cost of raw materials, and volatile organic solvents, etc., to achieve Improve frost resistance and low temperature stability, facilitate spraying operation, and reduce the effect of organic solvent components

Inactive Publication Date: 2020-04-24
广东绿洲化工有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Organic solvent-based spray glue uses organic solvents as the dispersion medium and diluent. Organic solvents are easy to volatilize and spread into the air to pollute the environment. Some products contain toxic and harmful solvents such as benzene and dichloroethane, which are harmful to people's health. Harm; water-based spray glue is mainly water-based chloroprene, which requires special spraying equipment, and the cost of raw materials is high
The antifreeze performance of water-based spray glue is not as good as that of organic solvent-based spray glue, which limits its application range

Method used

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  • Oil-in-water type environment-friendly spray adhesive and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0030] The oil-in-water type environmental protection spray glue of this embodiment includes 50 parts of oil phase, 10 parts of compound emulsifier, 50 parts of deionized water, 1 part of polyether modified polysiloxane defoamer, 1 part of diethylene glycol Glycol dibenzoate, 2 parts stabilizer (1 part methylcellulose and 1 part ethylcellulose); of which,

[0031] The composition of the oil phase comprises 10 parts of thermoplastic styrene-butadiene rubber (5 parts of Yuehua 1401, 5 parts of Yuehua 1301); 12 parts of tackifying resin (5 parts of rosin glyceride 138, 5 parts of rosin, 2 parts of terpene phenolic resin 803L); 100 parts of mixed solvent (50 parts of methyl acetate, 30 parts of ethyl acetate, 20 parts of absolute ethanol).

[0032] The composition of the compound emulsifier comprises 3 parts of sodium dodecylbenzenesulfonate, 3 parts of alkyl alcohol ether phosphate and 2 parts of alkylphenol polyoxyethylene ether.

Embodiment 2

[0034] The oil-in-water type environmental protection spray glue of this embodiment includes 80 parts of oil phase, 30 parts of compound emulsifier, 80 parts of deionized water, 1.5 parts of polyether modified polysiloxane defoamer, 2 parts of diethylene glycol Glycol dibenzoate, 3 parts stabilizer (1.5 parts methylcellulose and 1.5 parts ethylcellulose); of which,

[0035] The composition of described oil phase comprises 15 parts of thermoplastic styrene-butadiene rubbers (7.5 parts of Yuehua 1401, 7.5 parts of Yuehua 1301); 803L); 180 parts of mixed solvent (80 parts of methyl acetate, 60 parts of ethyl acetate, 40 parts of absolute ethanol).

[0036] The compound emulsifier comprises 5 parts of sodium dodecylbenzenesulfonate, 5 parts of alkyl alcohol ether phosphate and 5 parts of alkylphenol polyoxyethylene ether.

Embodiment 3

[0038] The oil-in-water type environmental protection spray glue of this embodiment includes 100 parts of oil phase, 50 parts of compound emulsifier, 100 parts of deionized water, 2 parts of polyether modified polysiloxane defoamer, 3 parts of diethylene glycol Glycol dibenzoate, 5 parts stabilizer (3 parts methylcellulose and 2 parts ethylcellulose); of which,

[0039] The composition of described oil phase comprises 20 parts of thermoplastic styrene-butadiene rubbers (10 parts of Yuehua 1401, 10 parts of Yuehua 1301); 30 parts of tackifying resins (8 parts of rosin glyceride 138, 16 parts of rosin, 6 parts of terpene phenolic resins 803L); 230 parts of mixed solvent (100 parts of methyl acetate, 80 parts of ethyl acetate, 50 parts of absolute ethanol).

[0040] The compound emulsifier comprises 10 parts of sodium dodecylbenzenesulfonate, 8 parts of alkyl alcohol ether phosphate and 6 parts of alkylphenol polyoxyethylene ether.

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Abstract

The invention provides an oil-in-water type environment-friendly spray adhesive and a preparation method thereof. The environment-friendly spray adhesive comprises 50-100 parts of an oil phase, 10-50parts of a compound emulsifier, 50-100 parts of deionized water, 1-2 parts of a defoaming agent, 1-3 parts of a plasticizer and 2-5 parts of a stabilizer, wherein the oil phase comprises 10-20 parts of thermoplastic styrene-butadiene rubber, 12-30 parts of tackifying resin and 100-230 parts of a mixed solvent; and the compound emulsifier comprises 6-18 parts of an anionic emulsifier and 2-6 partsof a nonionic emulsifier. The added plasticizer is environmentally friendly, the plasticizer and the stabilizer can improve the frost resistance and low-temperature stability of the oil-in-water typeenvironment-friendly spray adhesive, and the oil-in-water type environment-friendly spray adhesive product is moderate in viscosity, convenient to spray, high in initial adhesion and capable of completely replacing an existing solvent type spray adhesive.

Description

technical field [0001] The invention relates to an oil-in-water type environmental protection spray glue and a preparation method thereof. Background technique [0002] Spray glue is a type of adhesive that is sprayed on the surface of sponge, wood, leather and other materials to play a bonding role. Spray glue is divided into organic solvent spray glue and water-based spray glue. Organic solvent-based spray glue uses organic solvents as the dispersion medium and diluent. Organic solvents are easy to volatilize and spread into the air to pollute the environment. Some products contain toxic and harmful solvents such as benzene and dichloroethane, which are harmful to people's health. Harm; water-based spray glue is mainly water-based neoprene, which requires special spraying equipment, and the cost of raw materials is high. The antifreeze performance of water-based spray glue is not as good as that of organic solvent-based spray glue, which limits its application range. Co...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09J153/02C09J193/04C09J161/14C09J11/08C09J11/06
CPCC08L2205/025C08L2205/035C09J11/06C09J11/08C09J153/02C09J193/04C08L53/02C08L93/04C08L61/14C08L1/28C08K5/103
Inventor 郑秀明谭璋
Owner 广东绿洲化工有限公司
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