A kind of interior wall coating with long-lasting mosquito repelling effect and preparation method thereof
A technology for interior wall paint and function, applied in antifouling/underwater paints, coatings, paints containing biocides, etc. , to achieve the effects of excellent freeze-thaw stability, high safety and simple synthesis process
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preparation example 1
[0077] Preparation Example 1: Ethyl Acrylate (EA) Polymer Latex-1
[0078] A kind of zero addition polymer latex A is made by following process:
[0079] 1) 15g of sodium lauryl sulfate, 5g of ANPEO10, 5g of COPS-1, 285g of deionized water, 145g of MMA, 800g of EA, 50g of AAEM, and 5g of AA were mixed to obtain a pre-emulsion (ME);
[0080] 2) 1.6gAPS and 40g water are mixed to obtain the dripping initiator solution;
[0081] 3) 2.4gAPS and 30g water are mixed to obtain the initiator solution at the bottom of the tank;
[0082] 4) Add 0.5g of sodium lauryl sulfate and 500g of deionized water into the reactor, stir and dissolve them, and heat them to 85°C in a nitrogen environment. When the temperature in the reactor rises to 85°C, add 50g of Pre-emulsion (ME) and all the initiator solution at the bottom of the kettle are kept for 10 minutes;
[0083] 5) Control the temperature at 85°C, add the remaining pre-emulsion (ME) and the entire initiator solution dropwise at the sam...
preparation example 2
[0086] Preparation Example 2: Butyl Acrylate (BA) Polymer Latex-2
[0087] A zero-added polymer latex-2 is prepared by the following process:
[0088] 1) 15g sodium lauryl sulfate, 285g deionized water, COPS-1 of 5g, the MMA of ANPEO10,385g of 5g, the BA of 560g, the AAEM of 50g, the AA of 5g are mixed to obtain monomer pre-emulsion (ME );
[0089] 2) 1.6gAPS and 40g water are mixed to obtain the dripping initiator solution;
[0090] 3) 2.4gAPS and 40g water are mixed to obtain the initiator solution at the bottom of the tank;
[0091] 4) 0.5g of sodium lauryl sulfate and 500g of deionized water are added to the reactor and heated to 85°C in a nitrogen environment. When the temperature in the reactor is warming up to 85°C, 50g of pre-emulsion ( ME) and the initiator solution at the bottom of the tank were incubated for 10 min;
[0092] 5) Keep the temperature at about 85°C, add the remaining pre-emulsion (ME) and the initiator solution dropwise at the same time, keep the t...
preparation example 3
[0095] Preparation Example 3: Ethyl Acrylate (EA) Polymer Latex-3
[0096] A zero-added polymer latex-3 is prepared by the following process:
[0097] 1) 15g of sodium lauryl sulfate, 5g of COPS-1, 285g of deionized water, 145g of MMA, 800g of EA, 50g of AAEM, and 5g of AA were mixed to obtain a pre-emulsion (ME).
[0098] 2) Mix 1.6g APS and 40g water to obtain a dropwise initiator solution.
[0099] 3) Mix 2.4g APS and 40g water to obtain a tank bottom initiator solution.
[0100] 4) Add 0.5g of sodium lauryl sulfate and 500g of deionized water to the reactor and heat it to 85°C in a nitrogen atmosphere. When the temperature in the reactor rises to 85°C, add 50g of pre-emulsion (ME ) and the initiator solution at the bottom of the kettle were kept for 10 minutes.
[0101]5) Keep the temperature at about 85°C, add the remaining pre-emulsion (ME) and the initiator solution dropwise at the same time, keep the temperature for 20 minutes after the dropwise addition is complete...
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