Preparation method and application of novel lithium ion battery negative electrode material carbonized grape seed

A technology for lithium-ion batteries and negative electrode materials, applied in battery electrodes, chemical instruments and methods, negative electrodes, etc., can solve the problems of manufacturing technology limitations, high non-renewability of carbon precursors, and complicated costs, and achieve easy acquisition and operation Simple, the effect of increasing storage capacity

Inactive Publication Date: 2020-06-12
LIAONING UNIVERSITY
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

However, the non-renewability and high cost of carbon precursors and complex fabrication techniques limit their large-scale application
At present, there are no reports on the preparation of three-dimensional porous carbon materials from grape seeds and their application in the field of lithium-ion battery anodes.

Method used

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  • Preparation method and application of novel lithium ion battery negative electrode material carbonized grape seed
  • Preparation method and application of novel lithium ion battery negative electrode material carbonized grape seed
  • Preparation method and application of novel lithium ion battery negative electrode material carbonized grape seed

Examples

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Embodiment 2

[0045] Example 2 Application of Carbonized Grape Seed as Lithium-ion Battery Negative Electrode Material

[0046] (1) Assembly of lithium ion battery

[0047] 1) Take the common acetylene black bought in the market as the conductive agent, PVDF as the binder, and the carbonized grape seed prepared in Example 1 as the negative electrode material. According to the mass ratio, carbonized grape seeds: acetylene black: PVDF = 6:3:1 were mixed and paste, uniformly coated on the copper foil as the negative electrode, and (lithium sheet) as the positive electrode, assembled into a button battery-1.

[0048] 2) Take the common acetylene black bought in the market as the conductive agent, PVDF as the binder, and the carbonized grape seed prepared in Example 1 as the negative electrode material. According to the weight ratio, carbonized grape seeds: acetylene black: PVDF=7:2:1 are mixed and paste, evenly coated on the copper foil as the negative electrode, (lithium sheet) as the positiv...

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Abstract

The invention discloses a preparation method and application of a novel lithium ion battery negative electrode material carbonized grape seed. The preparation method comprises the following steps: drying grape seeds, grinding into powder, soaking in an activator solution, and magnetically stirring the solution at 80 DEG C for 4 hours; and filtering the solution, carrying out vacuum drying on the soaked grape seed powder at 80 DEG C for 12 hours, putting the dried grape seed powder into a tubular furnace, calcining the grape seed powder at 700-900 DEG C for 2-6 hours in an argon atmosphere, cooling the grape seed powder to room temperature, sequentially carrying out centrifugal washing with hydrochloric acid and distilled water to neutrality, carrying out vacuum drying, and grinding the grape seed powder to obtain the target product carbonized grape seeds. The carbonized grape seeds are used as the negative electrode material of the lithium ion battery, so that the raw materials are easy to obtain and are environment-friendly; secondly, the carbonized grape seeds have a porous structure, so that the reaction active sites are increased, the conductivity of the material can be improved, and the electrochemical performance of the material is improved.

Description

technical field [0001] The invention relates to the technical field of lithium ion batteries, in particular to a preparation method and application of carbonized grape seeds, a novel lithium ion battery negative electrode material. Background technique [0002] Since the lithium-ion battery was introduced to the market in the 1990s, it has received unanimous praise from the battery industry and users for its excellent electrochemical performance. At present, lithium-ion batteries have occupied a dominant position in the field of mobile electronic terminal equipment such as notebook computers, mobile phones, and cameras, and have great application prospects and commercial value in new energy fields such as power vehicles. [0003] Electrode active materials are the core of batteries and play a decisive role in battery performance. Carbon materials have been considered as the most commercially valuable anode materials in LIBs. The current carbon material used for the negativ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C01B32/348C01B32/324H01M4/587H01M10/0525H01M4/02
CPCC01B32/324C01B32/348H01M4/587H01M10/0525H01M2004/027Y02E60/10
Inventor 葛昊尚婷婷修忠海郭欣张诏
Owner LIAONING UNIVERSITY
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