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A kind of wool-like crimped electrospun nanofiber and its preparation method

A nanofiber and electrospinning technology, which is applied in electrospinning, fiber treatment, cellulose/protein conjugated artificial filament, etc., can solve the problems of difficult control of flight stretching and inability to guarantee composite fibers, etc., and achieve excellent compression back The effect of elastic energy

Active Publication Date: 2022-04-08
DONGHUA UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The present invention mixes high elastic polymer and low elastic polymer to form a homogeneous spinning solution for electrospinning, and utilizes the retraction of the two polymer molecular chains that are not fully stretched after the spinning jet is rapidly solidified in a high-humidity environment Curls are formed in different degrees, and the curly structure can be controlled by controlling the environmental humidity and the ratio between high elastic polymers and low elastic polymers, which solves the problem of the composite jets ejected by parallel electrospinning or coaxial nozzles in the spinning process in the prior art. In fact, it is difficult to control the flying stretching in the process, and the problem of forming composite fibers cannot be guaranteed; and the preparation method of the present invention carries out electrospinning of the mixed spinning solution of high elastic polymer and low elastic polymer in a high humidity environment. The production device has no special requirements, and can be carried out on the existing electrospinning mass production equipment

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0032] A method for preparing wool-like curled electrospun nanofibers, the steps are as follows:

[0033] (1) Dissolving polyurethane elastomer and polyacrylonitrile with a mass ratio of 1:5 in N,N-dimethylformamide and magnetic stirring to prepare a mixed spinning solution with a concentration of 5wt%, wherein the stirring time 6h, the stirring speed is 500rpm, and the stirring temperature is 70°C;

[0034] (2) Place the mixed spinning solution prepared in step (1) in the liquid supply device, adjust the electrospinning process parameters, switch on the high voltage power supply, adjust the relative humidity of the spinning environment to 70%, and start the electrospinning process , and receive the obtained wool-like crimped electrospun nanofibers through the collection device; wherein, the process parameters of electrospinning are: voltage 10kV, receiving distance 5cm, perfusion speed 0.1mL / h, spinning temperature 15°C.

[0035] The final obtained wool-like curled electrosp...

Embodiment 2

[0043] A method for preparing wool-like curled electrospun nanofibers, the steps are as follows:

[0044] (1) Polyurethane elastomer and polyvinylidene fluoride with a mass ratio of 1:7 are dissolved in N,N-dimethylacetamide and magnetically stirred to obtain a mixed spinning solution with a concentration of 7wt%, wherein the stirring The time is 6h, the stirring speed is 500rpm, and the stirring temperature is 70°C;

[0045] (2) Place the mixed spinning solution prepared in step (1) in the liquid supply device, adjust the electrospinning process parameters, switch on the high voltage power supply, adjust the relative humidity of the spinning environment to 70%, and start the electrospinning process , and receive the obtained wool-like crimped electrospun nanofibers through the collection device; wherein, the process parameters of the electrospinning are: voltage 20kV, receiving distance 5cm, perfusion speed 0.4mL / h, spinning temperature 15°C.

[0046] The final obtained wool...

Embodiment 3

[0048] A method for preparing wool-like curled electrospun nanofibers, the steps are as follows:

[0049] (1) Dissolve thermoplastic polyurethane and polystyrene with a mass ratio of 2:5 in ethyl acetate and magnetically stir to prepare a mixed spinning solution with a concentration of 10wt%, wherein the stirring time is 12h and the stirring speed is 280rpm , the stirring temperature is 50°C;

[0050] (2) Place the mixed spinning solution prepared in step (1) in the liquid supply device, adjust the electrospinning process parameters, switch on the high voltage power supply, adjust the relative humidity of the spinning environment to 72%, and start the electrospinning process , and receive the obtained wool-like crimped electrospun nanofibers through the collection device; wherein, the process parameters of the electrospinning are: voltage 30kV, receiving distance 8cm, perfusion speed 0.7mL / h, spinning temperature 20°C.

[0051] The final obtained wool-like curled electrospun ...

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Abstract

The invention relates to a wool-like crimped electrospun nanofiber and a preparation method thereof. The preparation method is as follows: the mixed spinning solution of a high-elasticity polymer and a low-elasticity polymer is carried out in a high-humidity (relative humidity of 70-95%) environment. Electrospinning obtains wool-like crimped electrospun nanofibers, and the mass ratio of the high elastic polymer to the low elastic polymer in the mixed spinning solution is 1-5:5-9; the prepared wool-like crimped electrospun nanofibers The diameter of the nanofiber is 100-700nm, with a helical coil structure, and the helical radius is 2-3μm; the thickness of the three-dimensional nanofiber material formed by the fluffy accumulation of wool-like curled electrospun nanofibers is 5-25mm, and the porosity is over 99%. 0.5-2.5 μm; the three-dimensional nanofibrous material has a compression rebound rate of more than 95% after cross-linking heat treatment. The preparation method of the invention is simple and easy, can be mass-produced, and the prepared product has excellent compression resilience performance.

Description

technical field [0001] The invention belongs to the technical field of electrospinning nanofibers, and relates to a wool-like crimped electrospinning nanofiber and a preparation method thereof. Background technique [0002] Electrospun nanofibers have the advantages of thin diameter and high specific surface area, and have broad application prospects in many fields. Light and fluffy nanofiber materials with high porosity and low density are one of the important directions for the development of nanofiber materials. This material has great potential in the fields of filtration and separation, sound absorption and noise reduction, tissue engineering, heat insulation, and aerospace. Value. However, the nanofibers obtained by traditional electrospinning technology are usually densely deposited, forming a dense fiber film with a thickness of no more than 0.5 mm, which limits the application of nanofibers in various fields. [0003] Wool fiber has a spiral crimp structure, which...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): D01D5/00D01D5/22D01D10/02D01D5/30D01F8/16D01F8/08D01F8/10D01F8/12D01F8/14D01F8/02D01F8/06
CPCD01D5/003D01D5/22D01D10/02D01D5/30D01F8/16D01F8/08D01F8/10D01F8/12D01F8/14D01F8/02D01F8/06
Inventor 丁彬吴红炎王赛李玉瑶田昱城赵磊郑作保斯阳印霞刘一涛俞建勇
Owner DONGHUA UNIV