Polysulfonic acid structure surface wetting agent and preparation method thereof

A technology of structured surface and wetting agent, applied in the preparation of sulfonic acid, chemical instruments and methods, other chemical processes, etc., can solve the problems of poor water spreadability, etc., to improve the water wetting speed, reduce surface tension, and improve the safety of raw materials. Effect

Inactive Publication Date: 2020-08-21
宁夏宇航油田工程有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] In order to solve the problem of poor spreadability of water on solid surfaces in the prior art, the object of the present invention is to provide a surface wetting agent with polysulfonic acid structure and its preparation method

Method used

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  • Polysulfonic acid structure surface wetting agent and preparation method thereof
  • Polysulfonic acid structure surface wetting agent and preparation method thereof
  • Polysulfonic acid structure surface wetting agent and preparation method thereof

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preparation example Construction

[0027] Concrete, a kind of preparation method of polysulfonic acid structure surface wetting agent, comprises the following steps:

[0028] (1) Add dipentaerythritol and hexanoyl chloride into a three-necked flask, wherein the molar ratio of dipentaerythritol and hexanoyl chloride is 1:(3.1-3.2). After the addition is complete, stir the reaction at 30-50°C for 2-4 hours, and cool to room temperature. Neutralize with sodium hydroxide solution, wherein the concentration of the sodium hydroxide solution is 4% (mass fraction). Wash with water, extract with an organic solvent, and distill off the solvent under reduced pressure to obtain viscous liquid intermediate Ⅰ.

[0029] (2) Add the viscous liquid intermediate I obtained in step (1) into a four-necked flask, and the added amount of the viscous liquid intermediate I is 0.025 mol. Then the first solvent dimethyl sulfoxide (DMSO) was added into the four-neck flask, and the added amount was 140 mL. After all the powder is disso...

Embodiment 1

[0034] Add dipentaerythritol and hexanoyl chloride into a three-necked flask at a molar ratio of 1:3.1. After the addition is complete, stir and react at 40°C for 3h, and cool to room temperature. Neutralize with 4% (mass fraction) sodium hydroxide solution, wash with water, extract with organic solvent, and distill off the solvent under reduced pressure to obtain viscous liquid intermediate I. Take 0.025mol of the viscous liquid intermediate I and add it to the four-necked flask, then add 140mL dimethyl sulfoxide (DMSO) into the four-necked flask, and after it is completely dissolved, add 4g of powdered sodium hydroxide and stir the reaction at 30°C 0.5h, then add 0.05mol 3-chloro-2-hydroxypropyl propane sulfonate into the solution containing dimethyl sulfoxide and other solvents, raise the temperature to 85°C, and react for 6 hours, then filter the above solution with suction to obtain a solid Product Intermediate II. Add 0.02 mol of solid product intermediate II to 29.24 g...

Embodiment 2

[0036] Add dipentaerythritol and hexanoyl chloride into a three-necked flask at a molar ratio of 1:3.12. After the addition is complete, stir and react at 40°C for 3h, and cool to room temperature. Neutralize with 4% (mass fraction) sodium hydroxide solution, wash with water, extract with organic solvent, and distill off the solvent under reduced pressure to obtain viscous liquid intermediate I. Take 0.025mol of the viscous liquid intermediate I and add it to the four-necked flask, then add 140mL dimethyl sulfoxide (DMSO) into the four-necked flask, and after it is completely dissolved, add 4g of powdered sodium hydroxide and stir the reaction at 30°C 0.5h, then add 0.05mol 3-chloro-2-hydroxypropyl propane sulfonate into the solution containing dimethyl sulfoxide and other solvents, raise the temperature to 85°C, and react for 6 hours, then filter the above solution with suction to obtain a solid Product Intermediate II. Add 0.02 mol of solid product intermediate II to 29.24 ...

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Abstract

The invention discloses a polysulfonic acid structure surface wetting agent and a preparation method thereof. The preparation method comprises the following steps: 1) mixing dipentaerythritol and hexanoyl chloride, stirring and reacting for 2-4 h at the temperature of 30-50 DEG C, cooling to the room temperature, neutralizing, washing with water, extracting, and distilling under reduced pressure to remove the solvent to obtain a viscous liquid intermediate I; 2) adding a first solvent into the viscous liquid intermediate I, adding powdery sodium hydroxide after the viscous liquid intermediateis completely dissolved, stirring and reacting for 0.5-1 h at 25-35 DEG C, then adding sodium 3-chloro-2-hydroxypropyl propanesulfonate into the solution, heating to 80-90 DEG C, reacting for 5-7 h, and carrying out suction filtration to obtain a solid product intermediate II; and 3) adding the solid product intermediate II into a second solvent, adding hexamethylene diisocyanate under magnetic stirring, heating to 40-50 DEG C, reacting for 3-5 h, carrying out suction filtration, and drying to obtain the polysulfonic acid structure surface wetting agent. The preparation method solves the problem of poor spreadability of water on the solid surface.

Description

technical field [0001] The invention relates to a surface wetting agent for chemical fiber materials, in particular to a surface wetting agent with a polysulfonic acid structure and a preparation method thereof. Background technique [0002] No matter what the situation is, the lotus can always keep itself clean. This is the so-called "lotus effect", and this phenomenon is a manifestation of moisturizing. Wetting is a phenomenon that widely exists in nature. The wetting property is one of the important properties in the theoretical study of solid surfaces. The most common wetting is that the gas on the solid surface is replaced by liquid, or solid- One liquid on the liquid interface is replaced by another liquid, and the substance that can enhance this replacement ability is a wetting agent. Wetting processes fall into three categories: wetting, wetting, and spreading. Contents of the invention [0003] In order to solve the problem of poor spreadability of water on soli...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C07C309/10C07C303/22C09K3/18B01F17/42C09K23/42
CPCC07C309/10C09K3/18C09K23/00
Inventor 王晨王江涛杨晓武李刚辉
Owner 宁夏宇航油田工程有限公司
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