The invention discloses a high temperature-resistant easy-collapsing precoated sand for casting. The high temperature-resistant easy-collapsing precoated sand is prepared from the following componentsin parts by weight: 87 to 118 parts of raw sand, 2 to 2.5 parts of benzoxazine resin, 0.7 to 3.1 parts of polyvinyl butyral, 3.7 to 5.6 parts of inorganic polymer, 0.3 to 0.5 part of sodium alginate,3 to 11 parts of bauxite, 3 to 13 parts of mullite powder, 5 to 15 parts of diatomite, 0.3 to 0.4 part of hexamethylenetetramine, 0.1 to 0.2 part of barium stearate, 0.1 to 0. 2 part of zinc stearate, 0.15 to 0.2 part of calcium stearate, 0.45 to 3.8 parts of flake graphite, 0.7 to 3.3 parts of dolomite powder, and 0.1 to 0.3 part of potassium nitrate. The high temperature-resistant easy-collapsing precoated sand for casting has the advantages that the combination of components is optimized; especially, the decomposing temperature of the potassium nitrate is high, the heat-resistant propertyof the benzoxazine resin is high, and the components can reach the synergistic cooperation function; the preparation method is simple, the sources of the raw materials are wide, and the high temperature-resistant property and the post-casting collapsing property of the precoated sand are guaranteed.